Mathematical Simulating the Biokatalytic Transformation of Methyl Phenyl Sulfide into (R)-Sulfoxide
A mathematical model is proposed for describing the biotransformation of methyl phenyl sulfide to ( R )-methyl phenyl sulfoxide by immobilized Gordonia terrae IEGM 136 cells. Kinetic patterns of the biotransformation of methyl phenyl sulfide are determined using experimental data on the initial conc...
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| Veröffentlicht in: | Catalysis in industry 2018, Vol.10 (1), p.83-90 |
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| container_title | Catalysis in industry |
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| creator | El’kin, A. A. Kylosova, T. I. Osipenko, M. A. Nyashin, Yu. I. Grishko, V. V. Ivshina, I. B. |
| description | A mathematical model is proposed for describing the biotransformation of methyl phenyl sulfide to (
R
)-methyl phenyl sulfoxide by immobilized
Gordonia terrae
IEGM 136 cells. Kinetic patterns of the biotransformation of methyl phenyl sulfide are determined using experimental data on the initial concentration of sulfide and the amount of biocatalyst. The experimental data are compared to simulations of sulfide biotransformation scaling in a laboratory bioreactor. A mathematical model is developed for describing the biotransformation of methyl phenyl sulfide with repeated use of the biocatalyst. The resulting data can be used for optimizing the biotransformation of a wide range of organic aryl alkyl sulfides to optically active sulfoxides. |
| doi_str_mv | 10.1134/S2070050418010051 |
| format | Article |
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R
)-methyl phenyl sulfoxide by immobilized
Gordonia terrae
IEGM 136 cells. Kinetic patterns of the biotransformation of methyl phenyl sulfide are determined using experimental data on the initial concentration of sulfide and the amount of biocatalyst. The experimental data are compared to simulations of sulfide biotransformation scaling in a laboratory bioreactor. A mathematical model is developed for describing the biotransformation of methyl phenyl sulfide with repeated use of the biocatalyst. The resulting data can be used for optimizing the biotransformation of a wide range of organic aryl alkyl sulfides to optically active sulfoxides.</description><identifier>ISSN: 2070-0504</identifier><identifier>EISSN: 2070-0555</identifier><identifier>DOI: 10.1134/S2070050418010051</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aromatic compounds ; Biocatalysis ; Biocatalysts ; Bioreactors ; Biotransformation ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Computer simulation ; Mathematical analysis ; Mathematical models ; Optical activity ; Sulfoxides</subject><ispartof>Catalysis in industry, 2018, Vol.10 (1), p.83-90</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c305t-8273c89746d1ed12613237f9e36f0c982e7ce2cb69befd08b01a1526460199623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S2070050418010051$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S2070050418010051$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>El’kin, A. A.</creatorcontrib><creatorcontrib>Kylosova, T. I.</creatorcontrib><creatorcontrib>Osipenko, M. A.</creatorcontrib><creatorcontrib>Nyashin, Yu. I.</creatorcontrib><creatorcontrib>Grishko, V. V.</creatorcontrib><creatorcontrib>Ivshina, I. B.</creatorcontrib><title>Mathematical Simulating the Biokatalytic Transformation of Methyl Phenyl Sulfide into (R)-Sulfoxide</title><title>Catalysis in industry</title><addtitle>Catal. Ind</addtitle><description>A mathematical model is proposed for describing the biotransformation of methyl phenyl sulfide to (
R
)-methyl phenyl sulfoxide by immobilized
Gordonia terrae
IEGM 136 cells. Kinetic patterns of the biotransformation of methyl phenyl sulfide are determined using experimental data on the initial concentration of sulfide and the amount of biocatalyst. The experimental data are compared to simulations of sulfide biotransformation scaling in a laboratory bioreactor. A mathematical model is developed for describing the biotransformation of methyl phenyl sulfide with repeated use of the biocatalyst. The resulting data can be used for optimizing the biotransformation of a wide range of organic aryl alkyl sulfides to optically active sulfoxides.</description><subject>Aromatic compounds</subject><subject>Biocatalysis</subject><subject>Biocatalysts</subject><subject>Bioreactors</subject><subject>Biotransformation</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Computer simulation</subject><subject>Mathematical analysis</subject><subject>Mathematical models</subject><subject>Optical activity</subject><subject>Sulfoxides</subject><issn>2070-0504</issn><issn>2070-0555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1UMFKAzEUDKJgqf0AbwEvelh9SXazyVGLVaFFsfW8pNmk3brd1GQX7N-bpaIH8V3eMG9mHgxC5wSuCWHpzZxCDpBBSgSQCMgRGvRUAlmWHf9gSE_RKIQNxKFSylwMkJ6pdm22qq20qvG82nZ1xM0KRxbfVe5dtarexyteeNUE63yvdQ12Fs9Mu97X-GVtmrjmXW2r0uCqaR2-fL1KesJ9RuoMnVhVBzP63kP0NrlfjB-T6fPD0_h2mmgGWZsImjMtZJ7ykpiSUE4YZbmVhnELWgpqcm2oXnK5NLYEsQSiSEZ5yoFIySkbootD7s67j86Etti4zjfxZUGBkpwLxkRUkYNKexeCN7bY-Wqr_L4gUPR1Fn_qjB568ISobVbG_yb_b_oCC3V1bg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>El’kin, A. A.</creator><creator>Kylosova, T. I.</creator><creator>Osipenko, M. A.</creator><creator>Nyashin, Yu. I.</creator><creator>Grishko, V. V.</creator><creator>Ivshina, I. B.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2018</creationdate><title>Mathematical Simulating the Biokatalytic Transformation of Methyl Phenyl Sulfide into (R)-Sulfoxide</title><author>El’kin, A. A. ; Kylosova, T. I. ; Osipenko, M. A. ; Nyashin, Yu. I. ; Grishko, V. V. ; Ivshina, I. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-8273c89746d1ed12613237f9e36f0c982e7ce2cb69befd08b01a1526460199623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aromatic compounds</topic><topic>Biocatalysis</topic><topic>Biocatalysts</topic><topic>Bioreactors</topic><topic>Biotransformation</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Computer simulation</topic><topic>Mathematical analysis</topic><topic>Mathematical models</topic><topic>Optical activity</topic><topic>Sulfoxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El’kin, A. A.</creatorcontrib><creatorcontrib>Kylosova, T. I.</creatorcontrib><creatorcontrib>Osipenko, M. A.</creatorcontrib><creatorcontrib>Nyashin, Yu. I.</creatorcontrib><creatorcontrib>Grishko, V. V.</creatorcontrib><creatorcontrib>Ivshina, I. B.</creatorcontrib><collection>CrossRef</collection><jtitle>Catalysis in industry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El’kin, A. A.</au><au>Kylosova, T. I.</au><au>Osipenko, M. A.</au><au>Nyashin, Yu. I.</au><au>Grishko, V. V.</au><au>Ivshina, I. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mathematical Simulating the Biokatalytic Transformation of Methyl Phenyl Sulfide into (R)-Sulfoxide</atitle><jtitle>Catalysis in industry</jtitle><stitle>Catal. Ind</stitle><date>2018</date><risdate>2018</risdate><volume>10</volume><issue>1</issue><spage>83</spage><epage>90</epage><pages>83-90</pages><issn>2070-0504</issn><eissn>2070-0555</eissn><abstract>A mathematical model is proposed for describing the biotransformation of methyl phenyl sulfide to (
R
)-methyl phenyl sulfoxide by immobilized
Gordonia terrae
IEGM 136 cells. Kinetic patterns of the biotransformation of methyl phenyl sulfide are determined using experimental data on the initial concentration of sulfide and the amount of biocatalyst. The experimental data are compared to simulations of sulfide biotransformation scaling in a laboratory bioreactor. A mathematical model is developed for describing the biotransformation of methyl phenyl sulfide with repeated use of the biocatalyst. The resulting data can be used for optimizing the biotransformation of a wide range of organic aryl alkyl sulfides to optically active sulfoxides.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S2070050418010051</doi><tpages>8</tpages></addata></record> |
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| subjects | Aromatic compounds Biocatalysis Biocatalysts Bioreactors Biotransformation Catalysis Chemistry Chemistry and Materials Science Computer simulation Mathematical analysis Mathematical models Optical activity Sulfoxides |
| title | Mathematical Simulating the Biokatalytic Transformation of Methyl Phenyl Sulfide into (R)-Sulfoxide |
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