Simultaneous production of biocrude oil and recovery of nutrients and metals from human feces via hydrothermal liquefaction

[Display omitted] •Fast degradation of human waste and energy recovery via hydrothermal liquefaction.•Biocrude, nutrients and metals in human waste are physically separated via HTL.•Max. liquefied fraction was 87.89%, and highest biocrude yield was 34.44%•HTL is promising for treatment from human wa...

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Veröffentlicht in:Energy conversion and management 2017-02, Vol.134, p.340-346
Hauptverfasser: Lu, Jianwen, Zhang, Jiaren, Zhu, Zhangbing, Zhang, Yuanhui, Zhao, Yu, Li, Ruirui, Watson, Jamison, Li, Baoming, Liu, Zhidan
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container_end_page 346
container_issue
container_start_page 340
container_title Energy conversion and management
container_volume 134
creator Lu, Jianwen
Zhang, Jiaren
Zhu, Zhangbing
Zhang, Yuanhui
Zhao, Yu
Li, Ruirui
Watson, Jamison
Li, Baoming
Liu, Zhidan
description [Display omitted] •Fast degradation of human waste and energy recovery via hydrothermal liquefaction.•Biocrude, nutrients and metals in human waste are physically separated via HTL.•Max. liquefied fraction was 87.89%, and highest biocrude yield was 34.44%•HTL is promising for treatment from human wastes, and other wet biowastes. Hydrothermal liquefaction (HTL) is a thermochemical process specifically suitable for treating wet wastes. This study investigated its potential for the production of biocrude oil and the recovery of nutrients and metals from human feces via HTL. Specifically, the effects of temperature (260°C, 300°C, 340°C), retention time (10min, 30min, 50min) and total solid (TS) content (5%, 15%, 25%) were studied. The maximum liquefied fraction was 87.89% and the highest biocrude yield reached 34.44% with a higher heating value of 40.29MJ/kg. Experimental results showed that 54% of carbon in the human feces was migrated to the biocrude oil while 72% of nitrogen was released to the aqueous phase. In addition, most of heavy and alkaline-earth metal elements in the human feces, including Ca (89%), Mg (81%), Al (88%), Fe (72%) and Zn (94%) were distributed in the solid residue, whereas K (89%) and Na (73%) were mainly dissolved into the aqueous phase. This study demonstrated that the efficient degradation of human waste via HTL without any pretreatment and its potential for the valorization in biocrude oil as well as separated nutrients and metals.
doi_str_mv 10.1016/j.enconman.2016.12.052
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Hydrothermal liquefaction (HTL) is a thermochemical process specifically suitable for treating wet wastes. This study investigated its potential for the production of biocrude oil and the recovery of nutrients and metals from human feces via HTL. Specifically, the effects of temperature (260°C, 300°C, 340°C), retention time (10min, 30min, 50min) and total solid (TS) content (5%, 15%, 25%) were studied. The maximum liquefied fraction was 87.89% and the highest biocrude yield reached 34.44% with a higher heating value of 40.29MJ/kg. Experimental results showed that 54% of carbon in the human feces was migrated to the biocrude oil while 72% of nitrogen was released to the aqueous phase. In addition, most of heavy and alkaline-earth metal elements in the human feces, including Ca (89%), Mg (81%), Al (88%), Fe (72%) and Zn (94%) were distributed in the solid residue, whereas K (89%) and Na (73%) were mainly dissolved into the aqueous phase. This study demonstrated that the efficient degradation of human waste via HTL without any pretreatment and its potential for the valorization in biocrude oil as well as separated nutrients and metals.</description><identifier>ISSN: 0196-8904</identifier><identifier>EISSN: 1879-2227</identifier><identifier>DOI: 10.1016/j.enconman.2016.12.052</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Alkaline earth metals ; Aluminum ; Biocrude oil ; Calcium ; Calorific value ; Carbon ; Feces ; Human feces ; Human wastes ; Hydrothermal liquefaction ; Iron ; Liquefaction ; Materials recovery ; Metal distribution ; Metals ; Nutrients ; Oil wastes ; Pretreatment ; Retention time ; Temperature effects ; Waste treatment ; Zinc</subject><ispartof>Energy conversion and management, 2017-02, Vol.134, p.340-346</ispartof><rights>2016 Elsevier Ltd</rights><rights>Copyright Elsevier Science Ltd. 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Hydrothermal liquefaction (HTL) is a thermochemical process specifically suitable for treating wet wastes. This study investigated its potential for the production of biocrude oil and the recovery of nutrients and metals from human feces via HTL. Specifically, the effects of temperature (260°C, 300°C, 340°C), retention time (10min, 30min, 50min) and total solid (TS) content (5%, 15%, 25%) were studied. The maximum liquefied fraction was 87.89% and the highest biocrude yield reached 34.44% with a higher heating value of 40.29MJ/kg. Experimental results showed that 54% of carbon in the human feces was migrated to the biocrude oil while 72% of nitrogen was released to the aqueous phase. In addition, most of heavy and alkaline-earth metal elements in the human feces, including Ca (89%), Mg (81%), Al (88%), Fe (72%) and Zn (94%) were distributed in the solid residue, whereas K (89%) and Na (73%) were mainly dissolved into the aqueous phase. 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subjects Alkaline earth metals
Aluminum
Biocrude oil
Calcium
Calorific value
Carbon
Feces
Human feces
Human wastes
Hydrothermal liquefaction
Iron
Liquefaction
Materials recovery
Metal distribution
Metals
Nutrients
Oil wastes
Pretreatment
Retention time
Temperature effects
Waste treatment
Zinc
title Simultaneous production of biocrude oil and recovery of nutrients and metals from human feces via hydrothermal liquefaction
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