Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands
Newly synthesized mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using physicochemical, spectral, thermal and powder X‐ray diffraction studies, and their antimicrobial activities were investigated. These derivatives have nanometric crystallite size (...
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| Veröffentlicht in: | Applied organometallic chemistry 2018-02, Vol.32 (2), p.n/a |
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| creator | Bhatiya, Sumit Chauhan, H.P.S. Carpenter, Nitin |
| description | Newly synthesized mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using physicochemical, spectral, thermal and powder X‐ray diffraction studies, and their antimicrobial activities were investigated. These derivatives have nanometric crystallite size (11.39–14.67 nm) with unit cell volume (4968.47 and 5079.79 Å3) and lower symmetry (monoclinic) crystal system. After thermal decomposition in inert atmosphere, these derivatives give antimony sulfide as a final decomposition product which has many potential applications, and they exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs (chloroamphenicol and terbinafine were used as standard antibacterial and antifungal drugs, respectively) due to the nanometric size of the complexes.
Newly synthesized bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using various methods. These derivatives give antimony sulfide as a final decomposition product and exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs due to the nanometric size of the complexes. |
| doi_str_mv | 10.1002/aoc.4026 |
| format | Article |
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Newly synthesized bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using various methods. These derivatives give antimony sulfide as a final decomposition product and exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs due to the nanometric size of the complexes.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.4026</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>Antiinfectives and antibacterials ; antimicrobial activities ; Antimony ; antimony(III) ; Chemistry ; Derivatives ; dialkyldithiophosphate ; Diffraction ; Fungicides ; Ligands ; powder XRD ; Thermal decomposition ; thermal studies ; X ray powder diffraction ; X-ray diffraction ; X-rays</subject><ispartof>Applied organometallic chemistry, 2018-02, Vol.32 (2), p.n/a</ispartof><rights>Copyright © 2017 John Wiley & Sons, Ltd.</rights><rights>Copyright © 2018 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3306-b160163534db2ccdb8f1ba19963d62dabdbbedcffe35ebe742eb80f391e5ea413</citedby><cites>FETCH-LOGICAL-c3306-b160163534db2ccdb8f1ba19963d62dabdbbedcffe35ebe742eb80f391e5ea413</cites><orcidid>0000-0001-9518-724X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.4026$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.4026$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Bhatiya, Sumit</creatorcontrib><creatorcontrib>Chauhan, H.P.S.</creatorcontrib><creatorcontrib>Carpenter, Nitin</creatorcontrib><title>Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands</title><title>Applied organometallic chemistry</title><description>Newly synthesized mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using physicochemical, spectral, thermal and powder X‐ray diffraction studies, and their antimicrobial activities were investigated. These derivatives have nanometric crystallite size (11.39–14.67 nm) with unit cell volume (4968.47 and 5079.79 Å3) and lower symmetry (monoclinic) crystal system. After thermal decomposition in inert atmosphere, these derivatives give antimony sulfide as a final decomposition product which has many potential applications, and they exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs (chloroamphenicol and terbinafine were used as standard antibacterial and antifungal drugs, respectively) due to the nanometric size of the complexes.
Newly synthesized bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using various methods. These derivatives give antimony sulfide as a final decomposition product and exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs due to the nanometric size of the complexes.</description><subject>Antiinfectives and antibacterials</subject><subject>antimicrobial activities</subject><subject>Antimony</subject><subject>antimony(III)</subject><subject>Chemistry</subject><subject>Derivatives</subject><subject>dialkyldithiophosphate</subject><subject>Diffraction</subject><subject>Fungicides</subject><subject>Ligands</subject><subject>powder XRD</subject><subject>Thermal decomposition</subject><subject>thermal studies</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kc1q3DAQgE1podu00EcQ9LKBdSpZtnd9DEvaLAS2kBZ6M_oZxRNsS5W8u3FPeYQ-Sx4pL9BXqLyba08SM998M9IkyUdGLxil2Wdh1UVOs_JVMmO0qlK65NXrZBYjqzQrafE2eRfCPaW0Klk-S_5-8-CEFwPafkGCAzV4G5R1qBZkaMB3oiWi18TZgwZPfj4__vFiJBqN8UJNZUQ1YrqCx98vnqlA9AN2qLyVOCkiuscBIRBrSIcPoInEMN8uts-PT1GqEYN13rqx1Tg0aF1jg2vEYGPydnEbqfOj0vbjfLPZnJM4Du5jw310HmIJCbYDYh_GO-iPE4Rda3aeaNtbT1q8i7HwPnljRBvgw8t5lvz4cvV9fZ3ebL9u1pc3qeKclqlkJWUlL3iuZaaUlivDpGBVVXJdZlpILSVoZQzwAiQs8wzkihpeMShA5IyfJZ9O3vikXzsIQ31vd76PLetoyVhVLLNVpOYnKn5TCB5M7Tx2wo81o_W0zjqus57WGdH0hB6whfG_XH25XR_5f8Pbrh4</recordid><startdate>201802</startdate><enddate>201802</enddate><creator>Bhatiya, Sumit</creator><creator>Chauhan, H.P.S.</creator><creator>Carpenter, Nitin</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-9518-724X</orcidid></search><sort><creationdate>201802</creationdate><title>Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands</title><author>Bhatiya, Sumit ; Chauhan, H.P.S. ; Carpenter, Nitin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3306-b160163534db2ccdb8f1ba19963d62dabdbbedcffe35ebe742eb80f391e5ea413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antiinfectives and antibacterials</topic><topic>antimicrobial activities</topic><topic>Antimony</topic><topic>antimony(III)</topic><topic>Chemistry</topic><topic>Derivatives</topic><topic>dialkyldithiophosphate</topic><topic>Diffraction</topic><topic>Fungicides</topic><topic>Ligands</topic><topic>powder XRD</topic><topic>Thermal decomposition</topic><topic>thermal studies</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bhatiya, Sumit</creatorcontrib><creatorcontrib>Chauhan, H.P.S.</creatorcontrib><creatorcontrib>Carpenter, Nitin</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bhatiya, Sumit</au><au>Chauhan, H.P.S.</au><au>Carpenter, Nitin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2018-02</date><risdate>2018</risdate><volume>32</volume><issue>2</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>Newly synthesized mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using physicochemical, spectral, thermal and powder X‐ray diffraction studies, and their antimicrobial activities were investigated. These derivatives have nanometric crystallite size (11.39–14.67 nm) with unit cell volume (4968.47 and 5079.79 Å3) and lower symmetry (monoclinic) crystal system. After thermal decomposition in inert atmosphere, these derivatives give antimony sulfide as a final decomposition product which has many potential applications, and they exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs (chloroamphenicol and terbinafine were used as standard antibacterial and antifungal drugs, respectively) due to the nanometric size of the complexes.
Newly synthesized bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives have been characterized using various methods. These derivatives give antimony sulfide as a final decomposition product and exhibit enhanced antimicrobial activities (greater zone of inhibition) as compared to the free ligands and standard drugs due to the nanometric size of the complexes.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.4026</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-9518-724X</orcidid></addata></record> |
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| ispartof | Applied organometallic chemistry, 2018-02, Vol.32 (2), p.n/a |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Antiinfectives and antibacterials antimicrobial activities Antimony antimony(III) Chemistry Derivatives dialkyldithiophosphate Diffraction Fungicides Ligands powder XRD Thermal decomposition thermal studies X ray powder diffraction X-ray diffraction X-rays |
| title | Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands |
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