N-chloro hydantoin functionalized polyurethane fibers toward protective cloth against chemical warfare agents
Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared for the decontamination of chemical warfare agents. Azido-polyurethane was firstly synthesized using azido-polydiol with 4,4′-methylenebis(phenylisocyanate) and 1,4-butanediol via step-addition polymerization....
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| Veröffentlicht in: | Polymer (Guilford) 2018-02, Vol.138, p.146-155 |
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| creator | Choi, Jihyun Moon, Da Som Ryu, Sam Gon Lee, Bumjae Ying, Wu Bin Lee, Kyung Jin |
| description | Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared for the decontamination of chemical warfare agents. Azido-polyurethane was firstly synthesized using azido-polydiol with 4,4′-methylenebis(phenylisocyanate) and 1,4-butanediol via step-addition polymerization. Hydantoin was introduced into the polyurethane via click reaction, followed by electrospinning and chlorination to obtain the decontaminable fibers. This N-chlorinated hydantoin-polyurethane fiber is an active decontaminable species for 2-chloroethyl ethyl sulfide and demeton-S-methyl, the simulant of chemical warfare agent. The decontamination efficiency of each exhibits 69% and 16% for 2-chloroethyl ethyl sulfide and demeton-S-methyl, respectively, with molar ratio of 1/1 for 2 h at ambient condition. This N-chlorinated hydantoin-polyurethane fiber exhibited considerable potential as the decontaminable material against toxic chemical warfare agents.
N-chloro hydantoin functionalized polyurethane fibers synthesized from hydantoin functionalization of azido-polyurethane, electrospinning and chlorination can decontaminate the chemical warfare agents. [Display omitted]
•Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared.•Nanofiber web is an active for decontamination of CEES and demeton-S-methyl.•Relatively high decontamination efficiency can be obtained using nanofiber web.•With great processibility of this polyurethane, it can be extended to actual army cloth. |
| doi_str_mv | 10.1016/j.polymer.2018.01.066 |
| format | Article |
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N-chloro hydantoin functionalized polyurethane fibers synthesized from hydantoin functionalization of azido-polyurethane, electrospinning and chlorination can decontaminate the chemical warfare agents. [Display omitted]
•Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared.•Nanofiber web is an active for decontamination of CEES and demeton-S-methyl.•Relatively high decontamination efficiency can be obtained using nanofiber web.•With great processibility of this polyurethane, it can be extended to actual army cloth.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2018.01.066</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Addition polymerization ; Azido-polyurethane ; Butanediol ; Chemical reactions ; Chemical synthesis ; Chemical warfare ; Chemical warfare agents ; Chlorination ; Cloth ; Decontamination ; Fibers ; Hydantoin ; N-chloro hydantoin ; Nanofibers ; Polymerization ; Polyurethane ; Polyurethane resins ; Sulfide ; Sulfides</subject><ispartof>Polymer (Guilford), 2018-02, Vol.138, p.146-155</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV Feb 28, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-d45e6c499ca69ab0ea8b1c295bb3fba0376a4e8b5682e6e071c54646bcb90c63</citedby><cites>FETCH-LOGICAL-c376t-d45e6c499ca69ab0ea8b1c295bb3fba0376a4e8b5682e6e071c54646bcb90c63</cites><orcidid>0000-0002-6709-3235 ; 0000-0003-2894-9296</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymer.2018.01.066$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>Choi, Jihyun</creatorcontrib><creatorcontrib>Moon, Da Som</creatorcontrib><creatorcontrib>Ryu, Sam Gon</creatorcontrib><creatorcontrib>Lee, Bumjae</creatorcontrib><creatorcontrib>Ying, Wu Bin</creatorcontrib><creatorcontrib>Lee, Kyung Jin</creatorcontrib><title>N-chloro hydantoin functionalized polyurethane fibers toward protective cloth against chemical warfare agents</title><title>Polymer (Guilford)</title><description>Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared for the decontamination of chemical warfare agents. Azido-polyurethane was firstly synthesized using azido-polydiol with 4,4′-methylenebis(phenylisocyanate) and 1,4-butanediol via step-addition polymerization. Hydantoin was introduced into the polyurethane via click reaction, followed by electrospinning and chlorination to obtain the decontaminable fibers. This N-chlorinated hydantoin-polyurethane fiber is an active decontaminable species for 2-chloroethyl ethyl sulfide and demeton-S-methyl, the simulant of chemical warfare agent. The decontamination efficiency of each exhibits 69% and 16% for 2-chloroethyl ethyl sulfide and demeton-S-methyl, respectively, with molar ratio of 1/1 for 2 h at ambient condition. This N-chlorinated hydantoin-polyurethane fiber exhibited considerable potential as the decontaminable material against toxic chemical warfare agents.
N-chloro hydantoin functionalized polyurethane fibers synthesized from hydantoin functionalization of azido-polyurethane, electrospinning and chlorination can decontaminate the chemical warfare agents. [Display omitted]
•Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared.•Nanofiber web is an active for decontamination of CEES and demeton-S-methyl.•Relatively high decontamination efficiency can be obtained using nanofiber web.•With great processibility of this polyurethane, it can be extended to actual army cloth.</description><subject>Addition polymerization</subject><subject>Azido-polyurethane</subject><subject>Butanediol</subject><subject>Chemical reactions</subject><subject>Chemical synthesis</subject><subject>Chemical warfare</subject><subject>Chemical warfare agents</subject><subject>Chlorination</subject><subject>Cloth</subject><subject>Decontamination</subject><subject>Fibers</subject><subject>Hydantoin</subject><subject>N-chloro hydantoin</subject><subject>Nanofibers</subject><subject>Polymerization</subject><subject>Polyurethane</subject><subject>Polyurethane resins</subject><subject>Sulfide</subject><subject>Sulfides</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqXwCUiWWCeMncRNVghVvKQKNt1btjMhrtK42E5R-XpclT2rWdwzVzOHkFsGOQMm7jf5zg2HLfqcA6tzYDkIcUZmrF4UGecNOyczgIJnRS3YJbkKYQMAvOLljGzfM9MPzjvaH1o1RmdH2k2jidaNarA_2NJj-eQx9mpE2lmNPtDovpVPkXcRE7tHagYXe6o-lR1DpKbHrTVqoAnrlMcU4BjDNbno1BDw5m_Oyfr5ab18zVYfL2_Lx1VmioWIWVtWKEzZNEaJRmlAVWtmeFNpXXRaQYJUibWuRM1RICyYqUpRCm10A0YUc3J3qk33fU0Yoty4yad_guTAm5ItoC4SVZ0o410IHju583ar_EEykEexciP_xMqjWAlMJrFp7-G0h-mDvU1pMBZHg631SYZsnf2n4Rd8moeu</recordid><startdate>20180228</startdate><enddate>20180228</enddate><creator>Choi, Jihyun</creator><creator>Moon, Da Som</creator><creator>Ryu, Sam Gon</creator><creator>Lee, Bumjae</creator><creator>Ying, Wu Bin</creator><creator>Lee, Kyung Jin</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0002-6709-3235</orcidid><orcidid>https://orcid.org/0000-0003-2894-9296</orcidid></search><sort><creationdate>20180228</creationdate><title>N-chloro hydantoin functionalized polyurethane fibers toward protective cloth against chemical warfare agents</title><author>Choi, Jihyun ; Moon, Da Som ; Ryu, Sam Gon ; Lee, Bumjae ; Ying, Wu Bin ; Lee, Kyung Jin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-d45e6c499ca69ab0ea8b1c295bb3fba0376a4e8b5682e6e071c54646bcb90c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Addition polymerization</topic><topic>Azido-polyurethane</topic><topic>Butanediol</topic><topic>Chemical reactions</topic><topic>Chemical synthesis</topic><topic>Chemical warfare</topic><topic>Chemical warfare agents</topic><topic>Chlorination</topic><topic>Cloth</topic><topic>Decontamination</topic><topic>Fibers</topic><topic>Hydantoin</topic><topic>N-chloro hydantoin</topic><topic>Nanofibers</topic><topic>Polymerization</topic><topic>Polyurethane</topic><topic>Polyurethane resins</topic><topic>Sulfide</topic><topic>Sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Choi, Jihyun</creatorcontrib><creatorcontrib>Moon, Da Som</creatorcontrib><creatorcontrib>Ryu, Sam Gon</creatorcontrib><creatorcontrib>Lee, Bumjae</creatorcontrib><creatorcontrib>Ying, Wu Bin</creatorcontrib><creatorcontrib>Lee, Kyung Jin</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choi, Jihyun</au><au>Moon, Da Som</au><au>Ryu, Sam Gon</au><au>Lee, Bumjae</au><au>Ying, Wu Bin</au><au>Lee, Kyung Jin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N-chloro hydantoin functionalized polyurethane fibers toward protective cloth against chemical warfare agents</atitle><jtitle>Polymer (Guilford)</jtitle><date>2018-02-28</date><risdate>2018</risdate><volume>138</volume><spage>146</spage><epage>155</epage><pages>146-155</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared for the decontamination of chemical warfare agents. Azido-polyurethane was firstly synthesized using azido-polydiol with 4,4′-methylenebis(phenylisocyanate) and 1,4-butanediol via step-addition polymerization. Hydantoin was introduced into the polyurethane via click reaction, followed by electrospinning and chlorination to obtain the decontaminable fibers. This N-chlorinated hydantoin-polyurethane fiber is an active decontaminable species for 2-chloroethyl ethyl sulfide and demeton-S-methyl, the simulant of chemical warfare agent. The decontamination efficiency of each exhibits 69% and 16% for 2-chloroethyl ethyl sulfide and demeton-S-methyl, respectively, with molar ratio of 1/1 for 2 h at ambient condition. This N-chlorinated hydantoin-polyurethane fiber exhibited considerable potential as the decontaminable material against toxic chemical warfare agents.
N-chloro hydantoin functionalized polyurethane fibers synthesized from hydantoin functionalization of azido-polyurethane, electrospinning and chlorination can decontaminate the chemical warfare agents. [Display omitted]
•Polyurethane nanofibers functionalized by high amount of N-chloro hydantoin were prepared.•Nanofiber web is an active for decontamination of CEES and demeton-S-methyl.•Relatively high decontamination efficiency can be obtained using nanofiber web.•With great processibility of this polyurethane, it can be extended to actual army cloth.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2018.01.066</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-6709-3235</orcidid><orcidid>https://orcid.org/0000-0003-2894-9296</orcidid></addata></record> |
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| ispartof | Polymer (Guilford), 2018-02, Vol.138, p.146-155 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Addition polymerization Azido-polyurethane Butanediol Chemical reactions Chemical synthesis Chemical warfare Chemical warfare agents Chlorination Cloth Decontamination Fibers Hydantoin N-chloro hydantoin Nanofibers Polymerization Polyurethane Polyurethane resins Sulfide Sulfides |
| title | N-chloro hydantoin functionalized polyurethane fibers toward protective cloth against chemical warfare agents |
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