Adsorption properties of shungite in purification of water–alcohol solutions

Shungite adsorption properties to remove higher alcohols and other impurities from water–alcohol solutions is studied by the methods of nitrogen adsorption, thermogravimetric analysis, wetting, temperature-programmed desorption mass spectrometry, and FTIR spectroscopy. Shungite is shown to be able t...

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Veröffentlicht in:Journal of superhard materials 2017-11, Vol.39 (6), p.416-421
Hauptverfasser: Mel’nik, L. M., Tkachuk, N. A., Turchun, O. V., Diyuk, V. E., Ischenko, O. V., Byeda, O. O., Kisterska, L. D., Loginova, O. B., Lysovenko, S. O., Gontar, O. G., Garashchenko, V. V.
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container_end_page 421
container_issue 6
container_start_page 416
container_title Journal of superhard materials
container_volume 39
creator Mel’nik, L. M.
Tkachuk, N. A.
Turchun, O. V.
Diyuk, V. E.
Ischenko, O. V.
Byeda, O. O.
Kisterska, L. D.
Loginova, O. B.
Lysovenko, S. O.
Gontar, O. G.
Garashchenko, V. V.
description Shungite adsorption properties to remove higher alcohols and other impurities from water–alcohol solutions is studied by the methods of nitrogen adsorption, thermogravimetric analysis, wetting, temperature-programmed desorption mass spectrometry, and FTIR spectroscopy. Shungite is shown to be able to effectively sorb impurities from water-alcohol solutions to form fairly strong adsorption systems. Heat treatment 180°C in vacuum results in almost complete decomposition of the adsorption systems, thus providing recovery and a slight increase of the specific surface and sorptive volume of shungite. The present findings demonstrate the theoretical possibility of recovery of adsorption centers on the shungite surface, which would extend its usable life as a sorbent.
doi_str_mv 10.3103/S1063457617060053
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1934-9408
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subjects Adsorption
Alcohol
Alcohols
Chemistry
Chemistry and Materials Science
Fourier transforms
Heat treatment
Impurities
Mass spectrometry
Physical Chemistry
Production
Properties
Recovery
Structure
Surface chemistry
Thermogravimetric analysis
Water purification
title Adsorption properties of shungite in purification of water–alcohol solutions
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