Porous carbons derived from waste printing paper for high rate performance supercapacitors in alkaline, acidic and neutral electrolytes

Renewable biomass as a precursor in the preparation of sustainable carbon materials for supercapacitors has gained much attention due to its huge reserves and being economical. In this paper, we used waste printing paper as the precursor to prepare highly porous carbons via a combined method of pre-...

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Veröffentlicht in:RSC advances 2018-01, Vol.8 (8), p.3974-3981
Hauptverfasser: Liu, Dandan, Wang, Yesheng, Qiu, Zhipeng, Li, Yanyan, Wang, Li, Zhao, Yi, Zhou, Jin
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container_issue 8
container_start_page 3974
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creator Liu, Dandan
Wang, Yesheng
Qiu, Zhipeng
Li, Yanyan
Wang, Li
Zhao, Yi
Zhou, Jin
description Renewable biomass as a precursor in the preparation of sustainable carbon materials for supercapacitors has gained much attention due to its huge reserves and being economical. In this paper, we used waste printing paper as the precursor to prepare highly porous carbons via a combined method of pre-carbonation and KOH activation. The prepared carbon materials exhibit huge specific surface areas and good conductivities as high as 2616.1 m 2 g −1 and 198.8 mS cm −1 , respectively. They were used as the electrode materials of supercapacitors in the most common aqueous electrolytes, including 6 M KOH, 1 M H 2 SO 4 , and 1 M Na 2 SO 4 , and showed excellent capacitive performance in all the investigated electrolytes, such as very high specific capacitances ( e.g. 385.0, 370.1, and 317.7 F g −1 in KOH, H 2 SO 4 and Na 2 SO 4 electrolyte at 0.2 A g −1 , respectively), outstanding rate capabilities ( e.g. 198 F g −1 at 60 A g −1 in H 2 SO 4 ), high energy densities ( e.g. 21.9 W h kg −1 in Na 2 SO 4 ), high power capability (at 28 000 W kg −1 , remains at 5.83 W h kg −1 in Na 2 SO 4 ), and good recyclability (about 94% retention after 10 000 cycles). Waste printing paper is used as a carbon precursor for the preparation of high performance carbon materials in supercapacitor applications.
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subjects Aqueous electrolytes
Carbonation
Electrode materials
Electrolytes
Recyclability
Sodium sulfate
Sulfuric acid
Supercapacitors
title Porous carbons derived from waste printing paper for high rate performance supercapacitors in alkaline, acidic and neutral electrolytes
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