Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different
The synthesis, structural aspects, thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi( iii ) and Sb( iii ) halide complexes based on a pyrazolium cation with the formulas (C 3 N 2 H 5 )[BiCl 4 ]·H 2 O and (C 3 N 2 H 5 )[SbCl 4 ]·H 2 O, are presented. The former com...
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| Veröffentlicht in: | CrystEngComm 2018, Vol.20 (15), p.2112-2119 |
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| container_title | CrystEngComm |
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| creator | Piecha-Bisiorek, Anna Mencel, Klaudia Kinzhybalo, Vasyl Szota, Aleksandra Jakubas, Ryszard Medycki, Wojciech Zawrocki, Wiktor |
| description | The synthesis, structural aspects, thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi(
iii
) and Sb(
iii
) halide complexes based on a pyrazolium cation with the formulas (C
3
N
2
H
5
)[BiCl
4
]·H
2
O and (C
3
N
2
H
5
)[SbCl
4
]·H
2
O, are presented. The former compound was found to undergo a ferroic phase transition of the ferroelastic type at 213/219 K (cooling/heating scans), whereas, the latter one exhibited a piezoelectric feature in the dielectric response function. The molecular motions of pyrazolium cations were analyzed based on the spin–lattice relaxation time of
1
H NMR measurements. |
| doi_str_mv | 10.1039/C8CE00140E |
| format | Article |
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iii
) and Sb(
iii
) halide complexes based on a pyrazolium cation with the formulas (C
3
N
2
H
5
)[BiCl
4
]·H
2
O and (C
3
N
2
H
5
)[SbCl
4
]·H
2
O, are presented. The former compound was found to undergo a ferroic phase transition of the ferroelastic type at 213/219 K (cooling/heating scans), whereas, the latter one exhibited a piezoelectric feature in the dielectric response function. The molecular motions of pyrazolium cations were analyzed based on the spin–lattice relaxation time of
1
H NMR measurements.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/C8CE00140E</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Antimony ; Bismuth ; Cations ; Dielectric properties ; Ferroelasticity ; NMR ; Nuclear magnetic resonance ; Phase transitions ; Piezoelectricity ; Relaxation time ; Response functions ; Thermal analysis</subject><ispartof>CrystEngComm, 2018, Vol.20 (15), p.2112-2119</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-2cd8372de0281af884dc4f8d330f060e3c6a329483bae2b4d83871b91ebe84d83</citedby><cites>FETCH-LOGICAL-c259t-2cd8372de0281af884dc4f8d330f060e3c6a329483bae2b4d83871b91ebe84d83</cites><orcidid>0000-0002-0314-4478 ; 0000-0003-1060-0459 ; 0000-0002-8134-8740</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Piecha-Bisiorek, Anna</creatorcontrib><creatorcontrib>Mencel, Klaudia</creatorcontrib><creatorcontrib>Kinzhybalo, Vasyl</creatorcontrib><creatorcontrib>Szota, Aleksandra</creatorcontrib><creatorcontrib>Jakubas, Ryszard</creatorcontrib><creatorcontrib>Medycki, Wojciech</creatorcontrib><creatorcontrib>Zawrocki, Wiktor</creatorcontrib><title>Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different</title><title>CrystEngComm</title><description>The synthesis, structural aspects, thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi(
iii
) and Sb(
iii
) halide complexes based on a pyrazolium cation with the formulas (C
3
N
2
H
5
)[BiCl
4
]·H
2
O and (C
3
N
2
H
5
)[SbCl
4
]·H
2
O, are presented. The former compound was found to undergo a ferroic phase transition of the ferroelastic type at 213/219 K (cooling/heating scans), whereas, the latter one exhibited a piezoelectric feature in the dielectric response function. The molecular motions of pyrazolium cations were analyzed based on the spin–lattice relaxation time of
1
H NMR measurements.</description><subject>Antimony</subject><subject>Bismuth</subject><subject>Cations</subject><subject>Dielectric properties</subject><subject>Ferroelasticity</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phase transitions</subject><subject>Piezoelectricity</subject><subject>Relaxation time</subject><subject>Response functions</subject><subject>Thermal analysis</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNkN1KwzAYhoMoOKcnXkHAM7Gan65LPZOyqTDwRI9Lmnx1GW0zkxSpR97D7tArMWUDPXp_eHj5-BC6pOSWEp7fFaJYEEJTsjhCE5pmWSII58f__Ck6834zMpSSCdotwTkLjfTBKBMGLDuNtwa-YgcquH1pa2zdu-yM-vneme7g8XqonNG4lQGckY3HnyasscS2g0SbFjpvbCebuBk18j64XoXewT32FnvTmka6GzxAGLM2dQ0OunCOTuq4BhcHnaK35eK1eEpWL4_PxcMqUWyWh4QpLficaSBMUFkLkWqV1kJzTmqSEeAqk5zlqeCVBFalkRZzWuUUKhBjmqKr_e7W2Y8efCg3tnfxYF8ywmacZYLPInW9p5Sz3juoy60zrXRDSUk5Pr38ezr_BYoXeIg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Piecha-Bisiorek, Anna</creator><creator>Mencel, Klaudia</creator><creator>Kinzhybalo, Vasyl</creator><creator>Szota, Aleksandra</creator><creator>Jakubas, Ryszard</creator><creator>Medycki, Wojciech</creator><creator>Zawrocki, Wiktor</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-0314-4478</orcidid><orcidid>https://orcid.org/0000-0003-1060-0459</orcidid><orcidid>https://orcid.org/0000-0002-8134-8740</orcidid></search><sort><creationdate>2018</creationdate><title>Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different</title><author>Piecha-Bisiorek, Anna ; Mencel, Klaudia ; Kinzhybalo, Vasyl ; Szota, Aleksandra ; Jakubas, Ryszard ; Medycki, Wojciech ; Zawrocki, Wiktor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-2cd8372de0281af884dc4f8d330f060e3c6a329483bae2b4d83871b91ebe84d83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antimony</topic><topic>Bismuth</topic><topic>Cations</topic><topic>Dielectric properties</topic><topic>Ferroelasticity</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phase transitions</topic><topic>Piezoelectricity</topic><topic>Relaxation time</topic><topic>Response functions</topic><topic>Thermal analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Piecha-Bisiorek, Anna</creatorcontrib><creatorcontrib>Mencel, Klaudia</creatorcontrib><creatorcontrib>Kinzhybalo, Vasyl</creatorcontrib><creatorcontrib>Szota, Aleksandra</creatorcontrib><creatorcontrib>Jakubas, Ryszard</creatorcontrib><creatorcontrib>Medycki, Wojciech</creatorcontrib><creatorcontrib>Zawrocki, Wiktor</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Piecha-Bisiorek, Anna</au><au>Mencel, Klaudia</au><au>Kinzhybalo, Vasyl</au><au>Szota, Aleksandra</au><au>Jakubas, Ryszard</au><au>Medycki, Wojciech</au><au>Zawrocki, Wiktor</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different</atitle><jtitle>CrystEngComm</jtitle><date>2018</date><risdate>2018</risdate><volume>20</volume><issue>15</issue><spage>2112</spage><epage>2119</epage><pages>2112-2119</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The synthesis, structural aspects, thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi(
iii
) and Sb(
iii
) halide complexes based on a pyrazolium cation with the formulas (C
3
N
2
H
5
)[BiCl
4
]·H
2
O and (C
3
N
2
H
5
)[SbCl
4
]·H
2
O, are presented. The former compound was found to undergo a ferroic phase transition of the ferroelastic type at 213/219 K (cooling/heating scans), whereas, the latter one exhibited a piezoelectric feature in the dielectric response function. The molecular motions of pyrazolium cations were analyzed based on the spin–lattice relaxation time of
1
H NMR measurements.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C8CE00140E</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-0314-4478</orcidid><orcidid>https://orcid.org/0000-0003-1060-0459</orcidid><orcidid>https://orcid.org/0000-0002-8134-8740</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018, Vol.20 (15), p.2112-2119 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_journals_2025326835 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Antimony Bismuth Cations Dielectric properties Ferroelasticity NMR Nuclear magnetic resonance Phase transitions Piezoelectricity Relaxation time Response functions Thermal analysis |
| title | Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different |
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