Hypervalent Iodine‐Mediated Alkene Functionalization: Oxazoline and Thiazoline Synthesis via Inter‐/Intramolecular Aminohydroxylation and Thioamination

A metal‐free oxidative difunctionalization of N‐allylamides and N‐allylthioamides has been developed. This system features the use of a hypervalent iodine oxidant with electron‐deficient amines to access 5‐amino‐oxazoline and thiazoline scaffolds under mild conditions. Notably, various electron‐defi...

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Veröffentlicht in:	Advanced synthesis & catalysis 2018-02, Vol.360 (4), p.779-783
Hauptverfasser:	Jeon, Hyeonho, Kim, Darong, Lee, Ji Hoon, Song, Jaeyoung, Lee, Won Seok, Kang, Dong Wook, Kang, Soosung, Lee, Seok Beom, Choi, Sungwook, Hong, Ki Bum
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Amines aminohydroxylation Benzene hypervalent iodine Iodine metal-free oxazoline Scaffolds thiazoline thioamination
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