Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature
A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a ran...
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Veröffentlicht in: | Applied organometallic chemistry 2018-03, Vol.32 (3), p.n/a |
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creator | Wang, Guofang Meng, Mengting Deng, Liping Cheng, Kai Qi, Chenze |
description | A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.
A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen. |
doi_str_mv | 10.1002/aoc.4203 |
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A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.4203</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>arylhydrazide hydrochlorides ; aryltrifluoroborates ; Chemistry ; Cobalt ; Coupling ; Hydrochlorides ; Palladium ; Room temperature ; Suzuki‐type cross‐coupling ; water ; water‐soluble Pd‐catalyzed</subject><ispartof>Applied organometallic chemistry, 2018-03, Vol.32 (3), p.n/a</ispartof><rights>Copyright © 2017 John Wiley & Sons, Ltd.</rights><rights>Copyright © 2018 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3303-1bcc94b5c8b590f4206637f27e9a26137d75f2762985c8028248be0216a7aac43</citedby><cites>FETCH-LOGICAL-c3303-1bcc94b5c8b590f4206637f27e9a26137d75f2762985c8028248be0216a7aac43</cites><orcidid>0000-0002-7080-8270</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.4203$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.4203$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Wang, Guofang</creatorcontrib><creatorcontrib>Meng, Mengting</creatorcontrib><creatorcontrib>Deng, Liping</creatorcontrib><creatorcontrib>Cheng, Kai</creatorcontrib><creatorcontrib>Qi, Chenze</creatorcontrib><title>Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature</title><title>Applied organometallic chemistry</title><description>A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.
A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.</description><subject>arylhydrazide hydrochlorides</subject><subject>aryltrifluoroborates</subject><subject>Chemistry</subject><subject>Cobalt</subject><subject>Coupling</subject><subject>Hydrochlorides</subject><subject>Palladium</subject><subject>Room temperature</subject><subject>Suzuki‐type cross‐coupling</subject><subject>water</subject><subject>water‐soluble Pd‐catalyzed</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kEtOwzAQhi0EEqUgcQRLbNikHdt5LqvwlCoV8RBLy3Ecakjj4MSgdMURWHM8ToJL2bLx2DOf_pE_hI4JTAgAnQojJyEFtoNGBLIsgIRlu2gENE4DGkO0jw667hkAspiEI_R1phrdW_OkGtHrN4Vvymnuvj8-pehFPaxVie_c2r1o3-qHVuHcmq7bzI1ra908YVPhmR3q3uqqdsaawljRqw6_6375O1kOpRVr3Sh85W9GLmtjdekJ3eBHj1rsmtKft8as8L1atcoHOKsO0V4l6k4d_dUxerg4v8-vgvni8jqfzQPJGLCAFFJmYRHJtIgyqPzf45glFU1UJmhMWFImkX_FNEs9AzSlYVoooCQWiRAyZGN0ss1trXl1quv5s3G28Ss5Ba-PpSSMPHW6peRGgFUVb61eCTtwAnxjnnvzfGPeo8EWfde1Gv7l-GyR__I_FI6KiA</recordid><startdate>201803</startdate><enddate>201803</enddate><creator>Wang, Guofang</creator><creator>Meng, Mengting</creator><creator>Deng, Liping</creator><creator>Cheng, Kai</creator><creator>Qi, Chenze</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7080-8270</orcidid></search><sort><creationdate>201803</creationdate><title>Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature</title><author>Wang, Guofang ; Meng, Mengting ; Deng, Liping ; Cheng, Kai ; Qi, Chenze</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3303-1bcc94b5c8b590f4206637f27e9a26137d75f2762985c8028248be0216a7aac43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>arylhydrazide hydrochlorides</topic><topic>aryltrifluoroborates</topic><topic>Chemistry</topic><topic>Cobalt</topic><topic>Coupling</topic><topic>Hydrochlorides</topic><topic>Palladium</topic><topic>Room temperature</topic><topic>Suzuki‐type cross‐coupling</topic><topic>water</topic><topic>water‐soluble Pd‐catalyzed</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Guofang</creatorcontrib><creatorcontrib>Meng, Mengting</creatorcontrib><creatorcontrib>Deng, Liping</creatorcontrib><creatorcontrib>Cheng, Kai</creatorcontrib><creatorcontrib>Qi, Chenze</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Guofang</au><au>Meng, Mengting</au><au>Deng, Liping</au><au>Cheng, Kai</au><au>Qi, Chenze</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2018-03</date><risdate>2018</risdate><volume>32</volume><issue>3</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.
A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.4203</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-7080-8270</orcidid></addata></record> |
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subjects | arylhydrazide hydrochlorides aryltrifluoroborates Chemistry Cobalt Coupling Hydrochlorides Palladium Room temperature Suzuki‐type cross‐coupling water water‐soluble Pd‐catalyzed |
title | Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature |
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