Ultralong Room‐Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State
Polymer‐based room‐temperature‐phosphorescent (RTP) materials are attractive alternatives to low‐molecular‐weight organic RTP compounds because they can form self‐standing transparent films with high thermal stability. However, their RTP lifetimes in air are usually short (
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| Veröffentlicht in: | Advanced functional materials 2018-04, Vol.28 (16), p.n/a |
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| container_title | Advanced functional materials |
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| creator | Ogoshi, Tomoki Tsuchida, Hiromu Kakuta, Takahiro Yamagishi, Tada‐aki Taema, Ai Ono, Toshikazu Sugimoto, Manabu Mizuno, Motohiro |
| description | Polymer‐based room‐temperature‐phosphorescent (RTP) materials are attractive alternatives to low‐molecular‐weight organic RTP compounds because they can form self‐standing transparent films with high thermal stability. However, their RTP lifetimes in air are usually short ( |
| doi_str_mv | 10.1002/adfm.201707369 |
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A simple organic amorphous polymer, poly(styrene sulfonic acid), exhibits emission with unexpected ultralong room temperature phosphorescence lifetime in air when it is desiccated. The maximum lifetime is 1.22 s, and the lifetime is able to be tuned by controlling the molecular weight of the polymer and the introduction ratio of sulfonic acid groups into the polymer.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.201707369</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>amorphous polymer ; dry solid state ; Lifetime ; lifetime‐encoding application ; Materials science ; Optoelectronic devices ; Phosphorescence ; poly(styrene sulfonic acid) ; Polymers ; Polystyrene resins ; Room temperature ; room‐temperature‐phosphorescent materials ; Sulfonic acid ; Thermal stability</subject><ispartof>Advanced functional materials, 2018-04, Vol.28 (16), p.n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4239-7278e8b5358c6526dc5d83de16fd6fb0792c27f3806e6f8cf243107de9f32f8c3</citedby><cites>FETCH-LOGICAL-c4239-7278e8b5358c6526dc5d83de16fd6fb0792c27f3806e6f8cf243107de9f32f8c3</cites><orcidid>0000-0002-4464-0347</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.201707369$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.201707369$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Ogoshi, Tomoki</creatorcontrib><creatorcontrib>Tsuchida, Hiromu</creatorcontrib><creatorcontrib>Kakuta, Takahiro</creatorcontrib><creatorcontrib>Yamagishi, Tada‐aki</creatorcontrib><creatorcontrib>Taema, Ai</creatorcontrib><creatorcontrib>Ono, Toshikazu</creatorcontrib><creatorcontrib>Sugimoto, Manabu</creatorcontrib><creatorcontrib>Mizuno, Motohiro</creatorcontrib><title>Ultralong Room‐Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State</title><title>Advanced functional materials</title><description>Polymer‐based room‐temperature‐phosphorescent (RTP) materials are attractive alternatives to low‐molecular‐weight organic RTP compounds because they can form self‐standing transparent films with high thermal stability. However, their RTP lifetimes in air are usually short (<≈0.4 s). Here, the simple organic amorphous polymer, poly(styrene sulfonic acid) (PSS), exhibits an ultralong RTP lifetime in air when desiccated. The maximum lifetime is 1.22 s, which is three times that of previously reported RTP amorphous organic polymers. The lifetime can be controlled by the PSS molecular weight and by the ratio of sulfonic acid groups introduced into the polymer. The dry polymers should enable unprecedented molecular engineering in organic molecule‐based optoelectronic devices because of the self‐standing and thermal stability attributes.
A simple organic amorphous polymer, poly(styrene sulfonic acid), exhibits emission with unexpected ultralong room temperature phosphorescence lifetime in air when it is desiccated. The maximum lifetime is 1.22 s, and the lifetime is able to be tuned by controlling the molecular weight of the polymer and the introduction ratio of sulfonic acid groups into the polymer.</description><subject>amorphous polymer</subject><subject>dry solid state</subject><subject>Lifetime</subject><subject>lifetime‐encoding application</subject><subject>Materials science</subject><subject>Optoelectronic devices</subject><subject>Phosphorescence</subject><subject>poly(styrene sulfonic acid)</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Room temperature</subject><subject>room‐temperature‐phosphorescent materials</subject><subject>Sulfonic acid</subject><subject>Thermal stability</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkM1Kw0AUhQdRsFa3rgfc6CJ1fprJZBlaq0LFYlpwF9LJHZuSZOpMgmQh-Ag-o09iaqUuXZ17L9-5Bw5C55QMKCHsOs10OWCEBiTgIjxAPSqo8Dhh8nA_0-djdOLcmnRYwIc99L4oapsWpnrBT8aUXx-fcyg3YNO6sYBnK-M2K2PBKagUYG1NiaPS2O7YODwzRVuC_dHLuG4tVIDjptCmyhWOVJ5d4bzCUW63Uq8Aj22LY1PkGY7rtIZTdKTTwsHZr_bRYnIzH91508fb-1E09dSQ8dALWCBBLn3uSyV8JjLlZ5JnQIXOhF6SIGSKBZpLIkBoqTQbckqCDELNWbfzPrrY_d1Y89qAq5O1aWzVRSaMMD-kkgnZUYMdpaxxzoJONjYvU9smlCTbipNtxcm-4s4Q7gxveQHtP3QSjScPf95v9FKCKQ</recordid><startdate>20180418</startdate><enddate>20180418</enddate><creator>Ogoshi, Tomoki</creator><creator>Tsuchida, Hiromu</creator><creator>Kakuta, Takahiro</creator><creator>Yamagishi, Tada‐aki</creator><creator>Taema, Ai</creator><creator>Ono, Toshikazu</creator><creator>Sugimoto, Manabu</creator><creator>Mizuno, Motohiro</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-4464-0347</orcidid></search><sort><creationdate>20180418</creationdate><title>Ultralong Room‐Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State</title><author>Ogoshi, Tomoki ; Tsuchida, Hiromu ; Kakuta, Takahiro ; Yamagishi, Tada‐aki ; Taema, Ai ; Ono, Toshikazu ; Sugimoto, Manabu ; Mizuno, Motohiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4239-7278e8b5358c6526dc5d83de16fd6fb0792c27f3806e6f8cf243107de9f32f8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>amorphous polymer</topic><topic>dry solid state</topic><topic>Lifetime</topic><topic>lifetime‐encoding application</topic><topic>Materials science</topic><topic>Optoelectronic devices</topic><topic>Phosphorescence</topic><topic>poly(styrene sulfonic acid)</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Room temperature</topic><topic>room‐temperature‐phosphorescent materials</topic><topic>Sulfonic acid</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ogoshi, Tomoki</creatorcontrib><creatorcontrib>Tsuchida, Hiromu</creatorcontrib><creatorcontrib>Kakuta, Takahiro</creatorcontrib><creatorcontrib>Yamagishi, Tada‐aki</creatorcontrib><creatorcontrib>Taema, Ai</creatorcontrib><creatorcontrib>Ono, Toshikazu</creatorcontrib><creatorcontrib>Sugimoto, Manabu</creatorcontrib><creatorcontrib>Mizuno, Motohiro</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ogoshi, Tomoki</au><au>Tsuchida, Hiromu</au><au>Kakuta, Takahiro</au><au>Yamagishi, Tada‐aki</au><au>Taema, Ai</au><au>Ono, Toshikazu</au><au>Sugimoto, Manabu</au><au>Mizuno, Motohiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultralong Room‐Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State</atitle><jtitle>Advanced functional materials</jtitle><date>2018-04-18</date><risdate>2018</risdate><volume>28</volume><issue>16</issue><epage>n/a</epage><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>Polymer‐based room‐temperature‐phosphorescent (RTP) materials are attractive alternatives to low‐molecular‐weight organic RTP compounds because they can form self‐standing transparent films with high thermal stability. However, their RTP lifetimes in air are usually short (<≈0.4 s). Here, the simple organic amorphous polymer, poly(styrene sulfonic acid) (PSS), exhibits an ultralong RTP lifetime in air when desiccated. The maximum lifetime is 1.22 s, which is three times that of previously reported RTP amorphous organic polymers. The lifetime can be controlled by the PSS molecular weight and by the ratio of sulfonic acid groups introduced into the polymer. The dry polymers should enable unprecedented molecular engineering in organic molecule‐based optoelectronic devices because of the self‐standing and thermal stability attributes.
A simple organic amorphous polymer, poly(styrene sulfonic acid), exhibits emission with unexpected ultralong room temperature phosphorescence lifetime in air when it is desiccated. The maximum lifetime is 1.22 s, and the lifetime is able to be tuned by controlling the molecular weight of the polymer and the introduction ratio of sulfonic acid groups into the polymer.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.201707369</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-4464-0347</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | amorphous polymer dry solid state Lifetime lifetime‐encoding application Materials science Optoelectronic devices Phosphorescence poly(styrene sulfonic acid) Polymers Polystyrene resins Room temperature room‐temperature‐phosphorescent materials Sulfonic acid Thermal stability |
| title | Ultralong Room‐Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State |
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