Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions
Ru on covaltent triazine frameworks (CTF) are highly active and selective catalysts for the conversion of xylitol to glycols (80% C-yield) in basic media. With increasing N-content decarbonylation reactions are suppressed leading to high glycol selectivity. The suppression can be attributed to the p...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.20 (6), p.1316-1322 |
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| container_issue | 6 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 20 |
| creator | Beine, Anna Katharina Krüger, Andreas J. D. Artz, Jens Weidenthaler, Claudia Glotzbach, Christoph Hausoul, Peter J. C. Palkovits, Regina |
| description | Ru on covaltent triazine frameworks (CTF) are highly active and selective catalysts for the conversion of xylitol to glycols (80% C-yield) in basic media. With increasing N-content decarbonylation reactions are suppressed leading to high glycol selectivity. The suppression can be attributed to the presence of N in the support and to metal-support interactions. The catalysts exhibit high stability and could be recycled 5 times with minor loss of activity. |
| doi_str_mv | 10.1039/C8GC00208H |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2018, Vol.20 (6), p.1316-1322 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_proquest_journals_2015027070 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Basic converters Catalysis Catalysts Glycols Green chemistry Triazine Xylitol |
| title | Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions |
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