Metal–Organic Framework Templated Porous Carbon‐Metal Oxide/Reduced Graphene Oxide as Superior Support of Bimetallic Nanoparticles for Efficient Hydrogen Generation from Formic Acid
Ultrafine PdAg nanoparticles (NPs) are successfully immobilized on zirconia/porous carbon/reduced graphene oxide (ZrO2/C/rGO) nanocomposite derived from metal organic framework/graphene oxide. Monodispersed PdAg NPs (diameter ≤2.5 nm) can be facilely anchored on the ZrO2/C/rGO and the aggregation of...
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| Veröffentlicht in: | Advanced energy materials 2018-01, Vol.8 (1), p.n/a |
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| creator | Song, Fu‐Zhan Zhu, Qi‐Long Yang, Xinchun Zhan, Wen‐Wen Pachfule, Pradip Tsumori, Nobuko Xu, Qiang |
| description | Ultrafine PdAg nanoparticles (NPs) are successfully immobilized on zirconia/porous carbon/reduced graphene oxide (ZrO2/C/rGO) nanocomposite derived from metal organic framework/graphene oxide. Monodispersed PdAg NPs (diameter ≤2.5 nm) can be facilely anchored on the ZrO2/C/rGO and the aggregation of metal NPs can be avoided utmostly. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO exhibits excellent activity (turnover frequency, 4500 h−1 at 333 K) for the dehydrogenation of formic acid. As an effective strategy, it provides an opportunity to immobilize ultrafine metal NPs on metal oxide/porous carbon/reduced graphene oxide, which has tremendous application prospects in various catalytic fields.
A superior support, namely ZrO2/C/rGO derived from metal–organic framework/graphene oxide, to immobilize ultrafine PdAg nanoparticles (NPs) (diameter ≤ 2.5 nm) is reported. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO nanocatalyst shows extremely high catalytic performance (turnover frequency, 4500 h−1) for the dehydrogenation of formic acid. |
| doi_str_mv | 10.1002/aenm.201701416 |
| format | Article |
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A superior support, namely ZrO2/C/rGO derived from metal–organic framework/graphene oxide, to immobilize ultrafine PdAg nanoparticles (NPs) (diameter ≤ 2.5 nm) is reported. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO nanocatalyst shows extremely high catalytic performance (turnover frequency, 4500 h−1) for the dehydrogenation of formic acid.</description><identifier>ISSN: 1614-6832</identifier><identifier>EISSN: 1614-6840</identifier><identifier>DOI: 10.1002/aenm.201701416</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Bimetals ; Carbon ; Catalysis ; Dehydrogenation ; Formic acid ; Graphene ; heterogeneous catalysis ; Hydrogen storage ; metal nanoparticles ; Metal oxides ; Metal-organic frameworks ; metal–organic framework ; Nanocomposites ; Nanoparticles ; Palladium ; Synergistic effect ; Zirconium dioxide</subject><ispartof>Advanced energy materials, 2018-01, Vol.8 (1), p.n/a</ispartof><rights>2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4206-c346c478a465c05a5d975899425fc6e5dcfd6d8848df1594769dd4f644daaf543</citedby><cites>FETCH-LOGICAL-c4206-c346c478a465c05a5d975899425fc6e5dcfd6d8848df1594769dd4f644daaf543</cites><orcidid>0000-0001-5385-9650</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faenm.201701416$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faenm.201701416$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Song, Fu‐Zhan</creatorcontrib><creatorcontrib>Zhu, Qi‐Long</creatorcontrib><creatorcontrib>Yang, Xinchun</creatorcontrib><creatorcontrib>Zhan, Wen‐Wen</creatorcontrib><creatorcontrib>Pachfule, Pradip</creatorcontrib><creatorcontrib>Tsumori, Nobuko</creatorcontrib><creatorcontrib>Xu, Qiang</creatorcontrib><title>Metal–Organic Framework Templated Porous Carbon‐Metal Oxide/Reduced Graphene Oxide as Superior Support of Bimetallic Nanoparticles for Efficient Hydrogen Generation from Formic Acid</title><title>Advanced energy materials</title><description>Ultrafine PdAg nanoparticles (NPs) are successfully immobilized on zirconia/porous carbon/reduced graphene oxide (ZrO2/C/rGO) nanocomposite derived from metal organic framework/graphene oxide. Monodispersed PdAg NPs (diameter ≤2.5 nm) can be facilely anchored on the ZrO2/C/rGO and the aggregation of metal NPs can be avoided utmostly. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO exhibits excellent activity (turnover frequency, 4500 h−1 at 333 K) for the dehydrogenation of formic acid. As an effective strategy, it provides an opportunity to immobilize ultrafine metal NPs on metal oxide/porous carbon/reduced graphene oxide, which has tremendous application prospects in various catalytic fields.
A superior support, namely ZrO2/C/rGO derived from metal–organic framework/graphene oxide, to immobilize ultrafine PdAg nanoparticles (NPs) (diameter ≤ 2.5 nm) is reported. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO nanocatalyst shows extremely high catalytic performance (turnover frequency, 4500 h−1) for the dehydrogenation of formic acid.</description><subject>Bimetals</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Dehydrogenation</subject><subject>Formic acid</subject><subject>Graphene</subject><subject>heterogeneous catalysis</subject><subject>Hydrogen storage</subject><subject>metal nanoparticles</subject><subject>Metal oxides</subject><subject>Metal-organic frameworks</subject><subject>metal–organic framework</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Palladium</subject><subject>Synergistic effect</subject><subject>Zirconium dioxide</subject><issn>1614-6832</issn><issn>1614-6840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkcFu1DAQhiMEUqu2V86WOO_WTmwnPi6r3S1S20VQzpFrj4tLYodxorK3PgIST9PX6ZPgZVE5MpcZjb5v5vAXxVtG54zS8lxD6OclZTVlnMlXxTGTjM9kw-nrl7kqj4qzlO5pLq4Yrarj4ukKRt09P_7a4p0O3pA16h4eIn4jN9APnR7Bko8R45TIUuNtDM-PP_84ZPvDWzj_BHYymdmgHr5CgMOa6EQ-TwOgj7gfhogjiY689_3e7fKjax3ioHH0poNEXOZWznnjIYzkYmcx3kEgm3wR9ehjIA5jT9YR--wujLenxRunuwRnf_tJ8WW9ullezC63mw_LxeXM8JLKmam4NLxuNJfCUKGFVbVolOKlcEaCsMZZaZuGN9YxoXgtlbXcSc6t1k7w6qR4d7g7YPw-QRrb-zhhyC9bphpeC0Vllan5gTIYU0Jw7YC-17hrGW33CbX7hNqXhLKgDsKD72D3H7pdrK6v_rm_AddFmg4</recordid><startdate>20180105</startdate><enddate>20180105</enddate><creator>Song, Fu‐Zhan</creator><creator>Zhu, Qi‐Long</creator><creator>Yang, Xinchun</creator><creator>Zhan, Wen‐Wen</creator><creator>Pachfule, Pradip</creator><creator>Tsumori, Nobuko</creator><creator>Xu, Qiang</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5385-9650</orcidid></search><sort><creationdate>20180105</creationdate><title>Metal–Organic Framework Templated Porous Carbon‐Metal Oxide/Reduced Graphene Oxide as Superior Support of Bimetallic Nanoparticles for Efficient Hydrogen Generation from Formic Acid</title><author>Song, Fu‐Zhan ; Zhu, Qi‐Long ; Yang, Xinchun ; Zhan, Wen‐Wen ; Pachfule, Pradip ; Tsumori, Nobuko ; Xu, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4206-c346c478a465c05a5d975899425fc6e5dcfd6d8848df1594769dd4f644daaf543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Bimetals</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Dehydrogenation</topic><topic>Formic acid</topic><topic>Graphene</topic><topic>heterogeneous catalysis</topic><topic>Hydrogen storage</topic><topic>metal nanoparticles</topic><topic>Metal oxides</topic><topic>Metal-organic frameworks</topic><topic>metal–organic framework</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Palladium</topic><topic>Synergistic effect</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Fu‐Zhan</creatorcontrib><creatorcontrib>Zhu, Qi‐Long</creatorcontrib><creatorcontrib>Yang, Xinchun</creatorcontrib><creatorcontrib>Zhan, Wen‐Wen</creatorcontrib><creatorcontrib>Pachfule, Pradip</creatorcontrib><creatorcontrib>Tsumori, Nobuko</creatorcontrib><creatorcontrib>Xu, Qiang</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced energy materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Fu‐Zhan</au><au>Zhu, Qi‐Long</au><au>Yang, Xinchun</au><au>Zhan, Wen‐Wen</au><au>Pachfule, Pradip</au><au>Tsumori, Nobuko</au><au>Xu, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal–Organic Framework Templated Porous Carbon‐Metal Oxide/Reduced Graphene Oxide as Superior Support of Bimetallic Nanoparticles for Efficient Hydrogen Generation from Formic Acid</atitle><jtitle>Advanced energy materials</jtitle><date>2018-01-05</date><risdate>2018</risdate><volume>8</volume><issue>1</issue><epage>n/a</epage><issn>1614-6832</issn><eissn>1614-6840</eissn><abstract>Ultrafine PdAg nanoparticles (NPs) are successfully immobilized on zirconia/porous carbon/reduced graphene oxide (ZrO2/C/rGO) nanocomposite derived from metal organic framework/graphene oxide. Monodispersed PdAg NPs (diameter ≤2.5 nm) can be facilely anchored on the ZrO2/C/rGO and the aggregation of metal NPs can be avoided utmostly. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO exhibits excellent activity (turnover frequency, 4500 h−1 at 333 K) for the dehydrogenation of formic acid. As an effective strategy, it provides an opportunity to immobilize ultrafine metal NPs on metal oxide/porous carbon/reduced graphene oxide, which has tremendous application prospects in various catalytic fields.
A superior support, namely ZrO2/C/rGO derived from metal–organic framework/graphene oxide, to immobilize ultrafine PdAg nanoparticles (NPs) (diameter ≤ 2.5 nm) is reported. By virtue of the synergistic effect between metal NPs and support, the resulting PdAg@ZrO2/C/rGO nanocatalyst shows extremely high catalytic performance (turnover frequency, 4500 h−1) for the dehydrogenation of formic acid.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aenm.201701416</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5385-9650</orcidid></addata></record> |
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| subjects | Bimetals Carbon Catalysis Dehydrogenation Formic acid Graphene heterogeneous catalysis Hydrogen storage metal nanoparticles Metal oxides Metal-organic frameworks metal–organic framework Nanocomposites Nanoparticles Palladium Synergistic effect Zirconium dioxide |
| title | Metal–Organic Framework Templated Porous Carbon‐Metal Oxide/Reduced Graphene Oxide as Superior Support of Bimetallic Nanoparticles for Efficient Hydrogen Generation from Formic Acid |
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