Study of Gaseous Sample Ionization by Excited Particles Formed in Glow Discharge Using High-Resolution Orthogonal Acceleration Time-of-Flight Mass Spectrometer
The experimental results of a mass spectral analysis of volatile organic compounds in a gaseous sample, obtained using an original design of an ion source based on the Penning ionization of a gas sample by excited metastable inert gas atoms, are presented. Using ANSYS software, a gas-dynamic simulat...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2017-12, Vol.72 (13), p.1331-1339 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
| container_volume | 72 |
| creator | Sulimenkov, I. V. Brusov, V. S. Zelenov, V. V. Skoblin, M. G. Filatov, V. V. Pikhtelev, A. R. Kozlovskii, V. I. |
| description | The experimental results of a mass spectral analysis of volatile organic compounds in a gaseous sample, obtained using an original design of an ion source based on the Penning ionization of a gas sample by excited metastable inert gas atoms, are presented. Using ANSYS software, a gas-dynamic simulation of reagent gas flow from discharge zone to ionization region was carried out to analyze the effect of gas flow profile on the transport of metastable atoms and ionization efficiency. The
n
-octane and toluene samples diluted with helium at 100 ppb mole concentrations were used for our experiments. The resulting mass spectra of
n
-octane and toluene samples containe far more intensive molecular ions in comparison to
n
-octane and toluene electron ionization mass spectra from the NIST database. The sensitivity of 5 ions per 1 pg and 130 ions per 1 pg was achieved for
n
-octane and toluene molecular ions using the developed ion source combined with our mass spectrometer. The corresponding detection limits are 2.3 pg s
–1
for n-octane molecular ions and 0.08 pg s
–1
for toluene molecular ions. The detection limit for the reported ion source was considered theoretically. |
| doi_str_mv | 10.1134/S1061934817130111 |
| format | Article |
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n
-octane and toluene samples diluted with helium at 100 ppb mole concentrations were used for our experiments. The resulting mass spectra of
n
-octane and toluene samples containe far more intensive molecular ions in comparison to
n
-octane and toluene electron ionization mass spectra from the NIST database. The sensitivity of 5 ions per 1 pg and 130 ions per 1 pg was achieved for
n
-octane and toluene molecular ions using the developed ion source combined with our mass spectrometer. The corresponding detection limits are 2.3 pg s
–1
for n-octane molecular ions and 0.08 pg s
–1
for toluene molecular ions. The detection limit for the reported ion source was considered theoretically.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934817130111</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analytical Chemistry ; CAD ; Chemistry ; Chemistry and Materials Science ; Computer aided design ; Dilution ; Discharge ; Gas flow ; Gas sampling ; Helium ; Ionization ; Ions ; Mass spectra ; Mass spectrometry ; Mass spectroscopy ; Metastable atoms ; Molecular ions ; Organic compounds ; Penning ionization ; Properties ; Quantitative analysis ; Rare gases ; Toluene ; VOCs ; Volatile organic compounds</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2017-12, Vol.72 (13), p.1331-1339</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c455t-57c23080d7f80dcc8662f1845bb88a2a91544de02a0b273c8ba92474824c51233</citedby><cites>FETCH-LOGICAL-c455t-57c23080d7f80dcc8662f1845bb88a2a91544de02a0b273c8ba92474824c51233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934817130111$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934817130111$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sulimenkov, I. V.</creatorcontrib><creatorcontrib>Brusov, V. S.</creatorcontrib><creatorcontrib>Zelenov, V. V.</creatorcontrib><creatorcontrib>Skoblin, M. G.</creatorcontrib><creatorcontrib>Filatov, V. V.</creatorcontrib><creatorcontrib>Pikhtelev, A. R.</creatorcontrib><creatorcontrib>Kozlovskii, V. I.</creatorcontrib><title>Study of Gaseous Sample Ionization by Excited Particles Formed in Glow Discharge Using High-Resolution Orthogonal Acceleration Time-of-Flight Mass Spectrometer</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>The experimental results of a mass spectral analysis of volatile organic compounds in a gaseous sample, obtained using an original design of an ion source based on the Penning ionization of a gas sample by excited metastable inert gas atoms, are presented. Using ANSYS software, a gas-dynamic simulation of reagent gas flow from discharge zone to ionization region was carried out to analyze the effect of gas flow profile on the transport of metastable atoms and ionization efficiency. The
n
-octane and toluene samples diluted with helium at 100 ppb mole concentrations were used for our experiments. The resulting mass spectra of
n
-octane and toluene samples containe far more intensive molecular ions in comparison to
n
-octane and toluene electron ionization mass spectra from the NIST database. The sensitivity of 5 ions per 1 pg and 130 ions per 1 pg was achieved for
n
-octane and toluene molecular ions using the developed ion source combined with our mass spectrometer. The corresponding detection limits are 2.3 pg s
–1
for n-octane molecular ions and 0.08 pg s
–1
for toluene molecular ions. The detection limit for the reported ion source was considered theoretically.</description><subject>Analytical Chemistry</subject><subject>CAD</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Computer aided design</subject><subject>Dilution</subject><subject>Discharge</subject><subject>Gas flow</subject><subject>Gas sampling</subject><subject>Helium</subject><subject>Ionization</subject><subject>Ions</subject><subject>Mass spectra</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>Metastable atoms</subject><subject>Molecular ions</subject><subject>Organic compounds</subject><subject>Penning ionization</subject><subject>Properties</subject><subject>Quantitative analysis</subject><subject>Rare gases</subject><subject>Toluene</subject><subject>VOCs</subject><subject>Volatile organic compounds</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1klFr2zAQx83YYF23D7A3wZ724FYnybb8GLomDXR0NO2zkZWzoyJbmSTTZl9mX7XqMihhGQLpuPv9_9yJy7LPQM8AuDhfAS2h5kJCBZwCwJvsBEoqcw51_TbFqZy_1N9nH0J4oJTWEsqT7PcqTusdcR1ZqIBuCmSlhq1FsnSj-aWicSNpd-TySZuIa_JD-Wi0xUDmzg8pYUaysO6RfDNBb5TvkdwHM_bkyvSb_BaDs9MfjxsfN653o7JkpjVa9HvvOzNg7rp8bpMgku8qpA62qKN3A0b0H7N3nbIBP_19T7P7-eXdxVV-fbNYXsyucy2KIuZFpRmnkq6rLl1ay7JkHUhRtK2UiqkaCiHWSJmiLau4lq2qmaiEZEIXwDg_zb7sfbfe_ZwwxObBTT61GxpGqRRcVBV9pXplsTFj56JXekizN7OCg6hLKqpE5UeoHsc0tHUjdialD_izI3w6axyMPir4eiBITMSn2KsphGa5uj1kYc9q70Lw2DVbbwbldw3Q5mV1mn9WJ2nYXhMSO_boXz_j_6JnvwTDbA</recordid><startdate>20171215</startdate><enddate>20171215</enddate><creator>Sulimenkov, I. V.</creator><creator>Brusov, V. S.</creator><creator>Zelenov, V. V.</creator><creator>Skoblin, M. G.</creator><creator>Filatov, V. V.</creator><creator>Pikhtelev, A. R.</creator><creator>Kozlovskii, V. I.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20171215</creationdate><title>Study of Gaseous Sample Ionization by Excited Particles Formed in Glow Discharge Using High-Resolution Orthogonal Acceleration Time-of-Flight Mass Spectrometer</title><author>Sulimenkov, I. V. ; Brusov, V. S. ; Zelenov, V. V. ; Skoblin, M. G. ; Filatov, V. V. ; Pikhtelev, A. R. ; Kozlovskii, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c455t-57c23080d7f80dcc8662f1845bb88a2a91544de02a0b273c8ba92474824c51233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analytical Chemistry</topic><topic>CAD</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Computer aided design</topic><topic>Dilution</topic><topic>Discharge</topic><topic>Gas flow</topic><topic>Gas sampling</topic><topic>Helium</topic><topic>Ionization</topic><topic>Ions</topic><topic>Mass spectra</topic><topic>Mass spectrometry</topic><topic>Mass spectroscopy</topic><topic>Metastable atoms</topic><topic>Molecular ions</topic><topic>Organic compounds</topic><topic>Penning ionization</topic><topic>Properties</topic><topic>Quantitative analysis</topic><topic>Rare gases</topic><topic>Toluene</topic><topic>VOCs</topic><topic>Volatile organic compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sulimenkov, I. V.</creatorcontrib><creatorcontrib>Brusov, V. S.</creatorcontrib><creatorcontrib>Zelenov, V. V.</creatorcontrib><creatorcontrib>Skoblin, M. G.</creatorcontrib><creatorcontrib>Filatov, V. V.</creatorcontrib><creatorcontrib>Pikhtelev, A. R.</creatorcontrib><creatorcontrib>Kozlovskii, V. I.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sulimenkov, I. V.</au><au>Brusov, V. S.</au><au>Zelenov, V. V.</au><au>Skoblin, M. G.</au><au>Filatov, V. V.</au><au>Pikhtelev, A. R.</au><au>Kozlovskii, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of Gaseous Sample Ionization by Excited Particles Formed in Glow Discharge Using High-Resolution Orthogonal Acceleration Time-of-Flight Mass Spectrometer</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2017-12-15</date><risdate>2017</risdate><volume>72</volume><issue>13</issue><spage>1331</spage><epage>1339</epage><pages>1331-1339</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>The experimental results of a mass spectral analysis of volatile organic compounds in a gaseous sample, obtained using an original design of an ion source based on the Penning ionization of a gas sample by excited metastable inert gas atoms, are presented. Using ANSYS software, a gas-dynamic simulation of reagent gas flow from discharge zone to ionization region was carried out to analyze the effect of gas flow profile on the transport of metastable atoms and ionization efficiency. The
n
-octane and toluene samples diluted with helium at 100 ppb mole concentrations were used for our experiments. The resulting mass spectra of
n
-octane and toluene samples containe far more intensive molecular ions in comparison to
n
-octane and toluene electron ionization mass spectra from the NIST database. The sensitivity of 5 ions per 1 pg and 130 ions per 1 pg was achieved for
n
-octane and toluene molecular ions using the developed ion source combined with our mass spectrometer. The corresponding detection limits are 2.3 pg s
–1
for n-octane molecular ions and 0.08 pg s
–1
for toluene molecular ions. The detection limit for the reported ion source was considered theoretically.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934817130111</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 1061-9348 |
| ispartof | Journal of analytical chemistry (New York, N.Y.), 2017-12, Vol.72 (13), p.1331-1339 |
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| language | eng |
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| source | SpringerNature Journals |
| subjects | Analytical Chemistry CAD Chemistry Chemistry and Materials Science Computer aided design Dilution Discharge Gas flow Gas sampling Helium Ionization Ions Mass spectra Mass spectrometry Mass spectroscopy Metastable atoms Molecular ions Organic compounds Penning ionization Properties Quantitative analysis Rare gases Toluene VOCs Volatile organic compounds |
| title | Study of Gaseous Sample Ionization by Excited Particles Formed in Glow Discharge Using High-Resolution Orthogonal Acceleration Time-of-Flight Mass Spectrometer |
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