An investigation of ligand effects on the visible light-induced formation of porphyrin–iron( iv )-oxo intermediates

High-valent porphyrin–iron-oxo intermediates are the central oxidizing species in heme-containing enzymes and synthetic oxidation catalysts. In this work, we investigated a new photochemical entry to porphyrin–iron( iv )-oxo derivatives in a variety of porphyrin ligands with different electronic and...

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Veröffentlicht in:	New journal of chemistry 2017, Vol.41 (23), p.14334-14341
Hauptverfasser:	Kwong, Ka Wai, Patel, Dharmesh, Malone, Jonathan, Lee, Ngo Fung, Kash, Benjamin, Zhang, Rui
Format:	Artikel
Sprache:	eng
Schlagworte:	Bromates Cations Derivatives Dimers Electrons Iron Ligands Oxidation Photolysis Porphyrins Rate constants
Online-Zugang:	Volltext
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