Durable and Washable Antibacterial Copper Nanoparticles Bridged by Surface Grafting Polymer Brushes on Cotton and Polymeric Materials
To increase the durability of antibacterial coating on cotton and polymeric substrates, surface initiated grafting polymer brushes are introduced onto the substrates surface to bridge copper nanoparticles coatings and substrate. The morphologies of the composites consisting of the copper nanoparticl...
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Veröffentlicht in: | Journal of nanomaterials 2018-01, Vol.2018 (2018), p.1-7 |
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creator | Wang, Yanbin Su, Qiong Li, Zhi Li, Yi Sun, Chufeng Liu, Xuqing |
description | To increase the durability of antibacterial coating on cotton and polymeric substrates, surface initiated grafting polymer brushes are introduced onto the substrates surface to bridge copper nanoparticles coatings and substrate. The morphologies of the composites consisting of the copper nanoparticles and polymer brushes were characterized with scanning electron microscopy (SEM). It was found that copper nanoparticles were uniformly and firmly distributed on the surfaces of the substrates by the polymer brushes; meanwhile, the reinforced concrete-like structures were formed in the composite materials. The substrates coated by the copper nanoparticles showed the efficient antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) even after washing by 30 cycles. The copper nanoparticles were tethered on the substrates by the strong chemical bonds, which led to the excellent washable fitness and durability. The change of the phase structure of the copper was analyzed to investigate the release mechanism of copper ions. |
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The morphologies of the composites consisting of the copper nanoparticles and polymer brushes were characterized with scanning electron microscopy (SEM). It was found that copper nanoparticles were uniformly and firmly distributed on the surfaces of the substrates by the polymer brushes; meanwhile, the reinforced concrete-like structures were formed in the composite materials. The substrates coated by the copper nanoparticles showed the efficient antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) even after washing by 30 cycles. The copper nanoparticles were tethered on the substrates by the strong chemical bonds, which led to the excellent washable fitness and durability. The change of the phase structure of the copper was analyzed to investigate the release mechanism of copper ions.</description><identifier>ISSN: 1687-4110</identifier><identifier>EISSN: 1687-4129</identifier><identifier>DOI: 10.1155/2018/6546193</identifier><language>eng</language><publisher>Cairo, Egypt: Hindawi Publishing Corporation</publisher><subject>Antimicrobial agents ; Bonding strength ; Brushes ; Cellulose ; Chemical bonds ; Composite materials ; Copper ; Cotton ; Durability ; E coli ; Electron microscopy ; Fitness ; Grafting ; Investigations ; Materials science ; Nanomaterials ; Nanoparticles ; Nitrogen ; Phase transitions ; Polyesters ; Polyethylene ; Polymer matrix composites ; Polymerization ; Polymers ; Reinforced concrete ; Solid phases ; Substrates ; Textiles</subject><ispartof>Journal of nanomaterials, 2018-01, Vol.2018 (2018), p.1-7</ispartof><rights>Copyright © 2018 Chufeng Sun et al.</rights><rights>Copyright © 2018 Chufeng Sun et al.; This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-42135150bd767ea14a689c9a301cfdfb3d3fcd52363845c26ba86e5c1ab600c43</citedby><cites>FETCH-LOGICAL-c360t-42135150bd767ea14a689c9a301cfdfb3d3fcd52363845c26ba86e5c1ab600c43</cites><orcidid>0000-0001-5998-6546</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><contributor>Naik, Rajesh R.</contributor><contributor>Rajesh R Naik</contributor><creatorcontrib>Wang, Yanbin</creatorcontrib><creatorcontrib>Su, Qiong</creatorcontrib><creatorcontrib>Li, Zhi</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Sun, Chufeng</creatorcontrib><creatorcontrib>Liu, Xuqing</creatorcontrib><title>Durable and Washable Antibacterial Copper Nanoparticles Bridged by Surface Grafting Polymer Brushes on Cotton and Polymeric Materials</title><title>Journal of nanomaterials</title><description>To increase the durability of antibacterial coating on cotton and polymeric substrates, surface initiated grafting polymer brushes are introduced onto the substrates surface to bridge copper nanoparticles coatings and substrate. The morphologies of the composites consisting of the copper nanoparticles and polymer brushes were characterized with scanning electron microscopy (SEM). It was found that copper nanoparticles were uniformly and firmly distributed on the surfaces of the substrates by the polymer brushes; meanwhile, the reinforced concrete-like structures were formed in the composite materials. The substrates coated by the copper nanoparticles showed the efficient antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) even after washing by 30 cycles. The copper nanoparticles were tethered on the substrates by the strong chemical bonds, which led to the excellent washable fitness and durability. The change of the phase structure of the copper was analyzed to investigate the release mechanism of copper ions.</description><subject>Antimicrobial agents</subject><subject>Bonding strength</subject><subject>Brushes</subject><subject>Cellulose</subject><subject>Chemical bonds</subject><subject>Composite materials</subject><subject>Copper</subject><subject>Cotton</subject><subject>Durability</subject><subject>E coli</subject><subject>Electron microscopy</subject><subject>Fitness</subject><subject>Grafting</subject><subject>Investigations</subject><subject>Materials science</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nitrogen</subject><subject>Phase transitions</subject><subject>Polyesters</subject><subject>Polyethylene</subject><subject>Polymer matrix composites</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Reinforced concrete</subject><subject>Solid phases</subject><subject>Substrates</subject><subject>Textiles</subject><issn>1687-4110</issn><issn>1687-4129</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>RHX</sourceid><sourceid>BENPR</sourceid><recordid>eNqFkEtPwzAQhCMEEqVw44wscYRQO34kObYFClJ5SIA4RhvHaV2lSbAdof4A_jcuqeDIaXa1385IEwSnBF8RwvkowiQZCc4ESeleMCAiiUNGonT_dyb4MDiydoUx4ymPBsHXdWcgrxSCukDvYJc_y7h2OgfplNFQoWnTtsqgR6ibFozTslIWTYwuFqpA-Qa9dKYEqdDMQOl0vUDPTbVZ-4-J6ezSs03tPZzzsk3ZXbVED9An2OPgoPSiTnY6DN5ub16nd-H8aXY_Hc9DSQV2IYsI5YTjvIhFrIAwEEkqU6CYyLIoc1rQUhY8ooImjMtI5JAIxSWBXGAsGR0G571va5qPTlmXrZrO1D4yizDGaRKziHvqsqekaaw1qsxao9dgNhnB2bbobFt0tiva4xc9vtR1AZ_6P_qsp5VnVAl_NEkZTxj9BgHQiF0</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Wang, Yanbin</creator><creator>Su, Qiong</creator><creator>Li, Zhi</creator><creator>Li, Yi</creator><creator>Sun, Chufeng</creator><creator>Liu, Xuqing</creator><general>Hindawi Publishing Corporation</general><general>Hindawi</general><general>Hindawi Limited</general><scope>ADJCN</scope><scope>AHFXO</scope><scope>RHU</scope><scope>RHW</scope><scope>RHX</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>CWDGH</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-5998-6546</orcidid></search><sort><creationdate>20180101</creationdate><title>Durable and Washable Antibacterial Copper Nanoparticles Bridged by Surface Grafting Polymer Brushes on Cotton and Polymeric Materials</title><author>Wang, Yanbin ; Su, Qiong ; Li, Zhi ; Li, Yi ; Sun, Chufeng ; Liu, Xuqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-42135150bd767ea14a689c9a301cfdfb3d3fcd52363845c26ba86e5c1ab600c43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antimicrobial agents</topic><topic>Bonding strength</topic><topic>Brushes</topic><topic>Cellulose</topic><topic>Chemical bonds</topic><topic>Composite materials</topic><topic>Copper</topic><topic>Cotton</topic><topic>Durability</topic><topic>E coli</topic><topic>Electron microscopy</topic><topic>Fitness</topic><topic>Grafting</topic><topic>Investigations</topic><topic>Materials science</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nitrogen</topic><topic>Phase transitions</topic><topic>Polyesters</topic><topic>Polyethylene</topic><topic>Polymer matrix composites</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Reinforced concrete</topic><topic>Solid phases</topic><topic>Substrates</topic><topic>Textiles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yanbin</creatorcontrib><creatorcontrib>Su, Qiong</creatorcontrib><creatorcontrib>Li, Zhi</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Sun, Chufeng</creatorcontrib><creatorcontrib>Liu, Xuqing</creatorcontrib><collection>الدوريات العلمية والإحصائية - e-Marefa Academic and Statistical Periodicals</collection><collection>معرفة - المحتوى العربي الأكاديمي المتكامل - e-Marefa Academic Complete</collection><collection>Hindawi Publishing Complete</collection><collection>Hindawi Publishing Subscription Journals</collection><collection>Hindawi Publishing Open Access Journals</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>Middle East & Africa Database</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of nanomaterials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yanbin</au><au>Su, Qiong</au><au>Li, Zhi</au><au>Li, Yi</au><au>Sun, Chufeng</au><au>Liu, Xuqing</au><au>Naik, Rajesh R.</au><au>Rajesh R Naik</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Durable and Washable Antibacterial Copper Nanoparticles Bridged by Surface Grafting Polymer Brushes on Cotton and Polymeric Materials</atitle><jtitle>Journal of nanomaterials</jtitle><date>2018-01-01</date><risdate>2018</risdate><volume>2018</volume><issue>2018</issue><spage>1</spage><epage>7</epage><pages>1-7</pages><issn>1687-4110</issn><eissn>1687-4129</eissn><abstract>To increase the durability of antibacterial coating on cotton and polymeric substrates, surface initiated grafting polymer brushes are introduced onto the substrates surface to bridge copper nanoparticles coatings and substrate. The morphologies of the composites consisting of the copper nanoparticles and polymer brushes were characterized with scanning electron microscopy (SEM). It was found that copper nanoparticles were uniformly and firmly distributed on the surfaces of the substrates by the polymer brushes; meanwhile, the reinforced concrete-like structures were formed in the composite materials. The substrates coated by the copper nanoparticles showed the efficient antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) even after washing by 30 cycles. The copper nanoparticles were tethered on the substrates by the strong chemical bonds, which led to the excellent washable fitness and durability. The change of the phase structure of the copper was analyzed to investigate the release mechanism of copper ions.</abstract><cop>Cairo, Egypt</cop><pub>Hindawi Publishing Corporation</pub><doi>10.1155/2018/6546193</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-5998-6546</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Antimicrobial agents Bonding strength Brushes Cellulose Chemical bonds Composite materials Copper Cotton Durability E coli Electron microscopy Fitness Grafting Investigations Materials science Nanomaterials Nanoparticles Nitrogen Phase transitions Polyesters Polyethylene Polymer matrix composites Polymerization Polymers Reinforced concrete Solid phases Substrates Textiles |
title | Durable and Washable Antibacterial Copper Nanoparticles Bridged by Surface Grafting Polymer Brushes on Cotton and Polymeric Materials |
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