Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix
Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750...
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Veröffentlicht in: | Russian journal of applied chemistry 2017-12, Vol.90 (12), p.1969-1973 |
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container_end_page | 1973 |
---|---|
container_issue | 12 |
container_start_page | 1969 |
container_title | Russian journal of applied chemistry |
container_volume | 90 |
creator | Raiskaya, E. A. Saveleva, G. G. Drozdov, V. A. Belskaya, O. B. |
description | Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (S
BET
) lower than 5 m2 g
–1
at the adsorption capacity for СО
2
higher than 1 mmol g
–1
for both samples were found. |
doi_str_mv | 10.1134/S1070427217120114 |
format | Article |
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BET
) lower than 5 m2 g
–1
at the adsorption capacity for СО
2
higher than 1 mmol g
–1
for both samples were found.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427217120114</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Carbon ; Carbon dioxide ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Densification ; Deposition ; Fluidized bed reactors ; Fluidized beds ; Industrial Chemistry/Chemical Engineering ; Production of New Materials ; Pyrolysis</subject><ispartof>Russian journal of applied chemistry, 2017-12, Vol.90 (12), p.1969-1973</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-594159661d2fd3a6d0fef0e0aefb173f11f5e4650391a7c2c9ab012d369ded053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427217120114$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427217120114$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Raiskaya, E. A.</creatorcontrib><creatorcontrib>Saveleva, G. G.</creatorcontrib><creatorcontrib>Drozdov, V. A.</creatorcontrib><creatorcontrib>Belskaya, O. B.</creatorcontrib><title>Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (S
BET
) lower than 5 m2 g
–1
at the adsorption capacity for СО
2
higher than 1 mmol g
–1
for both samples were found.</description><subject>Adsorption</subject><subject>Carbon</subject><subject>Carbon dioxide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Densification</subject><subject>Deposition</subject><subject>Fluidized bed reactors</subject><subject>Fluidized beds</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Production of New Materials</subject><subject>Pyrolysis</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8Bz9VM0qbbo66uCisu6J5L2iSSpdvUSQvWX2-WVTyIpxlm3veZD0LOgV0CiPTqBVjOUp5zyIEzgPSATECyWSJ4IQ9jHtvJrn9MTkLYMMYKKWcTMqzQdApV73xLvaXrpke1dTX6zqMfAn1SvUGnmkCrkS6awWn3aXRyYzRdjeibsXc1vTWdD-6HMVdYxcy1dOXRhF1J_RQjDt3HKTmyEWnOvuOUrBd3r_OHZPl8_zi_XiY1l7M-yYoUsrgnaG61UFIzaywzTBlbQS4sgM1MKjMmClB5zetCVQy4FrLQRrNMTMnFntuhfx9M6MuNH7CNI0vOuEhFLnkaVbBXxatDQGPLDt1W4VgCK3ffLf98N3r43hOitn0z-Ev-3_QF5Ep8dA</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Raiskaya, E. A.</creator><creator>Saveleva, G. G.</creator><creator>Drozdov, V. A.</creator><creator>Belskaya, O. B.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20171201</creationdate><title>Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix</title><author>Raiskaya, E. A. ; Saveleva, G. G. ; Drozdov, V. A. ; Belskaya, O. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-594159661d2fd3a6d0fef0e0aefb173f11f5e4650391a7c2c9ab012d369ded053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Adsorption</topic><topic>Carbon</topic><topic>Carbon dioxide</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Densification</topic><topic>Deposition</topic><topic>Fluidized bed reactors</topic><topic>Fluidized beds</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Production of New Materials</topic><topic>Pyrolysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Raiskaya, E. A.</creatorcontrib><creatorcontrib>Saveleva, G. G.</creatorcontrib><creatorcontrib>Drozdov, V. A.</creatorcontrib><creatorcontrib>Belskaya, O. B.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Raiskaya, E. A.</au><au>Saveleva, G. G.</au><au>Drozdov, V. A.</au><au>Belskaya, O. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>90</volume><issue>12</issue><spage>1969</spage><epage>1973</epage><pages>1969-1973</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (S
BET
) lower than 5 m2 g
–1
at the adsorption capacity for СО
2
higher than 1 mmol g
–1
for both samples were found.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070427217120114</doi><tpages>5</tpages></addata></record> |
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issn | 1070-4272 1608-3296 |
language | eng |
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source | SpringerNature Journals |
subjects | Adsorption Carbon Carbon dioxide Chemistry Chemistry and Materials Science Chemistry/Food Science Densification Deposition Fluidized bed reactors Fluidized beds Industrial Chemistry/Chemical Engineering Production of New Materials Pyrolysis |
title | Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix |
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