Compositional Evolution of Pyrochlore-Group Minerals in Carbonatites of the Belaya Zima Pluton, Eastern Sayan

Pyrochlore-group minerals are the main concentrators of niobium in carbonatites of the Belaya Zima alkaline pluton. Fluorcalciopyrochlore, kenopyrochlore and hydropyrochlore were identified in chemical composition. Their main characteristics are given: compositional variation, morphology, and zoning...

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Veröffentlicht in:Geology of ore deposits 2017-12, Vol.59 (8), p.752-764
Hauptverfasser: Khromova, E. A., Doroshkevich, A. G., Sharygin, V. V., Izbrodin, L. A.
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container_issue 8
container_start_page 752
container_title Geology of ore deposits
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creator Khromova, E. A.
Doroshkevich, A. G.
Sharygin, V. V.
Izbrodin, L. A.
description Pyrochlore-group minerals are the main concentrators of niobium in carbonatites of the Belaya Zima alkaline pluton. Fluorcalciopyrochlore, kenopyrochlore and hydropyrochlore were identified in chemical composition. Their main characteristics are given: compositional variation, morphology, and zoning. During evolution from early calcite to late ankerite carbonatites, the UO 2 , TiO 2 , REE, and Y contents gradually increased. All carbonatite types are suggested to contain initial fluorcalciopyrochlore. However, in calcite–dolomite and ankerite carbonatites, it is partially or completely hydrated due to hydrothermal processes at the late stage of the pluton. This hydration resulted in the appearance of kenopyrochlore and hydropyrochlore due to removal of Ca, Na and F, and input of Ba, H 2 O, K, Si, Fe, and probably U and REE. At the last stage of the pluton, this hydrated pyrochlore was replaced by Fe-bearing columbite.
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This hydration resulted in the appearance of kenopyrochlore and hydropyrochlore due to removal of Ca, Na and F, and input of Ba, H 2 O, K, Si, Fe, and probably U and REE. 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subjects Calcite
Composition
Concentrators
Dolomite
Dolostone
Earth and Environmental Science
Earth Sciences
Evolution
Hydrothermal activity
Iron
Mineral Resources
Minerals
Minerals and Mineral Parageneses
Niobium
Plutons
Pyrochlores
Removal
Titanium dioxide
Uranium dioxide
title Compositional Evolution of Pyrochlore-Group Minerals in Carbonatites of the Belaya Zima Pluton, Eastern Sayan
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