Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform
Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reaction...
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| Veröffentlicht in: | Advanced functional materials 2018-03, Vol.28 (13), p.n/a |
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| container_title | Advanced functional materials |
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| creator | Sun, Dengrong Jang, Seungwook Yim, Se‐Jun Ye, Lin Kim, Dong‐Pyo |
| description | Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reactions in a continuous‐flow microreactor and a batch system, indicating the great potential of the metal doped MOFs@COFs as a multifunctional platform for photocatalysis. Explanations for the performance enhancement are elucidated. An integrated dual‐chamber microreactor coupled with the metal doped MOFs@COFs is introduced to demonstrate a concept of an intensified green photochemical process, which can be broadly extended to challenging liquid–gas tandem and cascade reactions.
Pd doped core–shell TiATA@LZU1 is fabricated and shows excellent photocatalytic performance for hydrogenation and dehydrogenation reactions in batch and in a newly designed dual‐chamber microreactor. This indicates a great promise of metal–organic frameworks@covalent organic frameworks (MOFs@COFs) hybrids as a novel platform for efficient photocatalysis. |
| doi_str_mv | 10.1002/adfm.201707110 |
| format | Article |
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Pd doped core–shell TiATA@LZU1 is fabricated and shows excellent photocatalytic performance for hydrogenation and dehydrogenation reactions in batch and in a newly designed dual‐chamber microreactor. This indicates a great promise of metal–organic frameworks@covalent organic frameworks (MOFs@COFs) hybrids as a novel platform for efficient photocatalysis.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.201707110</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Cascade chemical reactions ; continuous‐flow microreactors ; core–shell metal–organic frameworks ; covalent organic frameworks ; Dehydrogenation ; Materials science ; Metal-organic frameworks ; Palladium ; Performance enhancement ; Photocatalysis</subject><ispartof>Advanced functional materials, 2018-03, Vol.28 (13), p.n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4200-130966acdb4d7dad676def87cc25acf397d84d8942b3ce3e3ef0d381431c1ea33</citedby><cites>FETCH-LOGICAL-c4200-130966acdb4d7dad676def87cc25acf397d84d8942b3ce3e3ef0d381431c1ea33</cites><orcidid>0000-0002-6804-1955</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.201707110$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.201707110$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids></links><search><creatorcontrib>Sun, Dengrong</creatorcontrib><creatorcontrib>Jang, Seungwook</creatorcontrib><creatorcontrib>Yim, Se‐Jun</creatorcontrib><creatorcontrib>Ye, Lin</creatorcontrib><creatorcontrib>Kim, Dong‐Pyo</creatorcontrib><title>Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform</title><title>Advanced functional materials</title><description>Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reactions in a continuous‐flow microreactor and a batch system, indicating the great potential of the metal doped MOFs@COFs as a multifunctional platform for photocatalysis. Explanations for the performance enhancement are elucidated. An integrated dual‐chamber microreactor coupled with the metal doped MOFs@COFs is introduced to demonstrate a concept of an intensified green photochemical process, which can be broadly extended to challenging liquid–gas tandem and cascade reactions.
Pd doped core–shell TiATA@LZU1 is fabricated and shows excellent photocatalytic performance for hydrogenation and dehydrogenation reactions in batch and in a newly designed dual‐chamber microreactor. This indicates a great promise of metal–organic frameworks@covalent organic frameworks (MOFs@COFs) hybrids as a novel platform for efficient photocatalysis.</description><subject>Cascade chemical reactions</subject><subject>continuous‐flow microreactors</subject><subject>core–shell metal–organic frameworks</subject><subject>covalent organic frameworks</subject><subject>Dehydrogenation</subject><subject>Materials science</subject><subject>Metal-organic frameworks</subject><subject>Palladium</subject><subject>Performance enhancement</subject><subject>Photocatalysis</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLwzAUx4soOKdXzwEveuhMmq5pb0pnnbC5gQreQpakrjNdZtJt9LaTZ8FvuE9i5mQePEgeyYP3-7_Az_NOEWwhCINLJvKyFUBEIEEI7nkNFKHIxzCI93c9ej70jqydQIcRHDa8976smAIdPZMCpNrI9erzYSyVAt-D9epjYF7YtOAgM6yUS21e7VWqF0zJaQX-zsB5f5A5wl0XoFuPTCEsYK7AvV5IBYZjXWnO3Oq6csGhYlWuTXnsHeRMWXny8za9p-zmMe36vcHtXXrd83kYQOgjDJMoYlyMQkEEExGJhMxjwnnQZjzHCRFxKOIkDEaYS-xODgWOUYgRR5Jh3PTOtntnRr_Npa3oRM_N1H1JnbmEOENt6KjWluJGW2tkTmemKJmpKYJ045puXNOdaxdItoFloWT9D02vO1n_N_sFsdSGDg</recordid><startdate>20180328</startdate><enddate>20180328</enddate><creator>Sun, Dengrong</creator><creator>Jang, Seungwook</creator><creator>Yim, Se‐Jun</creator><creator>Ye, Lin</creator><creator>Kim, Dong‐Pyo</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6804-1955</orcidid></search><sort><creationdate>20180328</creationdate><title>Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform</title><author>Sun, Dengrong ; Jang, Seungwook ; Yim, Se‐Jun ; Ye, Lin ; Kim, Dong‐Pyo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4200-130966acdb4d7dad676def87cc25acf397d84d8942b3ce3e3ef0d381431c1ea33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cascade chemical reactions</topic><topic>continuous‐flow microreactors</topic><topic>core–shell metal–organic frameworks</topic><topic>covalent organic frameworks</topic><topic>Dehydrogenation</topic><topic>Materials science</topic><topic>Metal-organic frameworks</topic><topic>Palladium</topic><topic>Performance enhancement</topic><topic>Photocatalysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Dengrong</creatorcontrib><creatorcontrib>Jang, Seungwook</creatorcontrib><creatorcontrib>Yim, Se‐Jun</creatorcontrib><creatorcontrib>Ye, Lin</creatorcontrib><creatorcontrib>Kim, Dong‐Pyo</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Dengrong</au><au>Jang, Seungwook</au><au>Yim, Se‐Jun</au><au>Ye, Lin</au><au>Kim, Dong‐Pyo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform</atitle><jtitle>Advanced functional materials</jtitle><date>2018-03-28</date><risdate>2018</risdate><volume>28</volume><issue>13</issue><epage>n/a</epage><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reactions in a continuous‐flow microreactor and a batch system, indicating the great potential of the metal doped MOFs@COFs as a multifunctional platform for photocatalysis. Explanations for the performance enhancement are elucidated. An integrated dual‐chamber microreactor coupled with the metal doped MOFs@COFs is introduced to demonstrate a concept of an intensified green photochemical process, which can be broadly extended to challenging liquid–gas tandem and cascade reactions.
Pd doped core–shell TiATA@LZU1 is fabricated and shows excellent photocatalytic performance for hydrogenation and dehydrogenation reactions in batch and in a newly designed dual‐chamber microreactor. This indicates a great promise of metal–organic frameworks@covalent organic frameworks (MOFs@COFs) hybrids as a novel platform for efficient photocatalysis.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.201707110</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6804-1955</orcidid></addata></record> |
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| language | eng |
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| subjects | Cascade chemical reactions continuous‐flow microreactors core–shell metal–organic frameworks covalent organic frameworks Dehydrogenation Materials science Metal-organic frameworks Palladium Performance enhancement Photocatalysis |
| title | Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform |
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