A Multifunctional Pincer Ligand for Cobalt‐Promoted Oxidation by N2O

The divalent cobalt complex of the diprotic pincer ligand bis‐pyrazolylpyridine, (H2L)CoCl2, is dehydrohalogenated twice by LiN(SiMe3)2 in the presence of PEt3 to give monomeric S=1/2 LCo(PEt3)2 (1), fully characterized in the solid‐state and solution as a square pyramidal monomer with a long axial...

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Veröffentlicht in:	Chemistry : a European journal 2018-04, Vol.24 (22), p.5962-5966
Hauptverfasser:	Cook, Brian J., Chen, Chun‐Hsing, Caulton, Kenneth G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Cobalt Cobalt compounds Heavy metals homogeneous catalysis Intermediates Ligands nitrogen oxides Nitrous oxide Oxidation Phosphine Phosphine oxide pincer ligands Transition metals
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