Featuring Xantphos
This review highlights the use of a bisphosphine ligand group in homogeneous catalysis. This ligand group is known as the Xantphos-like ligands, which are based on the generic formula of 2,2′-bis(phosphino)diaryl ether. The synthesis of the main members is summarized and emphasis is given to ligands...
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| Veröffentlicht in: | Catalysis science & technology 2018, Vol.8 (1), p.26-113 |
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| creator | van Leeuwen, Piet W. N. M Kamer, Paul C. J |
| description | This review highlights the use of a bisphosphine ligand group in homogeneous catalysis. This ligand group is known as the Xantphos-like ligands, which are based on the generic formula of 2,2′-bis(phosphino)diaryl ether. The synthesis of the main members is summarized and emphasis is given to ligands that can be easily synthesized, also on large scale. The catalytic applications are not comprehensively presented, but instead, about 20% of the examples from literature have been extracted, aiming at the demonstration of diversity, peculiar examples, historical development, design
vs.
trial and error, and new reactions. Metals ranging from group 7 to 11 have been used in a wide variety of reactions: hydroformylation, alkoxycarbonylation, hydrocyanation, cross-coupling reactions for many C-C and C-X bond forming reactions, carbonylative coupling reactions, phosphinations,
etc.
This review highlights the use of the bisphosphine ligand group in homogeneous catalysis. |
| doi_str_mv | 10.1039/c7cy01629h |
| format | Article |
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vs.
trial and error, and new reactions. Metals ranging from group 7 to 11 have been used in a wide variety of reactions: hydroformylation, alkoxycarbonylation, hydrocyanation, cross-coupling reactions for many C-C and C-X bond forming reactions, carbonylative coupling reactions, phosphinations,
etc.
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vs.
trial and error, and new reactions. Metals ranging from group 7 to 11 have been used in a wide variety of reactions: hydroformylation, alkoxycarbonylation, hydrocyanation, cross-coupling reactions for many C-C and C-X bond forming reactions, carbonylative coupling reactions, phosphinations,
etc.
This review highlights the use of the bisphosphine ligand group in homogeneous catalysis.</description><subject>Carbonyls</subject><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Chemical Sciences</subject><subject>Chemical synthesis</subject><subject>Coordination chemistry</subject><subject>Coupling</subject><subject>Cross coupling</subject><subject>Historical metallurgy</subject><subject>Ligands</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkE1Lw0AQhhdRsNReehcETwrRmf1Ido8lWCMEvCjoaUk2iUmpSdxNhP57t0biXGYYHl5mHkLWCHcITN2byBwAQ6rqE7KgwHnAoxBP51mwc7Jybge-uEKQdEHW2zIbRtu0H1dvWTv0decuyFmV7V25-utL8rp9eImTIH1-fIo3aWA4yiEwKHIhiwhNUdFKGlmC4pQaVoQmR6aqSFJUoIAzEECLiBehkDlKMCYXBWdLcjPl1tle97b5zOxBd1mjk02qjzugABRD_EbPXk9sb7uvsXSD3nWjbf15moL_RDBQwlO3E2Vs55wtqzkWQR8V6TiK338VJR6-nGDrzMz9K2Q_aqZeWQ</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>van Leeuwen, Piet W. N. M</creator><creator>Kamer, Paul C. J</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-2165-7090</orcidid><orcidid>https://orcid.org/0000-0002-9115-8844</orcidid></search><sort><creationdate>2018</creationdate><title>Featuring Xantphos</title><author>van Leeuwen, Piet W. N. M ; Kamer, Paul C. J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c418t-c15b58d71cdf2f8c8e09422c3d6cb139f78219090430502d74d658b180ccb5d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Carbonyls</topic><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Chemical Sciences</topic><topic>Chemical synthesis</topic><topic>Coordination chemistry</topic><topic>Coupling</topic><topic>Cross coupling</topic><topic>Historical metallurgy</topic><topic>Ligands</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>van Leeuwen, Piet W. N. M</creatorcontrib><creatorcontrib>Kamer, Paul C. J</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>van Leeuwen, Piet W. N. M</au><au>Kamer, Paul C. J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Featuring Xantphos</atitle><jtitle>Catalysis science & technology</jtitle><date>2018</date><risdate>2018</risdate><volume>8</volume><issue>1</issue><spage>26</spage><epage>113</epage><pages>26-113</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>This review highlights the use of a bisphosphine ligand group in homogeneous catalysis. This ligand group is known as the Xantphos-like ligands, which are based on the generic formula of 2,2′-bis(phosphino)diaryl ether. The synthesis of the main members is summarized and emphasis is given to ligands that can be easily synthesized, also on large scale. The catalytic applications are not comprehensively presented, but instead, about 20% of the examples from literature have been extracted, aiming at the demonstration of diversity, peculiar examples, historical development, design
vs.
trial and error, and new reactions. Metals ranging from group 7 to 11 have been used in a wide variety of reactions: hydroformylation, alkoxycarbonylation, hydrocyanation, cross-coupling reactions for many C-C and C-X bond forming reactions, carbonylative coupling reactions, phosphinations,
etc.
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| ispartof | Catalysis science & technology, 2018, Vol.8 (1), p.26-113 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Carbonyls Catalysis Chemical reactions Chemical Sciences Chemical synthesis Coordination chemistry Coupling Cross coupling Historical metallurgy Ligands |
| title | Featuring Xantphos |
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