Carbon nitride creates thioamides in high yields by the photocatalytic Kindler reaction
Potassium poly(heptazine imide), a carbon nitride based photocatalyst, effectively promotes the Kindler reaction of thioamide bond formation using amines and elemental sulfur as building blocks under visible light irradiation. The feasibility of the developed methodology was confirmed using 14 diffe...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.2 (4), p.838-842 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Kurpil, B Kumru, B Heil, T Antonietti, M Savateev, A |
| description | Potassium poly(heptazine imide), a carbon nitride based photocatalyst, effectively promotes the Kindler reaction of thioamide bond formation using amines and elemental sulfur as building blocks under visible light irradiation. The feasibility of the developed methodology was confirmed using 14 different primary and secondary amines, including substituted benzylamines and heterocyclic and aliphatic methylamines, which were successfully converted into thioamides with 68-92% isolated yields.
Potassium poly(heptazine imide), a carbon nitride based photocatalyst, effectively promotes the Kindler reaction of thioamide bond formation using amines and elemental sulfur as building blocks under visible light irradiation. |
| doi_str_mv | 10.1039/c7gc03734a |
| format | Article |
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| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2018, Vol.2 (4), p.838-842 |
| issn | 1463-9262 1463-9270 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aliphatic compounds Amines Carbon nitride Feasibility studies Green chemistry Irradiation Light irradiation Photocatalysis Potassium Radiation Sulfur |
| title | Carbon nitride creates thioamides in high yields by the photocatalytic Kindler reaction |
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