Directed ortho‐Metalation of Aryl Amides, O‐Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation

A systematic study on the competitive metalation of derivatives containing four directed metalation groups (DMGs), namely, Cl, OMe, methoxymethoxy (OMOM), and CONEt2, in comparison with the OCONEt2 DMG is described. In addition, the anionic ortho‐Fries (AoF) rearrangement, the double metalation–elec...

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Veröffentlicht in:	European journal of organic chemistry 2018-01, Vol.2018 (4), p.447-454
Hauptverfasser:	Miah, M. A. Jalil, Sibi, Mukund P., Chattopadhyay, S., Familoni, Oluwole B., Snieckus, Victor
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Aromatic compounds Aromatic substitution Carbamates Carbamates (tradename) Derivatives Metalation Regioselectivity Substitutes
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