Dual function of a high-contrast hydrophobic-hydrophilic coating for enhanced stability of perovskite solar cells in extremely humid environments

In spite of a continuous increase in their power conversion efficiency (PCE) and an economically viable fabrication process,organic-inorganic perovskite solar cells (PSCs) pose a significant problem when used in practical applications:They show fast degradation of the PCE when exposed to very humid...

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Veröffentlicht in:Nano research 2017-11, Vol.10 (11), p.3885-3895
Hauptverfasser: Yoo, Jin Sun, Han, Gill Sang, Lee, Seongha, Kim, Min Cheol, Choi, Mansoo, Jung, Hyun Suk, Lee, Jung-Kun
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container_end_page 3895
container_issue 11
container_start_page 3885
container_title Nano research
container_volume 10
creator Yoo, Jin Sun
Han, Gill Sang
Lee, Seongha
Kim, Min Cheol
Choi, Mansoo
Jung, Hyun Suk
Lee, Jung-Kun
description In spite of a continuous increase in their power conversion efficiency (PCE) and an economically viable fabrication process,organic-inorganic perovskite solar cells (PSCs) pose a significant problem when used in practical applications:They show fast degradation of the PCE when exposed to very humid environments.In this study,the stability of PSCs under very humid conditions is greatly enhanced by coating the surface of the PSC devices with a multi-layer film consisting of ultrahydrophobic and relatively hydrophilic layers.A hydrophobic composite of poly(methyl methacrylate) (PMMA),polyurethane (PU),and SiO2 nanoparticles successfully retards the water molecules from very humid surroundings.Also,the hydrophilic layer with moderately PMMA captures the residual moisture within the perovskite layer;subsequently,the perovskite layer recovers.This dual function of the coating film keeps the PCE of PSCs at 17.3% for 180 min when exposed to over 95% humidity.
doi_str_mv 10.1007/s12274-017-1603-6
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ispartof Nano research, 2017-11, Vol.10 (11), p.3885-3895
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1998-0000
language eng
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subjects Atomic/Molecular Structure and Spectra
Biomedicine
Biotechnology
Chemistry and Materials Science
Coating
Condensed Matter Physics
Economic conditions
Energy conversion efficiency
Fabrication
Hydrophobicity
Materials Science
Nanoparticles
Nanotechnology
Photovoltaic cells
Polymethyl methacrylate
Polymethylmethacrylate
Polyurethane
Polyurethane resins
Research Article
Silicon dioxide
Solar cells
Stability
Water chemistry
title Dual function of a high-contrast hydrophobic-hydrophilic coating for enhanced stability of perovskite solar cells in extremely humid environments
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