Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix

Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750...

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Veröffentlicht in:Russian journal of applied chemistry 2017-12, Vol.90 (12), p.1969-1973
Hauptverfasser: Raiskaya, E. A., Saveleva, G. G., Drozdov, V. A., Belskaya, O. B.
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container_end_page 1973
container_issue 12
container_start_page 1969
container_title Russian journal of applied chemistry
container_volume 90
creator Raiskaya, E. A.
Saveleva, G. G.
Drozdov, V. A.
Belskaya, O. B.
description Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (S BET ) lower than 5 m2 g –1 at the adsorption capacity for СО 2 higher than 1 mmol g –1 for both samples were found.
doi_str_mv 10.1134/S1070427217120114
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subjects Adsorption
Carbon
Carbon dioxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Densification
Deposition
Fluidized bed reactors
Fluidized beds
Industrial Chemistry/Chemical Engineering
Production of New Materials
Pyrolysis
title Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix
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