Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties
A series of heterometallic cluster organic frameworks based on cuprous-halide Cu 4 I 4 clusters and lanthanide clusters, [Ln 2 (H 2 O) 8 ] 2 (Cu 4 I 4 )(pdc) 4 ][NO 3 ] 4 ·solvent ( 1 -Ln , Ln = Y, Tb, Eu, H 2 pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvotherma...
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| Veröffentlicht in: | CrystEngComm 2018, Vol.2 (6), p.738-745 |
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| creator | Liu, Jin-Hua Gu, Ya-Nan Chen, Yi Qi, Yan-Jie Li, Xin-Xiong Zheng, Shou-Tian |
| description | A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters, [Ln
2
(H
2
O)
8
]
2
(Cu
4
I
4
)(pdc)
4
][NO
3
]
4
·solvent (
1
-Ln
, Ln = Y, Tb, Eu, H
2
pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that
1
-Ln
show fascinating three-dimensional porous framework structures constructed from two dissimilar types of nanosized coordination cages. Gas sorption measurements indicate that
1
-Ln
show moderate gas uptake capacities. The UV/vis spectroscopy measurements reveal that
1
-Ln
are a class of potential materials for the removal of Cr
2
O
7
2−
from aqueous solution. Additionally, the luminescence properties of
1
-Tb
and
1
-Eu
have also been investigated.
A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters have been successfully synthesized under solvothermal conditions. |
| doi_str_mv | 10.1039/c7ce01963g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2010853469</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2010853469</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-9139627b5fac9439b1a963a5d3b74ebdd99f89eebdb9fea88a73ccb748bf2aed3</originalsourceid><addsrcrecordid>eNpVkU1PwzAMhiMEEmNw4Y4UiRtSIVm6tjmiaWyTJnGBc5W6btfRJiVJNfF_-KGEjc-TLfuxX8svIZec3XIm5B2kgIzLRNRHZMTjJIkyJsTxn_yUnDm3ZYzHnLMReV9pMLY3VvlG1xSG3prBRRvVNiVSaAfn0TqqdElbpf1G6X91bygY7bwdwNMlhprp0Ku2beAbosbWYQpoZVWHO2NfHN01fkPboWs0OkANuBeoVRAqXTjHN0bTcEmP1jfozslJpVqHF19xTJ4f5k-zZbR-XKxm9-sIBM98JLmQySQtppUCGQtZcBU-oaalKNIYi7KUssokhqyQFaosU6kACL2sqCYKSzEm14e9Qfp1QOfzrRmsDpL5hHGWTUWcyEDdHCiwxjmLVd7bplP2Lecs_3Qhn6Wz-d6FRYCvDrB18MP9uiQ-ADfniyY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2010853469</pqid></control><display><type>article</type><title>Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Liu, Jin-Hua ; Gu, Ya-Nan ; Chen, Yi ; Qi, Yan-Jie ; Li, Xin-Xiong ; Zheng, Shou-Tian</creator><creatorcontrib>Liu, Jin-Hua ; Gu, Ya-Nan ; Chen, Yi ; Qi, Yan-Jie ; Li, Xin-Xiong ; Zheng, Shou-Tian</creatorcontrib><description>A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters, [Ln
2
(H
2
O)
8
]
2
(Cu
4
I
4
)(pdc)
4
][NO
3
]
4
·solvent (
1
-Ln
, Ln = Y, Tb, Eu, H
2
pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that
1
-Ln
show fascinating three-dimensional porous framework structures constructed from two dissimilar types of nanosized coordination cages. Gas sorption measurements indicate that
1
-Ln
show moderate gas uptake capacities. The UV/vis spectroscopy measurements reveal that
1
-Ln
are a class of potential materials for the removal of Cr
2
O
7
2−
from aqueous solution. Additionally, the luminescence properties of
1
-Tb
and
1
-Eu
have also been investigated.
A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters have been successfully synthesized under solvothermal conditions.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c7ce01963g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Cages ; Clusters ; Crystals ; Luminescence ; Optical properties ; Single crystals</subject><ispartof>CrystEngComm, 2018, Vol.2 (6), p.738-745</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-9139627b5fac9439b1a963a5d3b74ebdd99f89eebdb9fea88a73ccb748bf2aed3</citedby><cites>FETCH-LOGICAL-c318t-9139627b5fac9439b1a963a5d3b74ebdd99f89eebdb9fea88a73ccb748bf2aed3</cites><orcidid>0000-0002-3365-9747 ; 0000-0002-9903-2699</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4014,27914,27915,27916</link.rule.ids></links><search><creatorcontrib>Liu, Jin-Hua</creatorcontrib><creatorcontrib>Gu, Ya-Nan</creatorcontrib><creatorcontrib>Chen, Yi</creatorcontrib><creatorcontrib>Qi, Yan-Jie</creatorcontrib><creatorcontrib>Li, Xin-Xiong</creatorcontrib><creatorcontrib>Zheng, Shou-Tian</creatorcontrib><title>Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties</title><title>CrystEngComm</title><description>A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters, [Ln
2
(H
2
O)
8
]
2
(Cu
4
I
4
)(pdc)
4
][NO
3
]
4
·solvent (
1
-Ln
, Ln = Y, Tb, Eu, H
2
pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that
1
-Ln
show fascinating three-dimensional porous framework structures constructed from two dissimilar types of nanosized coordination cages. Gas sorption measurements indicate that
1
-Ln
show moderate gas uptake capacities. The UV/vis spectroscopy measurements reveal that
1
-Ln
are a class of potential materials for the removal of Cr
2
O
7
2−
from aqueous solution. Additionally, the luminescence properties of
1
-Tb
and
1
-Eu
have also been investigated.
A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters have been successfully synthesized under solvothermal conditions.</description><subject>Cages</subject><subject>Clusters</subject><subject>Crystals</subject><subject>Luminescence</subject><subject>Optical properties</subject><subject>Single crystals</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpVkU1PwzAMhiMEEmNw4Y4UiRtSIVm6tjmiaWyTJnGBc5W6btfRJiVJNfF_-KGEjc-TLfuxX8svIZec3XIm5B2kgIzLRNRHZMTjJIkyJsTxn_yUnDm3ZYzHnLMReV9pMLY3VvlG1xSG3prBRRvVNiVSaAfn0TqqdElbpf1G6X91bygY7bwdwNMlhprp0Ku2beAbosbWYQpoZVWHO2NfHN01fkPboWs0OkANuBeoVRAqXTjHN0bTcEmP1jfozslJpVqHF19xTJ4f5k-zZbR-XKxm9-sIBM98JLmQySQtppUCGQtZcBU-oaalKNIYi7KUssokhqyQFaosU6kACL2sqCYKSzEm14e9Qfp1QOfzrRmsDpL5hHGWTUWcyEDdHCiwxjmLVd7bplP2Lecs_3Qhn6Wz-d6FRYCvDrB18MP9uiQ-ADfniyY</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Liu, Jin-Hua</creator><creator>Gu, Ya-Nan</creator><creator>Chen, Yi</creator><creator>Qi, Yan-Jie</creator><creator>Li, Xin-Xiong</creator><creator>Zheng, Shou-Tian</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3365-9747</orcidid><orcidid>https://orcid.org/0000-0002-9903-2699</orcidid></search><sort><creationdate>2018</creationdate><title>Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties</title><author>Liu, Jin-Hua ; Gu, Ya-Nan ; Chen, Yi ; Qi, Yan-Jie ; Li, Xin-Xiong ; Zheng, Shou-Tian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-9139627b5fac9439b1a963a5d3b74ebdd99f89eebdb9fea88a73ccb748bf2aed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cages</topic><topic>Clusters</topic><topic>Crystals</topic><topic>Luminescence</topic><topic>Optical properties</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Jin-Hua</creatorcontrib><creatorcontrib>Gu, Ya-Nan</creatorcontrib><creatorcontrib>Chen, Yi</creatorcontrib><creatorcontrib>Qi, Yan-Jie</creatorcontrib><creatorcontrib>Li, Xin-Xiong</creatorcontrib><creatorcontrib>Zheng, Shou-Tian</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Jin-Hua</au><au>Gu, Ya-Nan</au><au>Chen, Yi</au><au>Qi, Yan-Jie</au><au>Li, Xin-Xiong</au><au>Zheng, Shou-Tian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties</atitle><jtitle>CrystEngComm</jtitle><date>2018</date><risdate>2018</risdate><volume>2</volume><issue>6</issue><spage>738</spage><epage>745</epage><pages>738-745</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters, [Ln
2
(H
2
O)
8
]
2
(Cu
4
I
4
)(pdc)
4
][NO
3
]
4
·solvent (
1
-Ln
, Ln = Y, Tb, Eu, H
2
pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that
1
-Ln
show fascinating three-dimensional porous framework structures constructed from two dissimilar types of nanosized coordination cages. Gas sorption measurements indicate that
1
-Ln
show moderate gas uptake capacities. The UV/vis spectroscopy measurements reveal that
1
-Ln
are a class of potential materials for the removal of Cr
2
O
7
2−
from aqueous solution. Additionally, the luminescence properties of
1
-Tb
and
1
-Eu
have also been investigated.
A series of heterometallic cluster organic frameworks based on cuprous-halide Cu
4
I
4
clusters and lanthanide clusters have been successfully synthesized under solvothermal conditions.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c7ce01963g</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3365-9747</orcidid><orcidid>https://orcid.org/0000-0002-9903-2699</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018, Vol.2 (6), p.738-745 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_journals_2010853469 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cages Clusters Crystals Luminescence Optical properties Single crystals |
| title | Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties |
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