Nanostructured all-solid-state supercapacitors based on NASICON-type Li1.4Al0.4Ti1.6(PO4)3 electrolyte
Lithium aluminum titanium phosphate (LATP), a NASICON-type (structure of Na 1 + x Zr 2 Si x P 3 − x O 12 , 0
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| Veröffentlicht in: | Journal of solid state electrochemistry 2018, Vol.22 (4), p.1055-1061 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Liao, Guangyue Mahrholz, Thorsten Geier, Sebastian Wierach, Peter Wiedemann, Martin |
| description | Lithium aluminum titanium phosphate (LATP), a NASICON-type (structure of Na
1 + x
Zr
2
Si
x
P
3 − x
O
12
, 0 |
| doi_str_mv | 10.1007/s10008-017-3849-z |
| format | Article |
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1 + x
Zr
2
Si
x
P
3 − x
O
12
, 0 <
x
< 3) lithium ionic conductor, possesses high ionic conductivity at ambient temperature and sufficiently high electrochemical stability compared to well-established types of solid electrolytes. This ensures LATP being potentially used as solid electrolyte for all-solid-state supercapacitors. In the pure ionic conductors like LATP, the stoichiometry change under work potential for energy storage is not possible. Therefore, it is essential to produce heterophase contacts, at which the compositional changes could occur. Carbon nanotube (CNT), an excellent electronical conductor, has been consequently mixed with LATP. The all-solid-state supercapacitors with this LATP/CNT mixture have been manufactured in sandwich structure—two mixture layers separated by a pure LATP layer as separator. And the impedance behavior as well as supercapacitance dependent on various CNT weight percentages (1–7.5%) has been investigated by electrochemical impedance spectroscopy and cyclic voltammetry. The results clearly prove that electrical double layer could be formed at the heterophase contacts indicating the supercapacitance behavior of the device, especially when the high contents of CNTs are used. The capacitance of specimen without CNT shows only a value of 0.52 mF/cm
3
, which is strongly promoted to 11.59 mF/cm
3
when CNT content increases to 7.5%.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-017-3849-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Ambient temperature ; Analytical Chemistry ; Carbon nanotubes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Conductors ; Electric contacts ; Electrical resistivity ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electrolytes ; Energy Storage ; Ion currents ; Lithium ; Molten salt electrolytes ; Nanotubes ; Original Paper ; Physical Chemistry ; Sandwich structures ; Solid electrolytes ; Solid state ; Stoichiometry ; Supercapacitors</subject><ispartof>Journal of solid state electrochemistry, 2018, Vol.22 (4), p.1055-1061</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2017</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c270z-81eace63bb5a9c0d9511456bb98e87fd5092588a6f748666f68888a420078b3c3</citedby><cites>FETCH-LOGICAL-c270z-81eace63bb5a9c0d9511456bb98e87fd5092588a6f748666f68888a420078b3c3</cites><orcidid>0000-0002-5464-3242</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-017-3849-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-017-3849-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Liao, Guangyue</creatorcontrib><creatorcontrib>Mahrholz, Thorsten</creatorcontrib><creatorcontrib>Geier, Sebastian</creatorcontrib><creatorcontrib>Wierach, Peter</creatorcontrib><creatorcontrib>Wiedemann, Martin</creatorcontrib><title>Nanostructured all-solid-state supercapacitors based on NASICON-type Li1.4Al0.4Ti1.6(PO4)3 electrolyte</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Lithium aluminum titanium phosphate (LATP), a NASICON-type (structure of Na
1 + x
Zr
2
Si
x
P
3 − x
O
12
, 0 <
x
< 3) lithium ionic conductor, possesses high ionic conductivity at ambient temperature and sufficiently high electrochemical stability compared to well-established types of solid electrolytes. This ensures LATP being potentially used as solid electrolyte for all-solid-state supercapacitors. In the pure ionic conductors like LATP, the stoichiometry change under work potential for energy storage is not possible. Therefore, it is essential to produce heterophase contacts, at which the compositional changes could occur. Carbon nanotube (CNT), an excellent electronical conductor, has been consequently mixed with LATP. The all-solid-state supercapacitors with this LATP/CNT mixture have been manufactured in sandwich structure—two mixture layers separated by a pure LATP layer as separator. And the impedance behavior as well as supercapacitance dependent on various CNT weight percentages (1–7.5%) has been investigated by electrochemical impedance spectroscopy and cyclic voltammetry. The results clearly prove that electrical double layer could be formed at the heterophase contacts indicating the supercapacitance behavior of the device, especially when the high contents of CNTs are used. The capacitance of specimen without CNT shows only a value of 0.52 mF/cm
3
, which is strongly promoted to 11.59 mF/cm
3
when CNT content increases to 7.5%.</description><subject>Aluminum</subject><subject>Ambient temperature</subject><subject>Analytical Chemistry</subject><subject>Carbon nanotubes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Conductors</subject><subject>Electric contacts</subject><subject>Electrical resistivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Ion currents</subject><subject>Lithium</subject><subject>Molten salt electrolytes</subject><subject>Nanotubes</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Sandwich structures</subject><subject>Solid electrolytes</subject><subject>Solid state</subject><subject>Stoichiometry</subject><subject>Supercapacitors</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAQhi0EEqXwA9giscDgYseOP8aqolCpapEos-U4DkoV4mA7Q_vrcQkSEzfc3fC8d9IDwC1GM4wQfwypIwER5pAIKuHxDEwwJQQizsT5z55DQYW4BFch7FECGUYTUG9050L0g4mDt1Wm2xYG1zYVDFFHm4Wht97oXpsmOh-yUodEuS7bzN9Wi-0GxkNvs3WDZ3TeohndpY3dv27pA8lsa030rj1Eew0uat0Ge_M7p-B9-bRbvMD19nm1mK-hyTk6QoGtNpaRsiy0NKiSBca0YGUphRW8rgok80IIzWpOBWOsZiKVpnlSIEpiyBTcjXd7774GG6Lau8F36aXKEaacSMnzROGRMt6F4G2tet98an9QGKmTTjXqVMmSOulUx5TJx0xIbPdh_d_l_0PfdR92TQ</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Liao, Guangyue</creator><creator>Mahrholz, Thorsten</creator><creator>Geier, Sebastian</creator><creator>Wierach, Peter</creator><creator>Wiedemann, Martin</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5464-3242</orcidid></search><sort><creationdate>2018</creationdate><title>Nanostructured all-solid-state supercapacitors based on NASICON-type Li1.4Al0.4Ti1.6(PO4)3 electrolyte</title><author>Liao, Guangyue ; Mahrholz, Thorsten ; Geier, Sebastian ; Wierach, Peter ; Wiedemann, Martin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270z-81eace63bb5a9c0d9511456bb98e87fd5092588a6f748666f68888a420078b3c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aluminum</topic><topic>Ambient temperature</topic><topic>Analytical Chemistry</topic><topic>Carbon nanotubes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Conductors</topic><topic>Electric contacts</topic><topic>Electrical resistivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Ion currents</topic><topic>Lithium</topic><topic>Molten salt electrolytes</topic><topic>Nanotubes</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Sandwich structures</topic><topic>Solid electrolytes</topic><topic>Solid state</topic><topic>Stoichiometry</topic><topic>Supercapacitors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liao, Guangyue</creatorcontrib><creatorcontrib>Mahrholz, Thorsten</creatorcontrib><creatorcontrib>Geier, Sebastian</creatorcontrib><creatorcontrib>Wierach, Peter</creatorcontrib><creatorcontrib>Wiedemann, Martin</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liao, Guangyue</au><au>Mahrholz, Thorsten</au><au>Geier, Sebastian</au><au>Wierach, Peter</au><au>Wiedemann, Martin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanostructured all-solid-state supercapacitors based on NASICON-type Li1.4Al0.4Ti1.6(PO4)3 electrolyte</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2018</date><risdate>2018</risdate><volume>22</volume><issue>4</issue><spage>1055</spage><epage>1061</epage><pages>1055-1061</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Lithium aluminum titanium phosphate (LATP), a NASICON-type (structure of Na
1 + x
Zr
2
Si
x
P
3 − x
O
12
, 0 <
x
< 3) lithium ionic conductor, possesses high ionic conductivity at ambient temperature and sufficiently high electrochemical stability compared to well-established types of solid electrolytes. This ensures LATP being potentially used as solid electrolyte for all-solid-state supercapacitors. In the pure ionic conductors like LATP, the stoichiometry change under work potential for energy storage is not possible. Therefore, it is essential to produce heterophase contacts, at which the compositional changes could occur. Carbon nanotube (CNT), an excellent electronical conductor, has been consequently mixed with LATP. The all-solid-state supercapacitors with this LATP/CNT mixture have been manufactured in sandwich structure—two mixture layers separated by a pure LATP layer as separator. And the impedance behavior as well as supercapacitance dependent on various CNT weight percentages (1–7.5%) has been investigated by electrochemical impedance spectroscopy and cyclic voltammetry. The results clearly prove that electrical double layer could be formed at the heterophase contacts indicating the supercapacitance behavior of the device, especially when the high contents of CNTs are used. The capacitance of specimen without CNT shows only a value of 0.52 mF/cm
3
, which is strongly promoted to 11.59 mF/cm
3
when CNT content increases to 7.5%.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-017-3849-z</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5464-3242</orcidid></addata></record> |
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| subjects | Aluminum Ambient temperature Analytical Chemistry Carbon nanotubes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Conductors Electric contacts Electrical resistivity Electrochemical impedance spectroscopy Electrochemistry Electrolytes Energy Storage Ion currents Lithium Molten salt electrolytes Nanotubes Original Paper Physical Chemistry Sandwich structures Solid electrolytes Solid state Stoichiometry Supercapacitors |
| title | Nanostructured all-solid-state supercapacitors based on NASICON-type Li1.4Al0.4Ti1.6(PO4)3 electrolyte |
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