Visible light-induced selective aerobic oxidative transposition of vinyl halides using a tetrahalogenoferrate( iii ) complex catalyst

We report tetrahalogenoferrate( iii ) complexes as a new kind of iron photocatalyst. These complexes are easily prepared from FeCl 3 with lithium bromide or ammonium bromides, and have a good and tunable photo-sensitivity in the visible light region. Their distinct catalytic mode with FeCl 3 enables...

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Veröffentlicht in:	Organic Chemistry Frontiers 2018-01, Vol.5 (3), p.380-385
Hauptverfasser:	Li, Sanliang, Zhu, Bo, Lee, Richmond, Qiao, Baokun, Jiang, Zhiyong
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonium Ammonium bromides Bromides Carbonyl compounds Carbonyls Catalysis Coordination compounds Halides Iron chlorides Ketones Lithium Organic chemistry Photocatalysts Substrates Transposition
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