Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries
Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepar...
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Veröffentlicht in: | Nano research 2017-12, Vol.10 (12), p.4266-4273 |
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creator | Zhang, Yufei Wang, Huanwen Yang, Jun Fan, Haosen Zhang, Yu Dai, Zhengfei Zheng, Yun Huang, Wei Dong, Xiaochen Yan, Qingyu |
description | Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepared and incorporated into freeze-dried graphene foam. The hydrogenated vanadium oxides show greatly improved charge-transfer kinetics, which lead to excellent electrochemical properties. When tested as anode materials (0.005-3.0 V vs. Li/Li+) in LIBs, the sample activated at 600℃ exhibits high specific capacity (-941 mA-h-g-1 at 100 mA.g-1) and high-rate capability (-504 mA·h·g-1 at 5 A·g-1), as well as excellent cycling performance (-285 mA.h.g-1 in the 1,000th cycle at 5A-g-1). These results demonstrate the promising application of vanadium oxides as anodes in LIBs. |
doi_str_mv | 10.1007/s12274-017-1582-7 |
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In this work, hydrogenated vanadium oxide nanoneedles were prepared and incorporated into freeze-dried graphene foam. The hydrogenated vanadium oxides show greatly improved charge-transfer kinetics, which lead to excellent electrochemical properties. When tested as anode materials (0.005-3.0 V vs. Li/Li+) in LIBs, the sample activated at 600℃ exhibits high specific capacity (-941 mA-h-g-1 at 100 mA.g-1) and high-rate capability (-504 mA·h·g-1 at 5 A·g-1), as well as excellent cycling performance (-285 mA.h.g-1 in the 1,000th cycle at 5A-g-1). These results demonstrate the promising application of vanadium oxides as anodes in LIBs.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-017-1582-7</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Anodes ; Atomic/Molecular Structure and Spectra ; Batteries ; Biomedicine ; Biotechnology ; Charge transfer ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrical conductivity ; Electrical resistivity ; Electrochemical analysis ; Electrochemistry ; Electrode materials ; Hydrogenation ; Lithium ; Lithium-ion batteries ; Materials Science ; Nanotechnology ; Oxides ; Research Article ; Specific capacity ; Vanadium ; Vanadium oxides</subject><ispartof>Nano research, 2017-12, Vol.10 (12), p.4266-4273</ispartof><rights>Tsinghua University Press and Springer-Verlag GmbH Germany 2017</rights><rights>Nano Research is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c343t-f1f4caa6e5be87ed3d0a0db97640269a130bd51a61976396a253a837abd5b8da3</citedby><cites>FETCH-LOGICAL-c343t-f1f4caa6e5be87ed3d0a0db97640269a130bd51a61976396a253a837abd5b8da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/71233X/71233X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-017-1582-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-017-1582-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zhang, Yufei</creatorcontrib><creatorcontrib>Wang, Huanwen</creatorcontrib><creatorcontrib>Yang, Jun</creatorcontrib><creatorcontrib>Fan, Haosen</creatorcontrib><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Dai, Zhengfei</creatorcontrib><creatorcontrib>Zheng, Yun</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Dong, Xiaochen</creatorcontrib><creatorcontrib>Yan, Qingyu</creatorcontrib><title>Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries</title><title>Nano research</title><addtitle>Nano Res</addtitle><addtitle>Nano Research</addtitle><description>Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepared and incorporated into freeze-dried graphene foam. The hydrogenated vanadium oxides show greatly improved charge-transfer kinetics, which lead to excellent electrochemical properties. When tested as anode materials (0.005-3.0 V vs. Li/Li+) in LIBs, the sample activated at 600℃ exhibits high specific capacity (-941 mA-h-g-1 at 100 mA.g-1) and high-rate capability (-504 mA·h·g-1 at 5 A·g-1), as well as excellent cycling performance (-285 mA.h.g-1 in the 1,000th cycle at 5A-g-1). 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materials</topic><topic>Hydrogenation</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Oxides</topic><topic>Research Article</topic><topic>Specific capacity</topic><topic>Vanadium</topic><topic>Vanadium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yufei</creatorcontrib><creatorcontrib>Wang, Huanwen</creatorcontrib><creatorcontrib>Yang, Jun</creatorcontrib><creatorcontrib>Fan, Haosen</creatorcontrib><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Dai, Zhengfei</creatorcontrib><creatorcontrib>Zheng, Yun</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Dong, Xiaochen</creatorcontrib><creatorcontrib>Yan, Qingyu</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 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Yu</au><au>Dai, Zhengfei</au><au>Zheng, Yun</au><au>Huang, Wei</au><au>Dong, Xiaochen</au><au>Yan, Qingyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><addtitle>Nano Research</addtitle><date>2017-12-01</date><risdate>2017</risdate><volume>10</volume><issue>12</issue><spage>4266</spage><epage>4273</epage><pages>4266-4273</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>Current research on vanadium oxides in lithium ion batteries (LIBs) considers them as cathode materials, whereas they are rarely studied for use as anodes in LIBs because of their low electrical conductivity and rapid capacity fading. In this work, hydrogenated vanadium oxide nanoneedles were prepared and incorporated into freeze-dried graphene foam. The hydrogenated vanadium oxides show greatly improved charge-transfer kinetics, which lead to excellent electrochemical properties. When tested as anode materials (0.005-3.0 V vs. Li/Li+) in LIBs, the sample activated at 600℃ exhibits high specific capacity (-941 mA-h-g-1 at 100 mA.g-1) and high-rate capability (-504 mA·h·g-1 at 5 A·g-1), as well as excellent cycling performance (-285 mA.h.g-1 in the 1,000th cycle at 5A-g-1). These results demonstrate the promising application of vanadium oxides as anodes in LIBs.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-017-1582-7</doi><tpages>8</tpages></addata></record> |
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subjects | Anodes Atomic/Molecular Structure and Spectra Batteries Biomedicine Biotechnology Charge transfer Chemistry and Materials Science Condensed Matter Physics Electrical conductivity Electrical resistivity Electrochemical analysis Electrochemistry Electrode materials Hydrogenation Lithium Lithium-ion batteries Materials Science Nanotechnology Oxides Research Article Specific capacity Vanadium Vanadium oxides |
title | Hydrogenated vanadium oxides as an advanced anode material in lithium ion batteries |
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