Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature

A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a ran...

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Veröffentlicht in:Applied organometallic chemistry 2018-03, Vol.32 (3), p.n/a
Hauptverfasser: Wang, Guofang, Meng, Mengting, Deng, Liping, Cheng, Kai, Qi, Chenze
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Meng, Mengting
Deng, Liping
Cheng, Kai
Qi, Chenze
description A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen. A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen.
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source Wiley Online Library Journals Frontfile Complete
subjects arylhydrazide hydrochlorides
aryltrifluoroborates
Chemistry
Cobalt
Coupling
Hydrochlorides
Palladium
Room temperature
Suzuki‐type cross‐coupling
water
water‐soluble Pd‐catalyzed
title Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature
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