Directed ortho‐Metalation of O‐Aryl N,N‐Dialkylcarbamates: Methodology, Anionic ortho‐Fries Rearrangement, and Lateral Metalation

The directed ortho‐lithiation reactions of O‐aryl N,N‐dialkylcarbamates as well as O‐1‐naphthyl and O‐2‐naphthyl N,N‐dialkylcarbamates with sec‐butyllithium/tetramethylethylenediamine (sBuLi/TMEDA) followed by quenching with various electrophiles afford a range of polysubstituted aromatic compounds....

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Veröffentlicht in:	European journal of organic chemistry 2018-01, Vol.2018 (4), p.440-446
Hauptverfasser:	Miah, M. A. Jalil, Sibi, Mukund P., Chattopadhyay, S., Familoni, Oluwole B., Snieckus, Victor
Format:	Artikel
Sprache:	eng
Schlagworte:	Anionic ortho‐Fries rearrangement Aromatic compounds Benzofurans Butyllithium Carbamates (tradename) Directed ortho‐metalation Lithium O‐Carbamates Quenching (cooling) Substituted aromatics
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