Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance
This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively d...
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Veröffentlicht in: | Ionics 2018-04, Vol.24 (4), p.1129-1137 |
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description | This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively decrease the corrosion current density by four orders of magnitude in comparison with the uncoated 316LSS. The experimental results showed that the PANI increased the open-circuit potential of the steel by about 140 mV. The polarization current value of PANI-coated 316LSS reduced to 2.3 × 10
−7
A/cm
2
under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. This indicates that the PANI coating was an effective barrier against the inward penetration of corrosive species. |
doi_str_mv | 10.1007/s11581-017-2274-8 |
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−7
A/cm
2
under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. This indicates that the PANI coating was an effective barrier against the inward penetration of corrosive species.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-017-2274-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Circuits ; Coating effects ; Condensed Matter Physics ; Corrosion currents ; Corrosion potential ; Corrosion prevention ; Corrosion resistance ; Corrosion resistant steels ; Electrochemical analysis ; Electrochemistry ; Energy Storage ; Nyquist plots ; Optical and Electronic Materials ; Original Paper ; Polyanilines ; Protective coatings ; Renewable and Green Energy</subject><ispartof>Ionics, 2018-04, Vol.24 (4), p.1129-1137</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-44688164f0c361641c62f053b78ec38774a6d1f9a308087f583fa1d4af383edb3</citedby><cites>FETCH-LOGICAL-c316t-44688164f0c361641c62f053b78ec38774a6d1f9a308087f583fa1d4af383edb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-017-2274-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-017-2274-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Li, Peipeng</creatorcontrib><creatorcontrib>Ding, Xianan</creatorcontrib><creatorcontrib>Yang, Zhaoyi</creatorcontrib><creatorcontrib>Chen, Ming</creatorcontrib><creatorcontrib>Wang, Meng</creatorcontrib><creatorcontrib>Wang, Xindong</creatorcontrib><title>Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance</title><title>Ionics</title><addtitle>Ionics</addtitle><description>This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively decrease the corrosion current density by four orders of magnitude in comparison with the uncoated 316LSS. The experimental results showed that the PANI increased the open-circuit potential of the steel by about 140 mV. The polarization current value of PANI-coated 316LSS reduced to 2.3 × 10
−7
A/cm
2
under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. This indicates that the PANI coating was an effective barrier against the inward penetration of corrosive species.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Circuits</subject><subject>Coating effects</subject><subject>Condensed Matter Physics</subject><subject>Corrosion currents</subject><subject>Corrosion potential</subject><subject>Corrosion prevention</subject><subject>Corrosion resistance</subject><subject>Corrosion resistant steels</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Nyquist plots</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Polyanilines</subject><subject>Protective coatings</subject><subject>Renewable and Green Energy</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kMFPwyAYxYnRxDn9A7yReEahtMCOZtnUZEYPeiaMgmVpSwWmmUf_cmlq4snTO3y_996XB8AlwdcEY34TCakEQZhwVBS8ROIIzIhgBcKc4WMww4uSI45LfgrOYtxhzBgp-Ax8r1qjU_C6MZ3TqoXx0KfGRBeh6muoGxWUTia4L5Wc76G3cPDtQfWudb1B2qtkavi8elwvYWdSDti6DKgAhzafIvx0qYGuG4L_yKD2Ifg4BoWxI6lem3NwYlUbzcWvzsHrevWyvEebp7uH5e0GaUpYQmXJhCCstFhTlpVoVlhc0S0XRlPBealYTexCUSyw4LYS1CpSl8pSQU29pXNwNeXmX973Jia58_vQ50pZYMKqBWVVkSkyUTo_GoOxcgiuU-EgCZbj1HKaWuap5Ti1FNlTTJ6Y2f7NhL_k_00_7ECDhg</recordid><startdate>20180401</startdate><enddate>20180401</enddate><creator>Li, Peipeng</creator><creator>Ding, Xianan</creator><creator>Yang, Zhaoyi</creator><creator>Chen, Ming</creator><creator>Wang, Meng</creator><creator>Wang, Xindong</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180401</creationdate><title>Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance</title><author>Li, Peipeng ; Ding, Xianan ; Yang, Zhaoyi ; Chen, Ming ; Wang, Meng ; Wang, Xindong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-44688164f0c361641c62f053b78ec38774a6d1f9a308087f583fa1d4af383edb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Circuits</topic><topic>Coating effects</topic><topic>Condensed Matter Physics</topic><topic>Corrosion currents</topic><topic>Corrosion potential</topic><topic>Corrosion prevention</topic><topic>Corrosion resistance</topic><topic>Corrosion resistant steels</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Nyquist plots</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Polyanilines</topic><topic>Protective coatings</topic><topic>Renewable and Green Energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Peipeng</creatorcontrib><creatorcontrib>Ding, Xianan</creatorcontrib><creatorcontrib>Yang, Zhaoyi</creatorcontrib><creatorcontrib>Chen, Ming</creatorcontrib><creatorcontrib>Wang, Meng</creatorcontrib><creatorcontrib>Wang, Xindong</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Peipeng</au><au>Ding, Xianan</au><au>Yang, Zhaoyi</au><au>Chen, Ming</au><au>Wang, Meng</au><au>Wang, Xindong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2018-04-01</date><risdate>2018</risdate><volume>24</volume><issue>4</issue><spage>1129</spage><epage>1137</epage><pages>1129-1137</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>This article reported the electrochemical deposition of polyaniline (PANI) on 316-L stainless steel (316LSS) to improve the anti-corrosion performance as PEMFC metal bipolar plates. The results indicate that PANI can increase the corrosion potential of 316LSS by more than 410.57 mV and effectively decrease the corrosion current density by four orders of magnitude in comparison with the uncoated 316LSS. The experimental results showed that the PANI increased the open-circuit potential of the steel by about 140 mV. The polarization current value of PANI-coated 316LSS reduced to 2.3 × 10
−7
A/cm
2
under the PEMFC cathode working condition. During exposure for 12 h, Nyquist plots of PANI-coated 316LSS did not change substantially. This indicates that the PANI coating was an effective barrier against the inward penetration of corrosive species.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-017-2274-8</doi><tpages>9</tpages></addata></record> |
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subjects | Chemistry Chemistry and Materials Science Circuits Coating effects Condensed Matter Physics Corrosion currents Corrosion potential Corrosion prevention Corrosion resistance Corrosion resistant steels Electrochemical analysis Electrochemistry Energy Storage Nyquist plots Optical and Electronic Materials Original Paper Polyanilines Protective coatings Renewable and Green Energy |
title | Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance |
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