Ultrastable red-emitting phosphor-in-glass for superior high-power artificial plant growth LEDs

Ultrastable red-emitting phosphor-in-glass (PiG) consisting of 3.5MgO·0.5MgF 2 ·GeO 2 :Mn 4+ (MMG:Mn 4+ ) phosphor in a glass matrix was prepared for superior artificial plant growth LEDs (PGLs). These obtained PiG plates show a thermal conductivity of 1.671 W m −1 K −1 and an external quantum effic...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018, Vol.6 (7), p.1738-1745
Hauptverfasser: Deng, Jiankun, Zhang, Haoran, Zhang, Xuejie, Zheng, Yinjian, Yuan, Junqiang, Liu, Hongzhong, Liu, Yingliang, Lei, Bingfu, Qiu, Jianbei
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container_issue 7
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container_title Journal of materials chemistry. C, Materials for optical and electronic devices
container_volume 6
creator Deng, Jiankun
Zhang, Haoran
Zhang, Xuejie
Zheng, Yinjian
Yuan, Junqiang
Liu, Hongzhong
Liu, Yingliang
Lei, Bingfu
Qiu, Jianbei
description Ultrastable red-emitting phosphor-in-glass (PiG) consisting of 3.5MgO·0.5MgF 2 ·GeO 2 :Mn 4+ (MMG:Mn 4+ ) phosphor in a glass matrix was prepared for superior artificial plant growth LEDs (PGLs). These obtained PiG plates show a thermal conductivity of 1.671 W m −1 K −1 and an external quantum efficiency of 27.5%, which provides the strong foundation for the application in high-power artificial plant growth LEDs (PGLs). Furthermore, a proof-of-concept PGL using 36 pieces of the title PiG plate and 420 nm-blue LED chip was fabricated. The combination of ∼420 nm from chip and the ∼659 nm chip from the MMG:Mn 4+ phosphor provide a well-matched spectrum with the absorption bands of photosynthetic pigments and the phytochrome ( P R and P FR ) of most green plants. As expected, the as-fabricated PGL-treated milk-Chinese cabbage cultured in the indoor plant factory showed that after 15 day-irradiation, the plant biomass was nearly 48.9% greater in treated sample than those cultured using the general R-B LED lamps. Further analysis also demonstrated that promotive effect can also be obtained in the level of ascorbic acid, soluble protein, soluble sugar and total chlorophyll. The PiG strategy presented in this paper afforded superior high-power artificial plant growth LEDs, which are crucial in the application of ecological agriculture. Red-emitting phosphor-in-glass with excellent thermal stability was prepared, showing great potential for high-power LED plant-growth lamps with high color stability.
doi_str_mv 10.1039/c7tc05250b
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These obtained PiG plates show a thermal conductivity of 1.671 W m −1 K −1 and an external quantum efficiency of 27.5%, which provides the strong foundation for the application in high-power artificial plant growth LEDs (PGLs). Furthermore, a proof-of-concept PGL using 36 pieces of the title PiG plate and 420 nm-blue LED chip was fabricated. The combination of ∼420 nm from chip and the ∼659 nm chip from the MMG:Mn 4+ phosphor provide a well-matched spectrum with the absorption bands of photosynthetic pigments and the phytochrome ( P R and P FR ) of most green plants. As expected, the as-fabricated PGL-treated milk-Chinese cabbage cultured in the indoor plant factory showed that after 15 day-irradiation, the plant biomass was nearly 48.9% greater in treated sample than those cultured using the general R-B LED lamps. Further analysis also demonstrated that promotive effect can also be obtained in the level of ascorbic acid, soluble protein, soluble sugar and total chlorophyll. 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C, Materials for optical and electronic devices</jtitle><date>2018</date><risdate>2018</risdate><volume>6</volume><issue>7</issue><spage>1738</spage><epage>1745</epage><pages>1738-1745</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Ultrastable red-emitting phosphor-in-glass (PiG) consisting of 3.5MgO·0.5MgF 2 ·GeO 2 :Mn 4+ (MMG:Mn 4+ ) phosphor in a glass matrix was prepared for superior artificial plant growth LEDs (PGLs). These obtained PiG plates show a thermal conductivity of 1.671 W m −1 K −1 and an external quantum efficiency of 27.5%, which provides the strong foundation for the application in high-power artificial plant growth LEDs (PGLs). Furthermore, a proof-of-concept PGL using 36 pieces of the title PiG plate and 420 nm-blue LED chip was fabricated. 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subjects Absorption spectra
Ascorbic acid
Chinese cabbage
Diodes
Germanium oxides
Light emitting diodes
Photosynthesis
Pigments
Plant growth
Quantum efficiency
Thermal conductivity
title Ultrastable red-emitting phosphor-in-glass for superior high-power artificial plant growth LEDs
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