Nucleophile and base differentiation of pyridine with tetrahalocatechols and the formation of manganese(iii)-catecholate and pyridinium-catecholate complexes for the in situ generation of H2O2 from O2

Crystal structures of two novel pyridinium catecholate compounds (1,2-dihydroxy-3,5,6-trichlorobenzene-4-pyridinium chloride and 1,2-dihydroxy-3,5,6-tribromobenzene-4-pyridinium bromide) were obtained by the reaction of pyridine with tetrachloro-o-benzoquinone (in the presence of hydroxylamine) and...

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Veröffentlicht in:	New journal of chemistry 2017, Vol.41 (24), p.15411-15419
Hauptverfasser:	Bakewell, Nicholas, Thavarajah, Rumintha, Motevalli, Majid, Sheriff, Tippu S
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catechol Crystal structure Hydrogen peroxide Manganese Mass spectrometry Quinones Reduction Substrates
Online-Zugang:	Volltext
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