Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer
An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p -formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m 2 g −1 . Th...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2018, Vol.6 (15), p.6455-6462 |
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| container_issue | 15 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
| container_volume | 6 |
| creator | Abdelnaby, Mahmoud M. Alloush, Ahmed M. Qasem, Naef A. A. Al-Maythalony, Bassem A. Mansour, Rached B. Cordova, Kyle E. Al Hamouz, Othman Charles S. |
| description | An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with
p
-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m
2
g
−1
. The high concentration of amines (–NH– and –NH
2
) within the backbone of the polymer result in exceptional selectivity (141) for CO
2
over N
2
and dynamic capacity (15.1 cm
3
g
−1
) in the presence of water (20 : 80 v/v CO
2
: N
2
, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture. |
| doi_str_mv | 10.1039/C8TA00012C |
| format | Article |
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p
-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m
2
g
−1
. The high concentration of amines (–NH– and –NH
2
) within the backbone of the polymer result in exceptional selectivity (141) for CO
2
over N
2
and dynamic capacity (15.1 cm
3
g
−1
) in the presence of water (20 : 80 v/v CO
2
: N
2
, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/C8TA00012C</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Amines ; Carbon dioxide ; Carbon sequestration ; Chemical synthesis ; Crosslinking ; Hydrochloric acid ; Organic materials ; Polymers ; Porous materials ; Recyclability ; Relative humidity ; Selectivity</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2018, Vol.6 (15), p.6455-6462</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-9029fe948a0f0c820a6fcf1d124b8dee3ec072d31542b1abf98486c3d2c98b3e3</citedby><cites>FETCH-LOGICAL-c337t-9029fe948a0f0c820a6fcf1d124b8dee3ec072d31542b1abf98486c3d2c98b3e3</cites><orcidid>0000-0002-4988-0497 ; 0000-0003-1885-6934 ; 0000-0002-3641-3996</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4009,27902,27903,27904</link.rule.ids></links><search><creatorcontrib>Abdelnaby, Mahmoud M.</creatorcontrib><creatorcontrib>Alloush, Ahmed M.</creatorcontrib><creatorcontrib>Qasem, Naef A. A.</creatorcontrib><creatorcontrib>Al-Maythalony, Bassem A.</creatorcontrib><creatorcontrib>Mansour, Rached B.</creatorcontrib><creatorcontrib>Cordova, Kyle E.</creatorcontrib><creatorcontrib>Al Hamouz, Othman Charles S.</creatorcontrib><title>Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with
p
-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m
2
g
−1
. The high concentration of amines (–NH– and –NH
2
) within the backbone of the polymer result in exceptional selectivity (141) for CO
2
over N
2
and dynamic capacity (15.1 cm
3
g
−1
) in the presence of water (20 : 80 v/v CO
2
: N
2
, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.</description><subject>Amines</subject><subject>Carbon dioxide</subject><subject>Carbon sequestration</subject><subject>Chemical synthesis</subject><subject>Crosslinking</subject><subject>Hydrochloric acid</subject><subject>Organic materials</subject><subject>Polymers</subject><subject>Porous materials</subject><subject>Recyclability</subject><subject>Relative humidity</subject><subject>Selectivity</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LAzEYhIMoWGov_oKAN2H1TbIfybEsaoWCl3oTlny8wa3tZk120f57Vyt6mjk8zAxDyCWDGwZC3dZyswQAxusTMuNQQFblqjz981Kek0VK24kBCVAqNSMvtY4mdNS14bN1SK3uhzEibTs6vCLtIybsLNLg6YceMFJzoLqjet92mBmd0FEbQ0q7tnubfB9iGNMku8Me4wU583qXcPGrc_J8f7epV9n66eGxXq4zK0Q1ZAq48qhyqcGDlRx06a1njvHcSIco0ELFnWBFzg3TxiuZy9IKx62SRqCYk6tjbh_D-4hpaLZhjN1U2XDghVRVAcVEXR-pn8ERfdPHdq_joWHQfB_Y_B8ovgD6sWLi</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Abdelnaby, Mahmoud M.</creator><creator>Alloush, Ahmed M.</creator><creator>Qasem, Naef A. A.</creator><creator>Al-Maythalony, Bassem A.</creator><creator>Mansour, Rached B.</creator><creator>Cordova, Kyle E.</creator><creator>Al Hamouz, Othman Charles S.</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-4988-0497</orcidid><orcidid>https://orcid.org/0000-0003-1885-6934</orcidid><orcidid>https://orcid.org/0000-0002-3641-3996</orcidid></search><sort><creationdate>2018</creationdate><title>Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer</title><author>Abdelnaby, Mahmoud M. ; Alloush, Ahmed M. ; Qasem, Naef A. A. ; Al-Maythalony, Bassem A. ; Mansour, Rached B. ; Cordova, Kyle E. ; Al Hamouz, Othman Charles S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-9029fe948a0f0c820a6fcf1d124b8dee3ec072d31542b1abf98486c3d2c98b3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Amines</topic><topic>Carbon dioxide</topic><topic>Carbon sequestration</topic><topic>Chemical synthesis</topic><topic>Crosslinking</topic><topic>Hydrochloric acid</topic><topic>Organic materials</topic><topic>Polymers</topic><topic>Porous materials</topic><topic>Recyclability</topic><topic>Relative humidity</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdelnaby, Mahmoud M.</creatorcontrib><creatorcontrib>Alloush, Ahmed M.</creatorcontrib><creatorcontrib>Qasem, Naef A. A.</creatorcontrib><creatorcontrib>Al-Maythalony, Bassem A.</creatorcontrib><creatorcontrib>Mansour, Rached B.</creatorcontrib><creatorcontrib>Cordova, Kyle E.</creatorcontrib><creatorcontrib>Al Hamouz, Othman Charles S.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdelnaby, Mahmoud M.</au><au>Alloush, Ahmed M.</au><au>Qasem, Naef A. A.</au><au>Al-Maythalony, Bassem A.</au><au>Mansour, Rached B.</au><au>Cordova, Kyle E.</au><au>Al Hamouz, Othman Charles S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2018</date><risdate>2018</risdate><volume>6</volume><issue>15</issue><spage>6455</spage><epage>6462</epage><pages>6455-6462</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with
p
-formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m
2
g
−1
. The high concentration of amines (–NH– and –NH
2
) within the backbone of the polymer result in exceptional selectivity (141) for CO
2
over N
2
and dynamic capacity (15.1 cm
3
g
−1
) in the presence of water (20 : 80 v/v CO
2
: N
2
, 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C8TA00012C</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-4988-0497</orcidid><orcidid>https://orcid.org/0000-0003-1885-6934</orcidid><orcidid>https://orcid.org/0000-0002-3641-3996</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2018, Vol.6 (15), p.6455-6462 |
| issn | 2050-7488 2050-7496 |
| language | eng |
| recordid | cdi_proquest_journals_2025897505 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Amines Carbon dioxide Carbon sequestration Chemical synthesis Crosslinking Hydrochloric acid Organic materials Polymers Porous materials Recyclability Relative humidity Selectivity |
| title | Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymer |
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