To the homogeneity range of tris(8-hydroxyquinoline)gallium
A new technique for the analysis of p 8-Hq – T diagrams has been developed for the metal–organic phosphor tris(8-hydroxyquinoline)gallium. The detection of mono- and bivariant equilibria within the p 8-Hq – T diagram was done using simultaneous measurements of the photoluminescence and reflection sp...
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| Veröffentlicht in: | CrystEngComm 2018, Vol.20 (7), p.930-936 |
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| container_title | CrystEngComm |
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| creator | Avetissov, I. Ch Akkuzina, A. A. Kozlova, N. N. Avetisov, R. I. |
| description | A new technique for the analysis of
p
8-Hq
–
T
diagrams has been developed for the metal–organic phosphor tris(8-hydroxyquinoline)gallium. The detection of mono- and bivariant equilibria within the
p
8-Hq
–
T
diagram was done using simultaneous measurements of the photoluminescence and reflection spectra of the condensed phase under controlled
p
8-Hq
pressure and temperature. Using preparations with purity better 99.9988 wt%, the S
i-Gaq3
S
j-Gaq3
V and S
i-Gaq3
LV equilibria were studied and the corresponding
p
8-Hq
–
T
diagram was plotted in the 408–665 K temperature range. For the α-Gaq
3
, it was demonstrated that changing the synthesis conditions within the homogeneity range of the phase resulted in change in the cell volume, chemical activity and electrical properties of crystalline preparation and thin layers deposited due to it. |
| doi_str_mv | 10.1039/C7CE02092A |
| format | Article |
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p
8-Hq
–
T
diagrams has been developed for the metal–organic phosphor tris(8-hydroxyquinoline)gallium. The detection of mono- and bivariant equilibria within the
p
8-Hq
–
T
diagram was done using simultaneous measurements of the photoluminescence and reflection spectra of the condensed phase under controlled
p
8-Hq
pressure and temperature. Using preparations with purity better 99.9988 wt%, the S
i-Gaq3
S
j-Gaq3
V and S
i-Gaq3
LV equilibria were studied and the corresponding
p
8-Hq
–
T
diagram was plotted in the 408–665 K temperature range. For the α-Gaq
3
, it was demonstrated that changing the synthesis conditions within the homogeneity range of the phase resulted in change in the cell volume, chemical activity and electrical properties of crystalline preparation and thin layers deposited due to it.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/C7CE02092A</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical activity ; Electrical properties ; Gallium ; Homogeneity ; Hydroxyquinoline ; Phase transitions ; Photoluminescence ; Thin films</subject><ispartof>CrystEngComm, 2018, Vol.20 (7), p.930-936</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-c16387d82059bdd441a449c6da117fa57352f55e56de2fa855c0a10bc7013c83</citedby><cites>FETCH-LOGICAL-c259t-c16387d82059bdd441a449c6da117fa57352f55e56de2fa855c0a10bc7013c83</cites><orcidid>0000-0002-6836-798X ; 0000-0001-6781-391X ; 0000-0002-4712-409X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>Avetissov, I. Ch</creatorcontrib><creatorcontrib>Akkuzina, A. A.</creatorcontrib><creatorcontrib>Kozlova, N. N.</creatorcontrib><creatorcontrib>Avetisov, R. I.</creatorcontrib><title>To the homogeneity range of tris(8-hydroxyquinoline)gallium</title><title>CrystEngComm</title><description>A new technique for the analysis of
p
8-Hq
–
T
diagrams has been developed for the metal–organic phosphor tris(8-hydroxyquinoline)gallium. The detection of mono- and bivariant equilibria within the
p
8-Hq
–
T
diagram was done using simultaneous measurements of the photoluminescence and reflection spectra of the condensed phase under controlled
p
8-Hq
pressure and temperature. Using preparations with purity better 99.9988 wt%, the S
i-Gaq3
S
j-Gaq3
V and S
i-Gaq3
LV equilibria were studied and the corresponding
p
8-Hq
–
T
diagram was plotted in the 408–665 K temperature range. For the α-Gaq
3
, it was demonstrated that changing the synthesis conditions within the homogeneity range of the phase resulted in change in the cell volume, chemical activity and electrical properties of crystalline preparation and thin layers deposited due to it.</description><subject>Chemical activity</subject><subject>Electrical properties</subject><subject>Gallium</subject><subject>Homogeneity</subject><subject>Hydroxyquinoline</subject><subject>Phase transitions</subject><subject>Photoluminescence</subject><subject>Thin films</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLw0AUhQdRsFY3_oKAGxWi984jM8FVCfUBBTfZh-lk8ihJpp1JwPx7LRV0dc7i4xz4CLlFeEJg6XMmszVQSOnqjCyQJ0msgLHzf_2SXIWwA0COCAvykrtobGzUuN7VdrDtOEdeD7WNXBWNvg33Km7m0ruv-TC1g-vawT7Uuuvaqb8mF5Xugr35zSXJX9d59h5vPt8-stUmNlSkY2wwYUqWioJIt2XJOWrOU5OUGlFWWkgmaCWEFUlpaaWVEAY0wtZIQGYUW5K70-zeu8Nkw1js3OSHn8eCAoLiTMKRejxRxrsQvK2KvW977ecCoTi6Kf7csG-ew1UW</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Avetissov, I. Ch</creator><creator>Akkuzina, A. A.</creator><creator>Kozlova, N. N.</creator><creator>Avetisov, R. I.</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6836-798X</orcidid><orcidid>https://orcid.org/0000-0001-6781-391X</orcidid><orcidid>https://orcid.org/0000-0002-4712-409X</orcidid></search><sort><creationdate>2018</creationdate><title>To the homogeneity range of tris(8-hydroxyquinoline)gallium</title><author>Avetissov, I. Ch ; Akkuzina, A. A. ; Kozlova, N. N. ; Avetisov, R. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-c16387d82059bdd441a449c6da117fa57352f55e56de2fa855c0a10bc7013c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemical activity</topic><topic>Electrical properties</topic><topic>Gallium</topic><topic>Homogeneity</topic><topic>Hydroxyquinoline</topic><topic>Phase transitions</topic><topic>Photoluminescence</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Avetissov, I. Ch</creatorcontrib><creatorcontrib>Akkuzina, A. A.</creatorcontrib><creatorcontrib>Kozlova, N. N.</creatorcontrib><creatorcontrib>Avetisov, R. I.</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Avetissov, I. Ch</au><au>Akkuzina, A. A.</au><au>Kozlova, N. N.</au><au>Avetisov, R. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>To the homogeneity range of tris(8-hydroxyquinoline)gallium</atitle><jtitle>CrystEngComm</jtitle><date>2018</date><risdate>2018</risdate><volume>20</volume><issue>7</issue><spage>930</spage><epage>936</epage><pages>930-936</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>A new technique for the analysis of
p
8-Hq
–
T
diagrams has been developed for the metal–organic phosphor tris(8-hydroxyquinoline)gallium. The detection of mono- and bivariant equilibria within the
p
8-Hq
–
T
diagram was done using simultaneous measurements of the photoluminescence and reflection spectra of the condensed phase under controlled
p
8-Hq
pressure and temperature. Using preparations with purity better 99.9988 wt%, the S
i-Gaq3
S
j-Gaq3
V and S
i-Gaq3
LV equilibria were studied and the corresponding
p
8-Hq
–
T
diagram was plotted in the 408–665 K temperature range. For the α-Gaq
3
, it was demonstrated that changing the synthesis conditions within the homogeneity range of the phase resulted in change in the cell volume, chemical activity and electrical properties of crystalline preparation and thin layers deposited due to it.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C7CE02092A</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6836-798X</orcidid><orcidid>https://orcid.org/0000-0001-6781-391X</orcidid><orcidid>https://orcid.org/0000-0002-4712-409X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018, Vol.20 (7), p.930-936 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_journals_2010843708 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical activity Electrical properties Gallium Homogeneity Hydroxyquinoline Phase transitions Photoluminescence Thin films |
| title | To the homogeneity range of tris(8-hydroxyquinoline)gallium |
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