Dual Brønsted‐acid Organocatalysis: Cooperative Asymmetric Catalysis with Combined Phosphoric and Carboxylic Acids

How can an assisting Brønsted‐acid be beneficial in asymmetric Brønsted‐acid catalysis? In this Minireview, we discuss selected examples of chiral organocatalysts that feature two acidic groups working cooperatively by virtue of intra‐ or intermolecular hydrogen‐bonding. In these systems, the assist...

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Veröffentlicht in:	ChemCatChem 2018-03, Vol.10 (6), p.1221-1234
Hauptverfasser:	Mitra, Raja, Niemeyer, Jochen
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids asymmetric organocatalysis Asymmetry brønsted-acids Carboxylic acids Catalysis cooperative catalysis hydrogen bonds Reaction mechanisms Substrates
Online-Zugang:	Volltext
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