Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance

This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively d...

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Veröffentlicht in:Ionics 2018-04, Vol.24 (4), p.1129-1137
Hauptverfasser: Li, Peipeng, Ding, Xianan, Yang, Zhaoyi, Chen, Ming, Wang, Meng, Wang, Xindong
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container_issue 4
container_start_page 1129
container_title Ionics
container_volume 24
creator Li, Peipeng
Ding, Xianan
Yang, Zhaoyi
Chen, Ming
Wang, Meng
Wang, Xindong
description This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively decrease the corrosion current density by four orders of magnitude in comparison with the uncoated 316LSS. The experimental results showed that the PANI increased the open-circuit potential of the steel by about 140 mV. The polarization current value of PANI-coated 316LSS reduced to 2.3 × 10 −7  A/cm 2 under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. This indicates that the PANI coating was an effective barrier against the inward penetration of corrosive species.
doi_str_mv 10.1007/s11581-017-2274-8
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The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively decrease the corrosion current density by four orders of magnitude in comparison with the uncoated 316LSS. The experimental results showed that the PANI increased the open-circuit potential of the steel by about 140 mV. The polarization current value of PANI-coated 316LSS reduced to 2.3 × 10 −7  A/cm 2 under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. 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subjects Chemistry
Chemistry and Materials Science
Circuits
Coating effects
Condensed Matter Physics
Corrosion currents
Corrosion potential
Corrosion prevention
Corrosion resistance
Corrosion resistant steels
Electrochemical analysis
Electrochemistry
Energy Storage
Nyquist plots
Optical and Electronic Materials
Original Paper
Polyanilines
Protective coatings
Renewable and Green Energy
title Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance
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