Benzo[α]phenothiazine sensitized ZrO2 based dye sensitized solar cell

Benzo[α]phenothiazine derived 6-methyl-5H-benzo[α]phenothiazin-5-one (benzo[α]phenothiazine) photosensitizer was synthesized and characterized by various spectroscopic techniques. ZrO 2 based dye sensitized solar cell was developed and fabricated successfully with 6-methyl-5H-benzo[α]phenothiazin-5-...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2018, Vol.29 (2), p.1034-1041
Hauptverfasser: Bhand, Sujit, Chadar, Dattatray, Pawar, Kalpana, Naushad, Mu, Pathan, Habib, Salunke-Gawali, Sunita
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container_issue 2
container_start_page 1034
container_title Journal of materials science. Materials in electronics
container_volume 29
creator Bhand, Sujit
Chadar, Dattatray
Pawar, Kalpana
Naushad, Mu
Pathan, Habib
Salunke-Gawali, Sunita
description Benzo[α]phenothiazine derived 6-methyl-5H-benzo[α]phenothiazin-5-one (benzo[α]phenothiazine) photosensitizer was synthesized and characterized by various spectroscopic techniques. ZrO 2 based dye sensitized solar cell was developed and fabricated successfully with 6-methyl-5H-benzo[α]phenothiazin-5-one dye as photosensitizer for photovoltaic performance. Synthesized dye exerts UV–visible bands at 258, 316, 337 and 382 nm attributed to π–π* transitions. The band ~ 477 nm was assigned to n–π* transition. Sandwich type cell was fabricated with ZrO 2 photoanode, mesoporous films were prepared with doctor blade method, films were annulated and after natural cooling they are subjected for dye loading. The observed photovoltaic performance was recorded and respective parameters obtained are J sc , V oc , FF and η as 3.01 mA/cm 2 , 0.42 V, 0.20 and 1.6% respectively.
doi_str_mv 10.1007/s10854-017-8003-2
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ZrO 2 based dye sensitized solar cell was developed and fabricated successfully with 6-methyl-5H-benzo[α]phenothiazin-5-one dye as photosensitizer for photovoltaic performance. Synthesized dye exerts UV–visible bands at 258, 316, 337 and 382 nm attributed to π–π* transitions. The band ~ 477 nm was assigned to n–π* transition. Sandwich type cell was fabricated with ZrO 2 photoanode, mesoporous films were prepared with doctor blade method, films were annulated and after natural cooling they are subjected for dye loading. 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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Dye-sensitized solar cells
Dyes
Materials Science
Optical and Electronic Materials
Photovoltaic cells
Synthesis
Zirconium dioxide
title Benzo[α]phenothiazine sensitized ZrO2 based dye sensitized solar cell
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