Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries

Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepar...

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Veröffentlicht in:Nano research 2017-12, Vol.10 (12), p.4266-4273
Hauptverfasser: Zhang, Yufei, Wang, Huanwen, Yang, Jun, Fan, Haosen, Zhang, Yu, Dai, Zhengfei, Zheng, Yun, Huang, Wei, Dong, Xiaochen, Yan, Qingyu
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container_end_page 4273
container_issue 12
container_start_page 4266
container_title Nano research
container_volume 10
creator Zhang, Yufei
Wang, Huanwen
Yang, Jun
Fan, Haosen
Zhang, Yu
Dai, Zhengfei
Zheng, Yun
Huang, Wei
Dong, Xiaochen
Yan, Qingyu
description Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepared and incorporated into freeze-dried graphene foam. The hydrogenated vanadium oxides show greatly improved charge-transfer kinetics, which lead to excellent electrochemical properties. When tested as anode materials (0.005-3.0 V vs. Li/Li+) in LIBs, the sample activated at 600℃ exhibits high specific capacity (-941 mA-h-g-1 at 100 mA.g-1) and high-rate capability (-504 mA·h·g-1 at 5 A·g-1), as well as excellent cycling performance (-285 mA.h.g-1 in the 1,000th cycle at 5A-g-1). These results demonstrate the promising application of vanadium oxides as anodes in LIBs.
doi_str_mv 10.1007/s12274-017-1582-7
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1998-0000
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subjects Anodes
Atomic/Molecular Structure and Spectra
Batteries
Biomedicine
Biotechnology
Charge transfer
Chemistry and Materials Science
Condensed Matter Physics
Electrical conductivity
Electrical resistivity
Electrochemical analysis
Electrochemistry
Electrode materials
Hydrogenation
Lithium
Lithium-ion batteries
Materials Science
Nanotechnology
Oxides
Research Article
Specific capacity
Vanadium
Vanadium oxides
title Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries
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