A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B
Molybdenum disulfide (MoS2) nanoflowers synthesized by a hydrothermal route were successfully grafted on a melamine-formaldehyde sponge through a facile dip-coating method to form MoS2 nanoflowers sponges. The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B...
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Veröffentlicht in: | Inorganic chemistry frontiers 2018-04, Vol.5 (4), p.827-834 |
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description | Molybdenum disulfide (MoS2) nanoflowers synthesized by a hydrothermal route were successfully grafted on a melamine-formaldehyde sponge through a facile dip-coating method to form MoS2 nanoflowers sponges. The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B (RhB), with a maximum adsorption capacity of 104.78 mg RhB g−1 product (equal to 213.84 mg RhB g−1 MoS2 by conversion) within 60 min, which was primarily attributed to the strong electrostatic interactions between electronegative MoS2 nanoflowers and positively charged RhB molecules. The equilibrium adsorption and kinetics data fitted well with the Sips isotherm model and the pseudo-second-order kinetic model, respectively. The recyclability experiments showed that the MoS2 sponge adsorbent could be reused for 10 times with above 86.7% of the adsorption capacity retained. More remarkably, the as-prepared sponge adsorbent can be separated from the dye solution easily through a simple salvage instead of any tedious centrifugation or filtration processes. Thus, the separable MoS2 sponge adsorbent with remarkable adsorption capacity and excellent reusability for organic dyes shows promise for large scale water remediation in the future. |
doi_str_mv | 10.1039/c8qi00012c |
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The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B (RhB), with a maximum adsorption capacity of 104.78 mg RhB g−1 product (equal to 213.84 mg RhB g−1 MoS2 by conversion) within 60 min, which was primarily attributed to the strong electrostatic interactions between electronegative MoS2 nanoflowers and positively charged RhB molecules. The equilibrium adsorption and kinetics data fitted well with the Sips isotherm model and the pseudo-second-order kinetic model, respectively. The recyclability experiments showed that the MoS2 sponge adsorbent could be reused for 10 times with above 86.7% of the adsorption capacity retained. More remarkably, the as-prepared sponge adsorbent can be separated from the dye solution easily through a simple salvage instead of any tedious centrifugation or filtration processes. Thus, the separable MoS2 sponge adsorbent with remarkable adsorption capacity and excellent reusability for organic dyes shows promise for large scale water remediation in the future.</description><identifier>ISSN: 2052-1545</identifier><identifier>EISSN: 2052-1553</identifier><identifier>DOI: 10.1039/c8qi00012c</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Adsorbents ; Adsorption ; Cationic dyes ; Dip coatings ; Electronegativity ; Immersion coating ; Inorganic chemistry ; Melamine ; Molybdenum disulfide ; Recyclability ; Rhodamine ; Salvage ; Sponges</subject><ispartof>Inorganic chemistry frontiers, 2018-04, Vol.5 (4), p.827-834</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Fang, Yueyun</creatorcontrib><creatorcontrib>Huang, Qizhang</creatorcontrib><creatorcontrib>Liu, Pengyi</creatorcontrib><creatorcontrib>Shi, Jifu</creatorcontrib><creatorcontrib>Xu, Gang</creatorcontrib><title>A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B</title><title>Inorganic chemistry frontiers</title><description>Molybdenum disulfide (MoS2) nanoflowers synthesized by a hydrothermal route were successfully grafted on a melamine-formaldehyde sponge through a facile dip-coating method to form MoS2 nanoflowers sponges. The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B (RhB), with a maximum adsorption capacity of 104.78 mg RhB g−1 product (equal to 213.84 mg RhB g−1 MoS2 by conversion) within 60 min, which was primarily attributed to the strong electrostatic interactions between electronegative MoS2 nanoflowers and positively charged RhB molecules. The equilibrium adsorption and kinetics data fitted well with the Sips isotherm model and the pseudo-second-order kinetic model, respectively. The recyclability experiments showed that the MoS2 sponge adsorbent could be reused for 10 times with above 86.7% of the adsorption capacity retained. More remarkably, the as-prepared sponge adsorbent can be separated from the dye solution easily through a simple salvage instead of any tedious centrifugation or filtration processes. Thus, the separable MoS2 sponge adsorbent with remarkable adsorption capacity and excellent reusability for organic dyes shows promise for large scale water remediation in the future.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Cationic dyes</subject><subject>Dip coatings</subject><subject>Electronegativity</subject><subject>Immersion coating</subject><subject>Inorganic chemistry</subject><subject>Melamine</subject><subject>Molybdenum disulfide</subject><subject>Recyclability</subject><subject>Rhodamine</subject><subject>Salvage</subject><subject>Sponges</subject><issn>2052-1545</issn><issn>2052-1553</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9jctOwzAQRS0EElXphi-wxDowduLUXpaKl1SExGNd-TFOjNo4tVM-ge8mLYjVzNw791xCLhlcMyjVjZW7AACM2xMy4SB4wYQoT__3SpyTWc7BwCiAYjCfkO8F9dqGDVIX-sJGPYSuoVsc2uioj4kOLdI-Ya_TaMWORk_z8TJj5jm-cZr72DWYqe7c4Tsk2oamLdD7YAN2A9Uux9Qf0wZb_RViygfO69iht6FDentBzrzeZJz9zSn5uL97Xz4Wq5eHp-ViVfRMlkOBYCwqy9DPJdOmBqkqMOCFEarUtTRguXSSVU5bKYStVC1d5ZGpSmnroJySq19un-Juj3lYf8Z96sbKNQdeQ1lLWZU_ejRlHg</recordid><startdate>20180401</startdate><enddate>20180401</enddate><creator>Fang, Yueyun</creator><creator>Huang, Qizhang</creator><creator>Liu, Pengyi</creator><creator>Shi, Jifu</creator><creator>Xu, Gang</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20180401</creationdate><title>A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B</title><author>Fang, Yueyun ; Huang, Qizhang ; Liu, Pengyi ; Shi, Jifu ; Xu, Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p183t-e0bce9c1ef781ab608940b0f5b593a68b0c28d814dac855c4968d4fe1949acd03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Cationic dyes</topic><topic>Dip coatings</topic><topic>Electronegativity</topic><topic>Immersion coating</topic><topic>Inorganic chemistry</topic><topic>Melamine</topic><topic>Molybdenum disulfide</topic><topic>Recyclability</topic><topic>Rhodamine</topic><topic>Salvage</topic><topic>Sponges</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fang, Yueyun</creatorcontrib><creatorcontrib>Huang, Qizhang</creatorcontrib><creatorcontrib>Liu, Pengyi</creatorcontrib><creatorcontrib>Shi, Jifu</creatorcontrib><creatorcontrib>Xu, Gang</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Inorganic chemistry frontiers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fang, Yueyun</au><au>Huang, Qizhang</au><au>Liu, Pengyi</au><au>Shi, Jifu</au><au>Xu, Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B</atitle><jtitle>Inorganic chemistry frontiers</jtitle><date>2018-04-01</date><risdate>2018</risdate><volume>5</volume><issue>4</issue><spage>827</spage><epage>834</epage><pages>827-834</pages><issn>2052-1545</issn><eissn>2052-1553</eissn><abstract>Molybdenum disulfide (MoS2) nanoflowers synthesized by a hydrothermal route were successfully grafted on a melamine-formaldehyde sponge through a facile dip-coating method to form MoS2 nanoflowers sponges. The MoS2 sponges exhibited high-efficient adsorption performance to cationic dye, Rhodamine B (RhB), with a maximum adsorption capacity of 104.78 mg RhB g−1 product (equal to 213.84 mg RhB g−1 MoS2 by conversion) within 60 min, which was primarily attributed to the strong electrostatic interactions between electronegative MoS2 nanoflowers and positively charged RhB molecules. The equilibrium adsorption and kinetics data fitted well with the Sips isotherm model and the pseudo-second-order kinetic model, respectively. The recyclability experiments showed that the MoS2 sponge adsorbent could be reused for 10 times with above 86.7% of the adsorption capacity retained. More remarkably, the as-prepared sponge adsorbent can be separated from the dye solution easily through a simple salvage instead of any tedious centrifugation or filtration processes. Thus, the separable MoS2 sponge adsorbent with remarkable adsorption capacity and excellent reusability for organic dyes shows promise for large scale water remediation in the future.</abstract><cop>London</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8qi00012c</doi><tpages>8</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008- |
subjects | Adsorbents Adsorption Cationic dyes Dip coatings Electronegativity Immersion coating Inorganic chemistry Melamine Molybdenum disulfide Recyclability Rhodamine Salvage Sponges |
title | A facile dip-coating method for the preparation of separable MoS2 sponges and their high-efficient adsorption behaviors of Rhodamine B |
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