Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate
Two new IB group metal coordination polymers, namely, {[Cu 3 (TFMIDC) 2 (H 2 O) 2 ] · 4H 2 O}n (I) and [Ag 2 (HTFMIDC)(Py)] n (II) (H 3 TFMIDC = 2-(trifluoromethyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine), have been successfully prepared and structurally characterized by different techniq...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2018, Vol.44 (1), p.64-71 |
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| container_title | Russian journal of coordination chemistry |
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| creator | Cai, S. L. Lin, H. M. Yang, J. R. He, Z. Q. Fu, S. Q. Xu, Z. B. Zheng, S. R. Zhang, W. G. |
| description | Two new IB group metal coordination polymers, namely, {[Cu
3
(TFMIDC)
2
(H
2
O)
2
] · 4H
2
O}n (I) and [Ag
2
(HTFMIDC)(Py)]
n
(II) (H
3
TFMIDC = 2-(trifluoromethyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine), have been successfully prepared and structurally characterized by different techniques including single crystal X-ray diffraction (CIF files CCDC nos. 1545402 (I) and 1545403 (II)), IR spectra, and powder X-ray diffraction. Compound I features an interesting two-dimentional (2D) sheet containing 1D left-handed and right-handed helical chains, while compound II exhibits an infinite 1D zig–zag chain structure. Both two coordination polymers further stack through weak interactions to give rise to 3D supramolecular frameworks. Furthermore, the thermal stabilities of I and II as well as the photoluminescent property of II were also studied. |
| doi_str_mv | 10.1134/S1070328418010025 |
| format | Article |
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3
(TFMIDC)
2
(H
2
O)
2
] · 4H
2
O}n (I) and [Ag
2
(HTFMIDC)(Py)]
n
(II) (H
3
TFMIDC = 2-(trifluoromethyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine), have been successfully prepared and structurally characterized by different techniques including single crystal X-ray diffraction (CIF files CCDC nos. 1545402 (I) and 1545403 (II)), IR spectra, and powder X-ray diffraction. Compound I features an interesting two-dimentional (2D) sheet containing 1D left-handed and right-handed helical chains, while compound II exhibits an infinite 1D zig–zag chain structure. Both two coordination polymers further stack through weak interactions to give rise to 3D supramolecular frameworks. Furthermore, the thermal stabilities of I and II as well as the photoluminescent property of II were also studied.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328418010025</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Crystal structure ; Diffraction ; Imidazole ; Infrared spectroscopy ; Inorganic Chemistry ; Photoluminescence ; Physical Chemistry ; Polymers ; Single crystals ; Supramolecular frameworks ; X ray powder diffraction ; X-ray diffraction ; X-rays</subject><ispartof>Russian journal of coordination chemistry, 2018, Vol.44 (1), p.64-71</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-8a51b60378c0548be52c9ed9c30dc86602238dc5499aad2b565603b43150994b3</citedby><cites>FETCH-LOGICAL-c316t-8a51b60378c0548be52c9ed9c30dc86602238dc5499aad2b565603b43150994b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328418010025$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328418010025$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Cai, S. L.</creatorcontrib><creatorcontrib>Lin, H. M.</creatorcontrib><creatorcontrib>Yang, J. R.</creatorcontrib><creatorcontrib>He, Z. Q.</creatorcontrib><creatorcontrib>Fu, S. Q.</creatorcontrib><creatorcontrib>Xu, Z. B.</creatorcontrib><creatorcontrib>Zheng, S. R.</creatorcontrib><creatorcontrib>Zhang, W. G.</creatorcontrib><title>Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Two new IB group metal coordination polymers, namely, {[Cu
3
(TFMIDC)
2
(H
2
O)
2
] · 4H
2
O}n (I) and [Ag
2
(HTFMIDC)(Py)]
n
(II) (H
3
TFMIDC = 2-(trifluoromethyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine), have been successfully prepared and structurally characterized by different techniques including single crystal X-ray diffraction (CIF files CCDC nos. 1545402 (I) and 1545403 (II)), IR spectra, and powder X-ray diffraction. Compound I features an interesting two-dimentional (2D) sheet containing 1D left-handed and right-handed helical chains, while compound II exhibits an infinite 1D zig–zag chain structure. Both two coordination polymers further stack through weak interactions to give rise to 3D supramolecular frameworks. Furthermore, the thermal stabilities of I and II as well as the photoluminescent property of II were also studied.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Diffraction</subject><subject>Imidazole</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Photoluminescence</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Single crystals</subject><subject>Supramolecular frameworks</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KAzEUhYMoqNUHcBdwo9BofibTzFLrTwsVhdb1kMmkOmU6qTcZdHwP39cMFVyIq3u553znwkHohNELxkRyOWd0RAVXCVOUUcrlDjpgKVVECKZ24x5l0uv76ND7Fe1NMjtAX_OuCa_WWz_EY-h80DWeB2hNaKG_6abET-A2FkJlPXZLvHh3eHqN78G1G_xge2DsHJRVo0PlGvzk6m5tweNr7W2J44WTswVUy7p14NY2vHb1OWETMl1Xpf50tSXJUJKbymgo3EdX62CP0N5S194e_8wBer67XYwnZPZ4Px1fzYgRLA1EacmKlIqRMlQmqrCSm8yWmRG0NCpNKedClUYmWaZ1yQuZyuguEsEkzbKkEAN0us3dgHtrrQ_5yrXQxJc5jw0lbCQiMEBs6zLgvAe7zDdQrTV0OaN5337-p_3I8C3jo7d5sfCb_D_0DX44hcs</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Cai, S. L.</creator><creator>Lin, H. M.</creator><creator>Yang, J. R.</creator><creator>He, Z. Q.</creator><creator>Fu, S. Q.</creator><creator>Xu, Z. B.</creator><creator>Zheng, S. R.</creator><creator>Zhang, W. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2018</creationdate><title>Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate</title><author>Cai, S. L. ; Lin, H. M. ; Yang, J. R. ; He, Z. Q. ; Fu, S. Q. ; Xu, Z. B. ; Zheng, S. R. ; Zhang, W. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-8a51b60378c0548be52c9ed9c30dc86602238dc5499aad2b565603b43150994b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Diffraction</topic><topic>Imidazole</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Photoluminescence</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Single crystals</topic><topic>Supramolecular frameworks</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cai, S. L.</creatorcontrib><creatorcontrib>Lin, H. M.</creatorcontrib><creatorcontrib>Yang, J. R.</creatorcontrib><creatorcontrib>He, Z. Q.</creatorcontrib><creatorcontrib>Fu, S. Q.</creatorcontrib><creatorcontrib>Xu, Z. B.</creatorcontrib><creatorcontrib>Zheng, S. R.</creatorcontrib><creatorcontrib>Zhang, W. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cai, S. L.</au><au>Lin, H. M.</au><au>Yang, J. R.</au><au>He, Z. Q.</au><au>Fu, S. Q.</au><au>Xu, Z. B.</au><au>Zheng, S. R.</au><au>Zhang, W. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2018</date><risdate>2018</risdate><volume>44</volume><issue>1</issue><spage>64</spage><epage>71</epage><pages>64-71</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Two new IB group metal coordination polymers, namely, {[Cu
3
(TFMIDC)
2
(H
2
O)
2
] · 4H
2
O}n (I) and [Ag
2
(HTFMIDC)(Py)]
n
(II) (H
3
TFMIDC = 2-(trifluoromethyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine), have been successfully prepared and structurally characterized by different techniques including single crystal X-ray diffraction (CIF files CCDC nos. 1545402 (I) and 1545403 (II)), IR spectra, and powder X-ray diffraction. Compound I features an interesting two-dimentional (2D) sheet containing 1D left-handed and right-handed helical chains, while compound II exhibits an infinite 1D zig–zag chain structure. Both two coordination polymers further stack through weak interactions to give rise to 3D supramolecular frameworks. Furthermore, the thermal stabilities of I and II as well as the photoluminescent property of II were also studied.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328418010025</doi><tpages>8</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Coordination polymers Crystal structure Diffraction Imidazole Infrared spectroscopy Inorganic Chemistry Photoluminescence Physical Chemistry Polymers Single crystals Supramolecular frameworks X ray powder diffraction X-ray diffraction X-rays |
| title | Syntheses, Crystal Structures, and Properties of Two IB Group Metal Coordination Polymers Based on 2-(Trifluoromethyl)-1H-Imidazole-4,5-Dicarboxylate |
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