Heterogeneous Catalytic Synthesis of Organic Compounds Labeled with Hydrogen Isotopes without Using Solvents
Solid-phase procedures for hydrogenolysis, hydrogenation, and isotope exchange are described. The possibilities of the solid-phase method for deuterium or tritium labeling of organic compounds are demonstrated. The influence of the reaction conditions on the yield of the labeled products and on the...
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| Veröffentlicht in: | Radiochemistry (New York, N.Y.) N.Y.), 2018-03, Vol.60 (2), p.105-139 |
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| container_end_page | 139 |
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| container_issue | 2 |
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| container_title | Radiochemistry (New York, N.Y.) |
| container_volume | 60 |
| creator | Shevchenko, V. P. Nagaev, I. Yu Myasoedov, N. F. |
| description | Solid-phase procedures for hydrogenolysis, hydrogenation, and isotope exchange are described. The possibilities of the solid-phase method for deuterium or tritium labeling of organic compounds are demonstrated. The influence of the reaction conditions on the yield of the labeled products and on the degree of hydrogen isotope incorporation into them is considered. An attempt is made to rationalize the data obtained by processes occurring in the hydrogen isotope–catalyst–support–substrate system. |
| doi_str_mv | 10.1134/S1066362218020017 |
| format | Article |
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| ispartof | Radiochemistry (New York, N.Y.), 2018-03, Vol.60 (2), p.105-139 |
| issn | 1066-3622 1608-3288 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Catalysis Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Deuterium Hydrogen isotopes Hydrogen storage Hydrogenolysis Isotopes Nuclear Chemistry Organic compounds Solvents Substrates Tritium |
| title | Heterogeneous Catalytic Synthesis of Organic Compounds Labeled with Hydrogen Isotopes without Using Solvents |
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