Re‐treated nanocellulose whiskers alongside a polyolefin elastomer to toughen and improve polypropylene composites
ABSTRACT Nanocellulose whiskers grafted with a polyolefin elastomer (POE–NCW) were prepared through the reaction of nanocellulose whiskers and a polyolefin elastomer (POE). This was followed by the blending of POE–NCW with polypropylene (PP), and thus, ternary nanocomposites were obtained. When the...
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| Veröffentlicht in: | Journal of applied polymer science 2018-04, Vol.135 (15), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Zhang, Yajuan Jiang, Xianyou Bai, Zhiwei Wang, Jikui Qian, Ziming Liu, Yaxin |
| description | ABSTRACT
Nanocellulose whiskers grafted with a polyolefin elastomer (POE–NCW) were prepared through the reaction of nanocellulose whiskers and a polyolefin elastomer (POE). This was followed by the blending of POE–NCW with polypropylene (PP), and thus, ternary nanocomposites were obtained. When the dosage of POE–NCW was 2%, the tensile strength, storage modulus, and Vicat softening temperature of the ternary nanocomposites increased by 60%, 35%, and 13 °C, respectively. A core–shell‐like cladding structure was formed by the coating of POE on the nanorigid particles; the toughness and rigidity of the composites were both significantly improved, and this prevented brittle fracture under impact and enlarges the range of applications for PP composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46066. |
| doi_str_mv | 10.1002/app.46066 |
| format | Article |
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Nanocellulose whiskers grafted with a polyolefin elastomer (POE–NCW) were prepared through the reaction of nanocellulose whiskers and a polyolefin elastomer (POE). This was followed by the blending of POE–NCW with polypropylene (PP), and thus, ternary nanocomposites were obtained. When the dosage of POE–NCW was 2%, the tensile strength, storage modulus, and Vicat softening temperature of the ternary nanocomposites increased by 60%, 35%, and 13 °C, respectively. A core–shell‐like cladding structure was formed by the coating of POE on the nanorigid particles; the toughness and rigidity of the composites were both significantly improved, and this prevented brittle fracture under impact and enlarges the range of applications for PP composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46066.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.46066</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>and nanocrystals ; Cladding ; copolymers ; Elastomers ; fibers ; Fracture toughness ; Materials science ; mechanical properties ; Nanocomposites ; nanoparticles ; nanowires ; Polymer matrix composites ; Polymers ; Polyolefins ; Polypropylene ; Storage modulus ; Whisker composites</subject><ispartof>Journal of applied polymer science, 2018-04, Vol.135 (15), p.n/a</ispartof><rights>2017 Wiley Periodicals, Inc.</rights><rights>2018 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2976-d4705120c13b7665cc9b9150f10f05c35294ab1775c05f7796177c935ef9ed143</citedby><cites>FETCH-LOGICAL-c2976-d4705120c13b7665cc9b9150f10f05c35294ab1775c05f7796177c935ef9ed143</cites><orcidid>0000-0001-5272-9774</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.46066$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.46066$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Zhang, Yajuan</creatorcontrib><creatorcontrib>Jiang, Xianyou</creatorcontrib><creatorcontrib>Bai, Zhiwei</creatorcontrib><creatorcontrib>Wang, Jikui</creatorcontrib><creatorcontrib>Qian, Ziming</creatorcontrib><creatorcontrib>Liu, Yaxin</creatorcontrib><title>Re‐treated nanocellulose whiskers alongside a polyolefin elastomer to toughen and improve polypropylene composites</title><title>Journal of applied polymer science</title><description>ABSTRACT
Nanocellulose whiskers grafted with a polyolefin elastomer (POE–NCW) were prepared through the reaction of nanocellulose whiskers and a polyolefin elastomer (POE). This was followed by the blending of POE–NCW with polypropylene (PP), and thus, ternary nanocomposites were obtained. When the dosage of POE–NCW was 2%, the tensile strength, storage modulus, and Vicat softening temperature of the ternary nanocomposites increased by 60%, 35%, and 13 °C, respectively. A core–shell‐like cladding structure was formed by the coating of POE on the nanorigid particles; the toughness and rigidity of the composites were both significantly improved, and this prevented brittle fracture under impact and enlarges the range of applications for PP composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46066.</description><subject>and nanocrystals</subject><subject>Cladding</subject><subject>copolymers</subject><subject>Elastomers</subject><subject>fibers</subject><subject>Fracture toughness</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Nanocomposites</subject><subject>nanoparticles</subject><subject>nanowires</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Polyolefins</subject><subject>Polypropylene</subject><subject>Storage modulus</subject><subject>Whisker composites</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kM9KxDAQxoMouK4efIOAJw_dTdomaY7L4j9YUETPJZtOd7umTU1al958BJ_RJzFuvQoD88H8ZubjQ-iSkhklJJ6rtp2lnHB-hCaUSBGlPM6O0STMaJRJyU7Rmfc7QihlhE9Q9wzfn1-dA9VBgRvVWA3G9MZ6wPtt5d_AeayMbTa-KgAr3FozWANl1WAwyne2Boc7G6rfbKHBqilwVbfOfsCBDaodDDSAta1b66sO_Dk6KZXxcPHXp-j19uZleR-tHu8elotVpGMpeFSkgjAaE02TteCcaS3XMtguKSkJ0wmLZarWVAimCSuFkDxoLRMGpYSCpskUXY13g4n3HnyX72zvmvAypzITPElIJgJ1PVLaWe8dlHnrqlq5Iack_w01D6Hmh1ADOx_ZfWVg-B_MF09P48YPClF7lw</recordid><startdate>20180415</startdate><enddate>20180415</enddate><creator>Zhang, Yajuan</creator><creator>Jiang, Xianyou</creator><creator>Bai, Zhiwei</creator><creator>Wang, Jikui</creator><creator>Qian, Ziming</creator><creator>Liu, Yaxin</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-5272-9774</orcidid></search><sort><creationdate>20180415</creationdate><title>Re‐treated nanocellulose whiskers alongside a polyolefin elastomer to toughen and improve polypropylene composites</title><author>Zhang, Yajuan ; Jiang, Xianyou ; Bai, Zhiwei ; Wang, Jikui ; Qian, Ziming ; Liu, Yaxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2976-d4705120c13b7665cc9b9150f10f05c35294ab1775c05f7796177c935ef9ed143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>and nanocrystals</topic><topic>Cladding</topic><topic>copolymers</topic><topic>Elastomers</topic><topic>fibers</topic><topic>Fracture toughness</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Nanocomposites</topic><topic>nanoparticles</topic><topic>nanowires</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Polyolefins</topic><topic>Polypropylene</topic><topic>Storage modulus</topic><topic>Whisker composites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yajuan</creatorcontrib><creatorcontrib>Jiang, Xianyou</creatorcontrib><creatorcontrib>Bai, Zhiwei</creatorcontrib><creatorcontrib>Wang, Jikui</creatorcontrib><creatorcontrib>Qian, Ziming</creatorcontrib><creatorcontrib>Liu, Yaxin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yajuan</au><au>Jiang, Xianyou</au><au>Bai, Zhiwei</au><au>Wang, Jikui</au><au>Qian, Ziming</au><au>Liu, Yaxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Re‐treated nanocellulose whiskers alongside a polyolefin elastomer to toughen and improve polypropylene composites</atitle><jtitle>Journal of applied polymer science</jtitle><date>2018-04-15</date><risdate>2018</risdate><volume>135</volume><issue>15</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
Nanocellulose whiskers grafted with a polyolefin elastomer (POE–NCW) were prepared through the reaction of nanocellulose whiskers and a polyolefin elastomer (POE). This was followed by the blending of POE–NCW with polypropylene (PP), and thus, ternary nanocomposites were obtained. When the dosage of POE–NCW was 2%, the tensile strength, storage modulus, and Vicat softening temperature of the ternary nanocomposites increased by 60%, 35%, and 13 °C, respectively. A core–shell‐like cladding structure was formed by the coating of POE on the nanorigid particles; the toughness and rigidity of the composites were both significantly improved, and this prevented brittle fracture under impact and enlarges the range of applications for PP composites. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46066.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/app.46066</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-5272-9774</orcidid></addata></record> |
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| subjects | and nanocrystals Cladding copolymers Elastomers fibers Fracture toughness Materials science mechanical properties Nanocomposites nanoparticles nanowires Polymer matrix composites Polymers Polyolefins Polypropylene Storage modulus Whisker composites |
| title | Re‐treated nanocellulose whiskers alongside a polyolefin elastomer to toughen and improve polypropylene composites |
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