Pyroelectric properties of Mn‐doped Aurivillius ceramics with different pseudo‐perovskite layers

The pyroelectric properties of Mn‐doped Aurivillius ceramics with different pseudo‐perovskite layers were investigated. The pyroelectric coefficients for 0.2 wt% Mn‐doped two‐layer CaBi2Nb2O9 (CBN–Mn), three‐layer Bi4Ti2.85Nb0.15O12 (BTN–Mn), and four‐layer CaBi4Ti3.95Nb0.05O15 (CBTN–Mn) ferroelectr...

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Veröffentlicht in:Journal of the American Ceramic Society 2018-04, Vol.101 (4), p.1592-1597
Hauptverfasser: Tang, Yanxue, Shen, Zong‐Yang, Zhao, Xiangyong, Wang, Feifei, Shi, Wangzhou, Sun, Dazhi, Zhou, Zhiyong, Zhang, Shujun
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container_end_page 1597
container_issue 4
container_start_page 1592
container_title Journal of the American Ceramic Society
container_volume 101
creator Tang, Yanxue
Shen, Zong‐Yang
Zhao, Xiangyong
Wang, Feifei
Shi, Wangzhou
Sun, Dazhi
Zhou, Zhiyong
Zhang, Shujun
description The pyroelectric properties of Mn‐doped Aurivillius ceramics with different pseudo‐perovskite layers were investigated. The pyroelectric coefficients for 0.2 wt% Mn‐doped two‐layer CaBi2Nb2O9 (CBN–Mn), three‐layer Bi4Ti2.85Nb0.15O12 (BTN–Mn), and four‐layer CaBi4Ti3.95Nb0.05O15 (CBTN–Mn) ferroelectric ceramics were found to be on the order of 26.0, 54.4, 84.4 μC/m2K at room temperature, respectively. These values were closely associated with the number of octahedral layers in the pseudo‐perovskite blocks. The high pyroelectric coefficient, together with low dielectric permittivity and loss (tan δ < 0.003), results in to high figures of merit for the current responsivity, voltage responsivity, and detectivity. The excellent pyroelectric properties and high Curie temperatures (TC > 660°C) make the Aurivillius ceramics potential candidates for pyroelectric devices over a broad temperature range.
doi_str_mv 10.1111/jace.15267
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The pyroelectric coefficients for 0.2 wt% Mn‐doped two‐layer CaBi2Nb2O9 (CBN–Mn), three‐layer Bi4Ti2.85Nb0.15O12 (BTN–Mn), and four‐layer CaBi4Ti3.95Nb0.05O15 (CBTN–Mn) ferroelectric ceramics were found to be on the order of 26.0, 54.4, 84.4 μC/m2K at room temperature, respectively. These values were closely associated with the number of octahedral layers in the pseudo‐perovskite blocks. The high pyroelectric coefficient, together with low dielectric permittivity and loss (tan δ &lt; 0.003), results in to high figures of merit for the current responsivity, voltage responsivity, and detectivity. 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The pyroelectric coefficients for 0.2 wt% Mn‐doped two‐layer CaBi2Nb2O9 (CBN–Mn), three‐layer Bi4Ti2.85Nb0.15O12 (BTN–Mn), and four‐layer CaBi4Ti3.95Nb0.05O15 (CBTN–Mn) ferroelectric ceramics were found to be on the order of 26.0, 54.4, 84.4 μC/m2K at room temperature, respectively. These values were closely associated with the number of octahedral layers in the pseudo‐perovskite blocks. The high pyroelectric coefficient, together with low dielectric permittivity and loss (tan δ &lt; 0.003), results in to high figures of merit for the current responsivity, voltage responsivity, and detectivity. The excellent pyroelectric properties and high Curie temperatures (TC &gt; 660°C) make the Aurivillius ceramics potential candidates for pyroelectric devices over a broad temperature range.</abstract><cop>Columbus</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1111/jace.15267</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-4926-0634</orcidid></addata></record>
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subjects bismuth oxide
Ceramics
electrical properties
Ferroelectric materials
Ferroelectricity
layered ceramics
Properties (attributes)
pyroelectricity
title Pyroelectric properties of Mn‐doped Aurivillius ceramics with different pseudo‐perovskite layers
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