Synthesis of ZnO nanoparticles for oil–water interfacial tension reduction in enhanced oil recovery

Nanoparticles show potential use in applications associated with upstream oil and gas engineering to increase the performance of numerous methods such as wettability alteration, interfacial tension reduction, thermal conductivity and enhanced oil recovery operations. Surface tension optimization is...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2018-02, Vol.124 (2), p.1-13, Article 128
Hauptverfasser: Soleimani, Hassan, Baig, Mirza Khurram, Yahya, Noorhana, Khodapanah, Leila, Sabet, Maziyar, Demiral, Birol M. R., Burda, Marek
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container_title Applied physics. A, Materials science & processing
container_volume 124
creator Soleimani, Hassan
Baig, Mirza Khurram
Yahya, Noorhana
Khodapanah, Leila
Sabet, Maziyar
Demiral, Birol M. R.
Burda, Marek
description Nanoparticles show potential use in applications associated with upstream oil and gas engineering to increase the performance of numerous methods such as wettability alteration, interfacial tension reduction, thermal conductivity and enhanced oil recovery operations. Surface tension optimization is an important parameter in enhanced oil recovery. Current work focuses on the new economical method of surface tension optimization of ZnO nanofluids for oil–water interfacial tension reduction in enhanced oil recovery. In this paper, zinc oxide (ZnO) nanocrystallites were prepared using the chemical route and explored for enhanced oil recovery (EOR). Adsorption of ZnO nanoparticles (NPs) on calcite (111) surface was investigated using the adsorption locator module of Materials Studio software. It was found that ZnO nanoparticles show maximum adsorption energy of − 253 kcal/mol. The adsorption of ZnO on the rock surface changes the wettability which results in capillary force reduction and consequently increasing EOR. The nanofluids have been prepared by varying the concentration of ZnO nanoparticles to find the optimum value for surface tension. The surface tension (ST) was calculated with different concentration of ZnO nanoparticles using the pendant drop method. The results show a maximum value of ST 35.57 mN/m at 0.3 wt% of ZnO NPs. It was found that the nanofluid with highest surface tension (0.3 wt%) resulted in higher recovery efficiency. The highest recovery factor of 11.82% at 0.3 wt% is due to the oil/water interfacial tension reduction and wettability alteration.
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Adsorption of ZnO nanoparticles (NPs) on calcite (111) surface was investigated using the adsorption locator module of Materials Studio software. It was found that ZnO nanoparticles show maximum adsorption energy of − 253 kcal/mol. The adsorption of ZnO on the rock surface changes the wettability which results in capillary force reduction and consequently increasing EOR. The nanofluids have been prepared by varying the concentration of ZnO nanoparticles to find the optimum value for surface tension. The surface tension (ST) was calculated with different concentration of ZnO nanoparticles using the pendant drop method. The results show a maximum value of ST 35.57 mN/m at 0.3 wt% of ZnO NPs. It was found that the nanofluid with highest surface tension (0.3 wt%) resulted in higher recovery efficiency. 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Adsorption of ZnO nanoparticles (NPs) on calcite (111) surface was investigated using the adsorption locator module of Materials Studio software. It was found that ZnO nanoparticles show maximum adsorption energy of − 253 kcal/mol. The adsorption of ZnO on the rock surface changes the wettability which results in capillary force reduction and consequently increasing EOR. The nanofluids have been prepared by varying the concentration of ZnO nanoparticles to find the optimum value for surface tension. The surface tension (ST) was calculated with different concentration of ZnO nanoparticles using the pendant drop method. The results show a maximum value of ST 35.57 mN/m at 0.3 wt% of ZnO NPs. It was found that the nanofluid with highest surface tension (0.3 wt%) resulted in higher recovery efficiency. 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subjects Adsorption
Applied physics
Calcite
Characterization and Evaluation of Materials
Condensed Matter Physics
Economic conditions
Enhanced oil recovery
Machines
Manufacturing
Materials science
Nanofluids
Nanoparticles
Nanotechnology
Natural gas
Optical and Electronic Materials
Optimization
Physics
Physics and Astronomy
Processes
Reduction
Surface chemistry
Surface tension
Surfaces and Interfaces
Thermal conductivity
Thin Films
Wettability
Zinc oxide
Zinc oxides
title Synthesis of ZnO nanoparticles for oil–water interfacial tension reduction in enhanced oil recovery
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