Thermocatalytic conversion of lignin in an ethanol/formic acid medium with NiMo catalysts: Role of the metal and acid sites

[Display omitted] •Lignin de-polymerization contributes more to the oil yield than monomer stabilization.•Ni0, Mo and strong Lewis acid sites catalyzed the de-polymerization of lignin.•HDO and alkylation reactions stabilize the lignin monomers.•Ni0 is more active than Mo and Lewis acidity for the de...

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Veröffentlicht in:	Applied catalysis. B, Environmental Environmental, 2017-11, Vol.217, p.353-364
Hauptverfasser:	Oregui-Bengoechea, Mikel, Gandarias, Inaki, Miletić, Nemanja, Simonsen, Sveinung F., Kronstad, Audun, Arias, Pedro L., Barth, Tanja
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Alkylation Alumina Aluminum oxide Bonding strength Catalysts Catalytic converters Cleavage Conversion Ethanol Formic acid Fragments Lewis acid Lignin NiMo catalyst Oil Polymerization Reaction mechanisms Studies Yield Zirconia
Online-Zugang:	Volltext
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