A sustainable aqueous Zn-I2 battery
Rechargeable metal-iodine batteries are an emerging attractive electrochemical energy storage technology that combines metallic anodes with halogen cathodes. Such batteries using aqueous electrolytes represent a viable solution for the safety and cost issues associated with organic electrolytes. A h...
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| Veröffentlicht in: | Nano research 2018-07, Vol.11 (7), p.3548-3554 |
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| container_title | Nano research |
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| creator | Bai, Chong Cai, Fengshi Wang, Lingchang Guo, Shengqi Liu, Xizheng Yuan, Zhihao |
| description | Rechargeable metal-iodine batteries are an emerging attractive electrochemical energy storage technology that combines metallic anodes with halogen cathodes. Such batteries using aqueous electrolytes represent a viable solution for the safety and cost issues associated with organic electrolytes. A hybrid-electrolyte battery architecture has been adopted in a lithium-iodine battery using a solid ceramic membrane that protects the metallic anode from contacting the aqueous electrolyte. Here we demonstrate an eco-friendly, low-cost zinc-iodine battery with an aqueous electrolyte, wherein active I2 is confined in a nanoporous carbon cloth substrate. The electrochemical reaction is confined in the nanopores as a single conversion reaction, thus avoiding the production of I
3
−
intermediates. The cathode architecture fully utilizes the active I
2
, showing a capacity of 255 mAh·g
−1
and low capacity cycling fading. The battery provides an energy density of ∼ 151 Wh·kg
−1
and exhibits an ultrastable cycle life of more than 1,500 cycles. |
| doi_str_mv | 10.1007/s12274-017-1920-9 |
| format | Article |
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3
−
intermediates. The cathode architecture fully utilizes the active I
2
, showing a capacity of 255 mAh·g
−1
and low capacity cycling fading. The battery provides an energy density of ∼ 151 Wh·kg
−1
and exhibits an ultrastable cycle life of more than 1,500 cycles.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-017-1920-9</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Anodes ; Anodic protection ; Aqueous electrolytes ; Architecture ; Atomic/Molecular Structure and Spectra ; Batteries ; Biomedicine ; Biotechnology ; Cathodes ; Chemistry and Materials Science ; Cloth ; Condensed Matter Physics ; Electrochemistry ; Electrolytes ; Energy storage ; Flux density ; Intermediates ; Iodine ; Lithium ; Materials Science ; Nanotechnology ; Nonaqueous electrolytes ; Porosity ; Product safety ; Rechargeable batteries ; Research Article ; Storage batteries ; Substrates ; Zinc</subject><ispartof>Nano research, 2018-07, Vol.11 (7), p.3548-3554</ispartof><rights>Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017</rights><rights>Nano Research is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2319-54ffb06026d346f78ca7f8cc83791ee10f4c947def80d556efd7cbc9a88178533</citedby><cites>FETCH-LOGICAL-c2319-54ffb06026d346f78ca7f8cc83791ee10f4c947def80d556efd7cbc9a88178533</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-017-1920-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-017-1920-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Bai, Chong</creatorcontrib><creatorcontrib>Cai, Fengshi</creatorcontrib><creatorcontrib>Wang, Lingchang</creatorcontrib><creatorcontrib>Guo, Shengqi</creatorcontrib><creatorcontrib>Liu, Xizheng</creatorcontrib><creatorcontrib>Yuan, Zhihao</creatorcontrib><title>A sustainable aqueous Zn-I2 battery</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>Rechargeable metal-iodine batteries are an emerging attractive electrochemical energy storage technology that combines metallic anodes with halogen cathodes. Such batteries using aqueous electrolytes represent a viable solution for the safety and cost issues associated with organic electrolytes. A hybrid-electrolyte battery architecture has been adopted in a lithium-iodine battery using a solid ceramic membrane that protects the metallic anode from contacting the aqueous electrolyte. Here we demonstrate an eco-friendly, low-cost zinc-iodine battery with an aqueous electrolyte, wherein active I2 is confined in a nanoporous carbon cloth substrate. The electrochemical reaction is confined in the nanopores as a single conversion reaction, thus avoiding the production of I
3
−
intermediates. The cathode architecture fully utilizes the active I
2
, showing a capacity of 255 mAh·g
−1
and low capacity cycling fading. The battery provides an energy density of ∼ 151 Wh·kg
−1
and exhibits an ultrastable cycle life of more than 1,500 cycles.</description><subject>Anodes</subject><subject>Anodic protection</subject><subject>Aqueous electrolytes</subject><subject>Architecture</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Batteries</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Cathodes</subject><subject>Chemistry and Materials Science</subject><subject>Cloth</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy storage</subject><subject>Flux density</subject><subject>Intermediates</subject><subject>Iodine</subject><subject>Lithium</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Nonaqueous electrolytes</subject><subject>Porosity</subject><subject>Product safety</subject><subject>Rechargeable batteries</subject><subject>Research Article</subject><subject>Storage batteries</subject><subject>Substrates</subject><subject>Zinc</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kDtPAzEQhC0EEiHwA-hOSm3YtX1-lFHEI1IkGmhoLJ_PRonCXbDvivx7HB2Iim12i5nZ0UfILcIdAqj7jIwpQQEVRcOAmjMyQ2M0hTLnvzcycUmuct4BSIZCz8hiWeUxD27buWYfKvc1hn7M1XtH16xq3DCEdLwmF9Htc7j52XPy9vjwunqmm5en9Wq5oZ5xNLQWMTYggcmWCxmV9k5F7b3mymAICFF4I1Qbooa2rmWIrfKNN05rVLrmfE4WU-4h9aVHHuyuH1NXXloGwICDVFBUOKl86nNOIdpD2n66dLQI9sTCTixsYWFPLKwpHjZ5ctF2HyH9Jf9v-gYlQ175</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Bai, Chong</creator><creator>Cai, Fengshi</creator><creator>Wang, Lingchang</creator><creator>Guo, Shengqi</creator><creator>Liu, 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Such batteries using aqueous electrolytes represent a viable solution for the safety and cost issues associated with organic electrolytes. A hybrid-electrolyte battery architecture has been adopted in a lithium-iodine battery using a solid ceramic membrane that protects the metallic anode from contacting the aqueous electrolyte. Here we demonstrate an eco-friendly, low-cost zinc-iodine battery with an aqueous electrolyte, wherein active I2 is confined in a nanoporous carbon cloth substrate. The electrochemical reaction is confined in the nanopores as a single conversion reaction, thus avoiding the production of I
3
−
intermediates. The cathode architecture fully utilizes the active I
2
, showing a capacity of 255 mAh·g
−1
and low capacity cycling fading. The battery provides an energy density of ∼ 151 Wh·kg
−1
and exhibits an ultrastable cycle life of more than 1,500 cycles.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-017-1920-9</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2018-07, Vol.11 (7), p.3548-3554 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_journals_2002030670 |
| source | SpringerNature Journals |
| subjects | Anodes Anodic protection Aqueous electrolytes Architecture Atomic/Molecular Structure and Spectra Batteries Biomedicine Biotechnology Cathodes Chemistry and Materials Science Cloth Condensed Matter Physics Electrochemistry Electrolytes Energy storage Flux density Intermediates Iodine Lithium Materials Science Nanotechnology Nonaqueous electrolytes Porosity Product safety Rechargeable batteries Research Article Storage batteries Substrates Zinc |
| title | A sustainable aqueous Zn-I2 battery |
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