New protocol to determine the equilibrium constant of atom transfer radical polymerization

A new electrochemical procedure is described to determine the equilibrium constant of atom transfer radical polymerization, KATRP. A rotating disk electrode (RDE) was used to monitor the concentration of the catalyst, CuIL+, during a reaction between the metal complex and an alkyl halide (RX) used a...

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Veröffentlicht in:	Electrochimica acta 2018-01, Vol.260, p.648-655
Hauptverfasser:	Lorandi, Francesca, Fantin, Marco, Isse, Abdirisak Ahmed, Gennaro, Armando, Matyjaszewski, Krzysztof
Format:	Artikel
Sprache:	eng
Schlagworte:	ATRP enthalpy ATRP equilibrium constant Catalysis Coordination compounds Correlation analysis Halidophilicity constant Initiators Polymerization Rotating disk electrode Rotating disks RX activation kinetics Studies Termination (polymerization)
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