Single Crystal of New Nanostructure Self-Assembled Copper–Cyanide and Hexamethylenetetramine as an Efficient Supramolecular Coordination Polymer Catalyst
Yellow prismatic nanoparticles of the supramolecular coordination polymer (SCP) [Cu 6 (CN) 7 (C 6 H 12 N 4 ) 2 (OH 3 )], 1 were obtained by the reaction of K 3 [Cu(CN) 4 ] and hexamethylenetetramine (hmt) in presence of Me 3 SnCl at ambient conditions. The X-ray structure of 1 consists of many rhomb...
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Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2018-05, Vol.28 (3), p.1136-1148 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | Yellow prismatic nanoparticles of the supramolecular coordination polymer (SCP) [Cu
6
(CN)
7
(C
6
H
12
N
4
)
2
(OH
3
)],
1
were obtained by the reaction of K
3
[Cu(CN)
4
] and hexamethylenetetramine (hmt) in presence of Me
3
SnCl at ambient conditions. The X-ray structure of
1
consists of many rhombic [(Cu)
2
µ
3
–(CN)
2
] motifs which construct eight fused cyclic rings accommodating two hmt ligands. The copper atoms exhibit pseudo-tetrahedral configuration. The cyanide ligands create the bifurcated µ
3
-CN bridges. The [(Cu)
2
µ
3
–(CN)
2
] motifs causes expansion of the structure of
1
to three dimensions while extensive H-bonds play an essential role in packing structure. SCP
1
was used as an efficient heterogeneous catalyst for oxidative mineralization of acid blue-92 (AB-92), textile dye, with H
2
O
2
. The study aimed to investigate the efficiency of recycled the catalyst
1
and the mechanism of degradation of AB-92. The morphological feature of the SCP
1
as a catalyst before and after catalysis was examined by high resolution transmission electron microscope (TEM). |
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ISSN: | 1574-1443 1574-1451 |
DOI: | 10.1007/s10904-017-0749-8 |