Binary systems based on aromatic amines with a view of development of novel hardeners for epoxy resins
Three binary systems based on aromatic amines [4,4′-diaminodiphenylmethane (DDM), 4,4′-diaminodiphenyl sulfone (DDS), 4,4′-diaminodiphenyl ether (DDE) and m -phenylenediamine (MPDA)] were investigated by differential scanning calorimetry (DSC). Phase diagrams for different compositions were construc...
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Veröffentlicht in: | Journal of thermal analysis and calorimetry 2018-04, Vol.132 (1), p.643-650 |
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creator | Amirova, Lyaysan R. Surnova, Albina V. Alchin, Ruslan M. Gatiatulin, Askar K. Ziganshin, Marat A. Ibragimov, Marsel R. Amirova, Liliya M. |
description | Three binary systems based on aromatic amines [4,4′-diaminodiphenylmethane (DDM), 4,4′-diaminodiphenyl sulfone (DDS), 4,4′-diaminodiphenyl ether (DDE) and
m
-phenylenediamine (MPDA)] were investigated by differential scanning calorimetry (DSC). Phase diagrams for different compositions were constructed. The DSC results showed that all binary systems form simple eutectic mixtures. Formation of eutectic physical mixture of MPDA–DDM and MPDA–DDS was confirmed by powder XRD study. In the case of DDE–DDS system, it was found that besides the eutectic mixture a small amount of the charge transfer complex forms with the novel crystal structure. |
doi_str_mv | 10.1007/s10973-017-6922-z |
format | Article |
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m
-phenylenediamine (MPDA)] were investigated by differential scanning calorimetry (DSC). Phase diagrams for different compositions were constructed. The DSC results showed that all binary systems form simple eutectic mixtures. Formation of eutectic physical mixture of MPDA–DDM and MPDA–DDS was confirmed by powder XRD study. In the case of DDE–DDS system, it was found that besides the eutectic mixture a small amount of the charge transfer complex forms with the novel crystal structure.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-017-6922-z</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Amines ; Analytical Chemistry ; Aromatic amines ; Binary system ; Binary systems ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Diamines ; Differential scanning calorimetry ; Epoxy resins ; Eutectics ; Hardeners ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Methylene dianiline ; Phenylenediamine ; Physical Chemistry ; Polymer Sciences</subject><ispartof>Journal of thermal analysis and calorimetry, 2018-04, Vol.132 (1), p.643-650</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-6791871d9a364006eee9d1103b85fddd67550ca2831db33b9a20de3429c599253</citedby><cites>FETCH-LOGICAL-c426t-6791871d9a364006eee9d1103b85fddd67550ca2831db33b9a20de3429c599253</cites><orcidid>0000-0001-6306-4309</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-017-6922-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-017-6922-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Amirova, Lyaysan R.</creatorcontrib><creatorcontrib>Surnova, Albina V.</creatorcontrib><creatorcontrib>Alchin, Ruslan M.</creatorcontrib><creatorcontrib>Gatiatulin, Askar K.</creatorcontrib><creatorcontrib>Ziganshin, Marat A.</creatorcontrib><creatorcontrib>Ibragimov, Marsel R.</creatorcontrib><creatorcontrib>Amirova, Liliya M.</creatorcontrib><title>Binary systems based on aromatic amines with a view of development of novel hardeners for epoxy resins</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Three binary systems based on aromatic amines [4,4′-diaminodiphenylmethane (DDM), 4,4′-diaminodiphenyl sulfone (DDS), 4,4′-diaminodiphenyl ether (DDE) and
m
-phenylenediamine (MPDA)] were investigated by differential scanning calorimetry (DSC). Phase diagrams for different compositions were constructed. The DSC results showed that all binary systems form simple eutectic mixtures. Formation of eutectic physical mixture of MPDA–DDM and MPDA–DDS was confirmed by powder XRD study. In the case of DDE–DDS system, it was found that besides the eutectic mixture a small amount of the charge transfer complex forms with the novel crystal structure.</description><subject>Amines</subject><subject>Analytical Chemistry</subject><subject>Aromatic amines</subject><subject>Binary system</subject><subject>Binary systems</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Diamines</subject><subject>Differential scanning calorimetry</subject><subject>Epoxy resins</subject><subject>Eutectics</subject><subject>Hardeners</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Methylene dianiline</subject><subject>Phenylenediamine</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kcFqGzEQhpfSQtM0D5CbIKceNhlJXu3q6Ia2MQQKSXsW8mrWUfBKrkaO4zx9ZDYQfCg6aEZ8nyTmr6pzDpccoL0iDrqVNfC2VlqI-uVDdcKbrquFFupjqWWpFW_gc_WF6BEAtAZ-Ug3ffbBpz2hPGUdiS0voWAzMpjja7HtmRx-Q2M7nB2bZk8cdiwNz-ITruBkx5EMbYmnZg00OAyZiQ0wMN_F5zxKSD_S1-jTYNeHZ235a_f3548_1TX37-9fien5b9zOhcq1azbuWO22lmgEoRNSOc5DLrhmcc6ptGuit6CR3SymX2gpwKGdC943WopGn1cV07ybFf1ukbB7jNoXypBHAoeuUELJQlxO1sms0PgwxJ9uX5XD0fQw4-HI-b2QZU6u6WRG-HQmFyficV3ZLZBb3d8csn9g-RaKEg9kkP5YZGw7mkJWZsjIlK3PIyrwUR0wOFTasML1_-__SK_54llI</recordid><startdate>20180401</startdate><enddate>20180401</enddate><creator>Amirova, Lyaysan R.</creator><creator>Surnova, Albina V.</creator><creator>Alchin, Ruslan M.</creator><creator>Gatiatulin, Askar K.</creator><creator>Ziganshin, Marat A.</creator><creator>Ibragimov, Marsel R.</creator><creator>Amirova, Liliya M.</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><orcidid>https://orcid.org/0000-0001-6306-4309</orcidid></search><sort><creationdate>20180401</creationdate><title>Binary systems based on aromatic amines with a view of development of novel hardeners for epoxy resins</title><author>Amirova, Lyaysan R. ; Surnova, Albina V. ; Alchin, Ruslan M. ; Gatiatulin, Askar K. ; Ziganshin, Marat A. ; Ibragimov, Marsel R. ; Amirova, Liliya M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-6791871d9a364006eee9d1103b85fddd67550ca2831db33b9a20de3429c599253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Amines</topic><topic>Analytical Chemistry</topic><topic>Aromatic amines</topic><topic>Binary system</topic><topic>Binary systems</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Diamines</topic><topic>Differential scanning calorimetry</topic><topic>Epoxy resins</topic><topic>Eutectics</topic><topic>Hardeners</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Methylene dianiline</topic><topic>Phenylenediamine</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amirova, Lyaysan R.</creatorcontrib><creatorcontrib>Surnova, Albina V.</creatorcontrib><creatorcontrib>Alchin, Ruslan M.</creatorcontrib><creatorcontrib>Gatiatulin, Askar K.</creatorcontrib><creatorcontrib>Ziganshin, Marat A.</creatorcontrib><creatorcontrib>Ibragimov, Marsel R.</creatorcontrib><creatorcontrib>Amirova, Liliya M.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amirova, Lyaysan R.</au><au>Surnova, Albina V.</au><au>Alchin, Ruslan M.</au><au>Gatiatulin, Askar K.</au><au>Ziganshin, Marat A.</au><au>Ibragimov, Marsel R.</au><au>Amirova, Liliya M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binary systems based on aromatic amines with a view of development of novel hardeners for epoxy resins</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2018-04-01</date><risdate>2018</risdate><volume>132</volume><issue>1</issue><spage>643</spage><epage>650</epage><pages>643-650</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Three binary systems based on aromatic amines [4,4′-diaminodiphenylmethane (DDM), 4,4′-diaminodiphenyl sulfone (DDS), 4,4′-diaminodiphenyl ether (DDE) and
m
-phenylenediamine (MPDA)] were investigated by differential scanning calorimetry (DSC). Phase diagrams for different compositions were constructed. The DSC results showed that all binary systems form simple eutectic mixtures. Formation of eutectic physical mixture of MPDA–DDM and MPDA–DDS was confirmed by powder XRD study. In the case of DDE–DDS system, it was found that besides the eutectic mixture a small amount of the charge transfer complex forms with the novel crystal structure.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-017-6922-z</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-6306-4309</orcidid></addata></record> |
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subjects | Amines Analytical Chemistry Aromatic amines Binary system Binary systems Charge transfer Chemistry Chemistry and Materials Science Crystal structure Diamines Differential scanning calorimetry Epoxy resins Eutectics Hardeners Inorganic Chemistry Measurement Science and Instrumentation Methylene dianiline Phenylenediamine Physical Chemistry Polymer Sciences |
title | Binary systems based on aromatic amines with a view of development of novel hardeners for epoxy resins |
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