Aliphatic-aromatic poly(carbonate-co-ester)s containing biobased furan monomer: Synthesis and thermo-mechanical properties
Aliphatic-aromatic poly(carbonate-co-ester) random copolymers poly(butylene carbonate-co-furandicarboxylate)s (PBCFs) with different composition had been prepared from dimethyl carbonate (DMC), 1,4-butanediol (BD) and bio-based dimethyl furan-2,5-dicarboxylate (DMFA) by two-step melt polycondensatio...
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| Veröffentlicht in: | Polymer (Guilford) 2018-01, Vol.134, p.63-70 |
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| creator | Cai, Xiaodong Yang, Xiangui Zhang, Hua Wang, Gongying |
| description | Aliphatic-aromatic poly(carbonate-co-ester) random copolymers poly(butylene carbonate-co-furandicarboxylate)s (PBCFs) with different composition had been prepared from dimethyl carbonate (DMC), 1,4-butanediol (BD) and bio-based dimethyl furan-2,5-dicarboxylate (DMFA) by two-step melt polycondensation method. A series of characterization results can be explained as follows: the varying melting temperature (Tm) and enthalpy (ΔHm) displayed that the copolymers were strongly dependent upon the compositions of butylene carbonate (BC) and butylene furandicarboxylate (BF) units. In addition, glass transition temperature (Tg) noticeably increased with the content of BF units increasing, which agreed with Fox equation; a comparative kinetics research of isothermal crystallization of homopolymer and copolymers with different composition displayed that the existence of BF units could accelerate the crystallization rate of PBC. Furthermore, all of PBCFs exhibited a typical isodimorphic cocrystallization behavior, whose crystal lattice structure shifted from PBC type crystal to PBF type; the thermal stability of PBCFs also expressed to be enhanced during the process of the increasing BF unit content; last but not the least, the mechanical performances could be easily by adjusting the feed components.
Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers. [Display omitted]
•Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers had been synthesized via two-step melt polycondensation method.•Bio-based furan units could significantly influence the thermal transition behavior, thermal stability as well as crystallinity of copolymers.•The mechanical properties of copolymers can be adjusted by changing the feed composition. |
| doi_str_mv | 10.1016/j.polymer.2017.11.058 |
| format | Article |
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Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers. [Display omitted]
•Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers had been synthesized via two-step melt polycondensation method.•Bio-based furan units could significantly influence the thermal transition behavior, thermal stability as well as crystallinity of copolymers.•The mechanical properties of copolymers can be adjusted by changing the feed composition.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2017.11.058</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Aliphatic compounds ; Aliphatic-aromatic copolymers ; Bio-based furanic monomer ; Butanediol ; Chemical synthesis ; Cocrystallization ; Copolymers ; Crystal lattices ; Crystal structure ; Crystallization ; Enthalpy ; Glass transition temperature ; Kinetics ; Mechanical properties ; Melt temperature ; Polycarbonate resins ; Polymers ; Studies ; Thermal stability ; Thermo-mechanical properties ; Thermomechanical properties ; Transition temperatures</subject><ispartof>Polymer (Guilford), 2018-01, Vol.134, p.63-70</ispartof><rights>2017 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jan 3, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c374t-5492d93dbaefbba2557204552d7f67d27a766ad451c15ccb9678ca53a3e6751c3</citedby><cites>FETCH-LOGICAL-c374t-5492d93dbaefbba2557204552d7f67d27a766ad451c15ccb9678ca53a3e6751c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymer.2017.11.058$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Cai, Xiaodong</creatorcontrib><creatorcontrib>Yang, Xiangui</creatorcontrib><creatorcontrib>Zhang, Hua</creatorcontrib><creatorcontrib>Wang, Gongying</creatorcontrib><title>Aliphatic-aromatic poly(carbonate-co-ester)s containing biobased furan monomer: Synthesis and thermo-mechanical properties</title><title>Polymer (Guilford)</title><description>Aliphatic-aromatic poly(carbonate-co-ester) random copolymers poly(butylene carbonate-co-furandicarboxylate)s (PBCFs) with different composition had been prepared from dimethyl carbonate (DMC), 1,4-butanediol (BD) and bio-based dimethyl furan-2,5-dicarboxylate (DMFA) by two-step melt polycondensation method. A series of characterization results can be explained as follows: the varying melting temperature (Tm) and enthalpy (ΔHm) displayed that the copolymers were strongly dependent upon the compositions of butylene carbonate (BC) and butylene furandicarboxylate (BF) units. In addition, glass transition temperature (Tg) noticeably increased with the content of BF units increasing, which agreed with Fox equation; a comparative kinetics research of isothermal crystallization of homopolymer and copolymers with different composition displayed that the existence of BF units could accelerate the crystallization rate of PBC. Furthermore, all of PBCFs exhibited a typical isodimorphic cocrystallization behavior, whose crystal lattice structure shifted from PBC type crystal to PBF type; the thermal stability of PBCFs also expressed to be enhanced during the process of the increasing BF unit content; last but not the least, the mechanical performances could be easily by adjusting the feed components.
Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers. [Display omitted]
•Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers had been synthesized via two-step melt polycondensation method.•Bio-based furan units could significantly influence the thermal transition behavior, thermal stability as well as crystallinity of copolymers.•The mechanical properties of copolymers can be adjusted by changing the feed composition.</description><subject>Aliphatic compounds</subject><subject>Aliphatic-aromatic copolymers</subject><subject>Bio-based furanic monomer</subject><subject>Butanediol</subject><subject>Chemical synthesis</subject><subject>Cocrystallization</subject><subject>Copolymers</subject><subject>Crystal lattices</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Enthalpy</subject><subject>Glass transition temperature</subject><subject>Kinetics</subject><subject>Mechanical properties</subject><subject>Melt temperature</subject><subject>Polycarbonate resins</subject><subject>Polymers</subject><subject>Studies</subject><subject>Thermal stability</subject><subject>Thermo-mechanical properties</subject><subject>Thermomechanical properties</subject><subject>Transition temperatures</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFUE1r3DAQFaWBbpP-hIKgl_YgR5Ity-6lhCVfsJBD0rMYS-OulrXkSt7A9tdHy-be0zxm5r038wj5KngluGivd9Uc98cJUyW50JUQFVfdB7ISna6ZlL34SFac15LVXSs-kc857zjnUslmRf7d7P28hcVbBilOJ0BPat8tpCEGWJDZyDAvmH5kamNYwAcf_tDBxwEyOjoeEgQ6xRDLBT_p8zEsW8w-UwiOFpimyCa0Wwjewp7OKc6YFo_5ilyMsM_45b1ekt93ty_rB7Z5un9c32yYrXWzMNX00vW1GwDHYQCplJa8UUo6PbbaSQ26bcE1SlihrB36VncWVA01tro060vy7axbrP8eyitmFw8pFEtT8uq46EXTli113rIp5pxwNHPyE6SjEdycYjY78x7ziaaNEKbEXHi_zjwsL7z6Ms3WY7DofEK7GBf9fxTeAOjfi-I</recordid><startdate>20180103</startdate><enddate>20180103</enddate><creator>Cai, Xiaodong</creator><creator>Yang, Xiangui</creator><creator>Zhang, Hua</creator><creator>Wang, Gongying</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20180103</creationdate><title>Aliphatic-aromatic poly(carbonate-co-ester)s containing biobased furan monomer: Synthesis and thermo-mechanical properties</title><author>Cai, Xiaodong ; Yang, Xiangui ; Zhang, Hua ; Wang, Gongying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c374t-5492d93dbaefbba2557204552d7f67d27a766ad451c15ccb9678ca53a3e6751c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aliphatic compounds</topic><topic>Aliphatic-aromatic copolymers</topic><topic>Bio-based furanic monomer</topic><topic>Butanediol</topic><topic>Chemical synthesis</topic><topic>Cocrystallization</topic><topic>Copolymers</topic><topic>Crystal lattices</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Enthalpy</topic><topic>Glass transition temperature</topic><topic>Kinetics</topic><topic>Mechanical properties</topic><topic>Melt temperature</topic><topic>Polycarbonate resins</topic><topic>Polymers</topic><topic>Studies</topic><topic>Thermal stability</topic><topic>Thermo-mechanical properties</topic><topic>Thermomechanical properties</topic><topic>Transition temperatures</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cai, Xiaodong</creatorcontrib><creatorcontrib>Yang, Xiangui</creatorcontrib><creatorcontrib>Zhang, Hua</creatorcontrib><creatorcontrib>Wang, Gongying</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cai, Xiaodong</au><au>Yang, Xiangui</au><au>Zhang, Hua</au><au>Wang, Gongying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aliphatic-aromatic poly(carbonate-co-ester)s containing biobased furan monomer: Synthesis and thermo-mechanical properties</atitle><jtitle>Polymer (Guilford)</jtitle><date>2018-01-03</date><risdate>2018</risdate><volume>134</volume><spage>63</spage><epage>70</epage><pages>63-70</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>Aliphatic-aromatic poly(carbonate-co-ester) random copolymers poly(butylene carbonate-co-furandicarboxylate)s (PBCFs) with different composition had been prepared from dimethyl carbonate (DMC), 1,4-butanediol (BD) and bio-based dimethyl furan-2,5-dicarboxylate (DMFA) by two-step melt polycondensation method. A series of characterization results can be explained as follows: the varying melting temperature (Tm) and enthalpy (ΔHm) displayed that the copolymers were strongly dependent upon the compositions of butylene carbonate (BC) and butylene furandicarboxylate (BF) units. In addition, glass transition temperature (Tg) noticeably increased with the content of BF units increasing, which agreed with Fox equation; a comparative kinetics research of isothermal crystallization of homopolymer and copolymers with different composition displayed that the existence of BF units could accelerate the crystallization rate of PBC. Furthermore, all of PBCFs exhibited a typical isodimorphic cocrystallization behavior, whose crystal lattice structure shifted from PBC type crystal to PBF type; the thermal stability of PBCFs also expressed to be enhanced during the process of the increasing BF unit content; last but not the least, the mechanical performances could be easily by adjusting the feed components.
Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers. [Display omitted]
•Bio-based aliphatic-aromatic poly(carbonate-co-ester) random copolymers had been synthesized via two-step melt polycondensation method.•Bio-based furan units could significantly influence the thermal transition behavior, thermal stability as well as crystallinity of copolymers.•The mechanical properties of copolymers can be adjusted by changing the feed composition.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2017.11.058</doi><tpages>8</tpages></addata></record> |
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| subjects | Aliphatic compounds Aliphatic-aromatic copolymers Bio-based furanic monomer Butanediol Chemical synthesis Cocrystallization Copolymers Crystal lattices Crystal structure Crystallization Enthalpy Glass transition temperature Kinetics Mechanical properties Melt temperature Polycarbonate resins Polymers Studies Thermal stability Thermo-mechanical properties Thermomechanical properties Transition temperatures |
| title | Aliphatic-aromatic poly(carbonate-co-ester)s containing biobased furan monomer: Synthesis and thermo-mechanical properties |
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