Electrochemical polymerization of alizarin and the electrochemical properties of poly(alizarin)
Electrochemical polymerization of alizarin on glassy carbon electrode (GCE) was carried out in acidic solution by cyclic voltammetry (CV), and the polymerization process was monitored by electrochemical quartz crystal microbalance (EQCM). A possible mechanism concerning the polymerization of alizari...
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| Veröffentlicht in: | Ionics 2018-05, Vol.24 (5), p.1391-1397 |
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| container_title | Ionics |
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| creator | Jiang, Yan Niu, Tianci Wang, Zhihua Tan, Wensheng Liu, Feng Kong, Yong |
| description | Electrochemical polymerization of alizarin on glassy carbon electrode (GCE) was carried out in acidic solution by cyclic voltammetry (CV), and the polymerization process was monitored by electrochemical quartz crystal microbalance (EQCM). A possible mechanism concerning the polymerization of alizarin was also proposed in this work. The as-synthesized poly(alizarin) was characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The study on electrode reaction process shows that the electrode reaction of poly(alizarin) is controlled by diffusion. Finally, the activation energy (
E
a
) of the electrode reactions of poly(alizarin) was obtained according to the temperature dependence of the redox peak currents. |
| doi_str_mv | 10.1007/s11581-017-2288-2 |
| format | Article |
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E
a
) of the electrode reactions of poly(alizarin) was obtained according to the temperature dependence of the redox peak currents.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-017-2288-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Alizarin ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electrodes ; Energy Storage ; Glassy carbon ; Optical and Electronic Materials ; Original Paper ; Polymerization ; Renewable and Green Energy ; Scanning electron microscopy ; Temperature dependence</subject><ispartof>Ionics, 2018-05, Vol.24 (5), p.1391-1397</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d5b885a50461332d925371cf44512f93be69a0dbdae7bf60f60c0698f98759b13</citedby><cites>FETCH-LOGICAL-c316t-d5b885a50461332d925371cf44512f93be69a0dbdae7bf60f60c0698f98759b13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-017-2288-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-017-2288-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Jiang, Yan</creatorcontrib><creatorcontrib>Niu, Tianci</creatorcontrib><creatorcontrib>Wang, Zhihua</creatorcontrib><creatorcontrib>Tan, Wensheng</creatorcontrib><creatorcontrib>Liu, Feng</creatorcontrib><creatorcontrib>Kong, Yong</creatorcontrib><title>Electrochemical polymerization of alizarin and the electrochemical properties of poly(alizarin)</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Electrochemical polymerization of alizarin on glassy carbon electrode (GCE) was carried out in acidic solution by cyclic voltammetry (CV), and the polymerization process was monitored by electrochemical quartz crystal microbalance (EQCM). A possible mechanism concerning the polymerization of alizarin was also proposed in this work. The as-synthesized poly(alizarin) was characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The study on electrode reaction process shows that the electrode reaction of poly(alizarin) is controlled by diffusion. Finally, the activation energy (
E
a
) of the electrode reactions of poly(alizarin) was obtained according to the temperature dependence of the redox peak currents.</description><subject>Alizarin</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Energy Storage</subject><subject>Glassy carbon</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Polymerization</subject><subject>Renewable and Green Energy</subject><subject>Scanning electron microscopy</subject><subject>Temperature dependence</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8FL3qIzqRtPo6yrB-w4EXPIU1Tt0u3WZPuYf31plQRBCEwBJ7nneEl5BLhFgHEXUQsJVJAQRmTkrIjMkPJGQXB4ZjMQBWCCijEKTmLcQPAOTIxI3rZOTsEb9du21rTZTvfHbYutJ9maH2f-SYzXfqEts9MX2fD2mXurxL8zoWhdXHEx4DrH-fmnJw0povu4nvOydvD8nXxRFcvj8-L-xW1OfKB1mUlZWlKKDjmOasVK3OBtimKElmj8spxZaCuauNE1XBIzwJXslFSlKrCfE6uptx0zMfexUFv_D70aaVmwARXrFAjhRNlg48xuEbvQrs14aAR9NijnnrUqUc99qhZctjkxMT27y78Jv8vfQHOTHZ0</recordid><startdate>20180501</startdate><enddate>20180501</enddate><creator>Jiang, Yan</creator><creator>Niu, Tianci</creator><creator>Wang, Zhihua</creator><creator>Tan, Wensheng</creator><creator>Liu, Feng</creator><creator>Kong, Yong</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180501</creationdate><title>Electrochemical polymerization of alizarin and the electrochemical properties of poly(alizarin)</title><author>Jiang, Yan ; Niu, Tianci ; Wang, Zhihua ; Tan, Wensheng ; Liu, Feng ; Kong, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d5b885a50461332d925371cf44512f93be69a0dbdae7bf60f60c0698f98759b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alizarin</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Energy Storage</topic><topic>Glassy carbon</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Polymerization</topic><topic>Renewable and Green Energy</topic><topic>Scanning electron microscopy</topic><topic>Temperature dependence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Yan</creatorcontrib><creatorcontrib>Niu, Tianci</creatorcontrib><creatorcontrib>Wang, Zhihua</creatorcontrib><creatorcontrib>Tan, Wensheng</creatorcontrib><creatorcontrib>Liu, Feng</creatorcontrib><creatorcontrib>Kong, Yong</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Yan</au><au>Niu, Tianci</au><au>Wang, Zhihua</au><au>Tan, Wensheng</au><au>Liu, Feng</au><au>Kong, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical polymerization of alizarin and the electrochemical properties of poly(alizarin)</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2018-05-01</date><risdate>2018</risdate><volume>24</volume><issue>5</issue><spage>1391</spage><epage>1397</epage><pages>1391-1397</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Electrochemical polymerization of alizarin on glassy carbon electrode (GCE) was carried out in acidic solution by cyclic voltammetry (CV), and the polymerization process was monitored by electrochemical quartz crystal microbalance (EQCM). A possible mechanism concerning the polymerization of alizarin was also proposed in this work. The as-synthesized poly(alizarin) was characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The study on electrode reaction process shows that the electrode reaction of poly(alizarin) is controlled by diffusion. Finally, the activation energy (
E
a
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| language | eng |
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| subjects | Alizarin Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemical analysis Electrochemical impedance spectroscopy Electrochemistry Electrodes Energy Storage Glassy carbon Optical and Electronic Materials Original Paper Polymerization Renewable and Green Energy Scanning electron microscopy Temperature dependence |
| title | Electrochemical polymerization of alizarin and the electrochemical properties of poly(alizarin) |
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