[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism
The crystal structure of [NiEn 3 ]CrO 4 (En is ethylendiamine), C 6 H 24 CrN 6 NiO 4 is studied: a = 9.0408(5) Å, c = 9.7466(4) Å, V = 689.92(8) Å 3 , space group P 6 3 / mmc , Z = 2, d x = 1.704 g/cm 3 , Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in...
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| Veröffentlicht in: | Journal of structural chemistry 2017-12, Vol.58 (7), p.1448-1452 |
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| container_title | Journal of structural chemistry |
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| creator | Khranenko, S. P. Komarov, V. Yu Gerasimov, E. Yu Zadesenets, A. V. Maksimovsky, E. A. Gromilov, S. A. |
| description | The crystal structure of [NiEn
3
]CrO
4
(En is ethylendiamine), C
6
H
24
CrN
6
NiO
4
is studied:
a
= 9.0408(5) Å,
c
= 9.7466(4) Å,
V
= 689.92(8) Å
3
, space group
P
6
3
/
mmc
,
Z
= 2,
d
x
= 1.704 g/cm
3
, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr
2
O
3
powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn
3
]CrO
4
single crystals. |
| doi_str_mv | 10.1134/S0022476617070265 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1982332672</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1982332672</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-dd03858dc629965848fd591248f72d727167f376b624d57e32d6899c8057c8b73</originalsourceid><addsrcrecordid>eNp1kE9Lw0AQxRdRsFY_gLeA10Z3Z7M7ux4EKa0KxR6qJ5GQZjc2pfnjbHLw25tSD4J4eof3fm-Gx9il4NdCyORmxTlAgloL5MhBqyM2EgplbBDtMRvt7Xjvn7KzELacc2usHrG7t-dyVsv3KS2T22jVUZ93PflJ1G08VdkuaqlpPXWlD5Moq13UBt-7pmqo3ZShOmcnRbYL_uJHx-x1PnuZPsaL5cPT9H4R51LoLnaOS6OMyzVYq5VJTOGUFTAogkNAobGQqNcaEqfQS3DaWJsbrjA3a5RjdnXoHd757H3o0m3TUz2cTIU1ICVohCElDqmcmhDIF2lLZZXRVyp4up8p_TPTwMCBCUO2_vD0q_lf6BswoWbM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1982332672</pqid></control><display><type>article</type><title>[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism</title><source>Springer Nature - Complete Springer Journals</source><creator>Khranenko, S. P. ; Komarov, V. Yu ; Gerasimov, E. Yu ; Zadesenets, A. V. ; Maksimovsky, E. A. ; Gromilov, S. A.</creator><creatorcontrib>Khranenko, S. P. ; Komarov, V. Yu ; Gerasimov, E. Yu ; Zadesenets, A. V. ; Maksimovsky, E. A. ; Gromilov, S. A.</creatorcontrib><description>The crystal structure of [NiEn
3
]CrO
4
(En is ethylendiamine), C
6
H
24
CrN
6
NiO
4
is studied:
a
= 9.0408(5) Å,
c
= 9.7466(4) Å,
V
= 689.92(8) Å
3
, space group
P
6
3
/
mmc
,
Z
= 2,
d
x
= 1.704 g/cm
3
, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr
2
O
3
powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn
3
]CrO
4
single crystals.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476617070265</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Coherent scattering ; Crystal structure ; Crystals ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics ; Thermal decomposition ; Thermodynamic properties</subject><ispartof>Journal of structural chemistry, 2017-12, Vol.58 (7), p.1448-1452</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-dd03858dc629965848fd591248f72d727167f376b624d57e32d6899c8057c8b73</citedby><cites>FETCH-LOGICAL-c316t-dd03858dc629965848fd591248f72d727167f376b624d57e32d6899c8057c8b73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476617070265$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476617070265$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27913,27914,41477,42546,51308</link.rule.ids></links><search><creatorcontrib>Khranenko, S. P.</creatorcontrib><creatorcontrib>Komarov, V. Yu</creatorcontrib><creatorcontrib>Gerasimov, E. Yu</creatorcontrib><creatorcontrib>Zadesenets, A. V.</creatorcontrib><creatorcontrib>Maksimovsky, E. A.</creatorcontrib><creatorcontrib>Gromilov, S. A.</creatorcontrib><title>[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The crystal structure of [NiEn
3
]CrO
4
(En is ethylendiamine), C
6
H
24
CrN
6
NiO
4
is studied:
a
= 9.0408(5) Å,
c
= 9.7466(4) Å,
V
= 689.92(8) Å
3
, space group
P
6
3
/
mmc
,
Z
= 2,
d
x
= 1.704 g/cm
3
, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr
2
O
3
powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn
3
]CrO
4
single crystals.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coherent scattering</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Thermal decomposition</subject><subject>Thermodynamic properties</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFY_gLeA10Z3Z7M7ux4EKa0KxR6qJ5GQZjc2pfnjbHLw25tSD4J4eof3fm-Gx9il4NdCyORmxTlAgloL5MhBqyM2EgplbBDtMRvt7Xjvn7KzELacc2usHrG7t-dyVsv3KS2T22jVUZ93PflJ1G08VdkuaqlpPXWlD5Moq13UBt-7pmqo3ZShOmcnRbYL_uJHx-x1PnuZPsaL5cPT9H4R51LoLnaOS6OMyzVYq5VJTOGUFTAogkNAobGQqNcaEqfQS3DaWJsbrjA3a5RjdnXoHd757H3o0m3TUz2cTIU1ICVohCElDqmcmhDIF2lLZZXRVyp4up8p_TPTwMCBCUO2_vD0q_lf6BswoWbM</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Khranenko, S. P.</creator><creator>Komarov, V. Yu</creator><creator>Gerasimov, E. Yu</creator><creator>Zadesenets, A. V.</creator><creator>Maksimovsky, E. A.</creator><creator>Gromilov, S. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20171201</creationdate><title>[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism</title><author>Khranenko, S. P. ; Komarov, V. Yu ; Gerasimov, E. Yu ; Zadesenets, A. V. ; Maksimovsky, E. A. ; Gromilov, S. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-dd03858dc629965848fd591248f72d727167f376b624d57e32d6899c8057c8b73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coherent scattering</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Thermal decomposition</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khranenko, S. P.</creatorcontrib><creatorcontrib>Komarov, V. Yu</creatorcontrib><creatorcontrib>Gerasimov, E. Yu</creatorcontrib><creatorcontrib>Zadesenets, A. V.</creatorcontrib><creatorcontrib>Maksimovsky, E. A.</creatorcontrib><creatorcontrib>Gromilov, S. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khranenko, S. P.</au><au>Komarov, V. Yu</au><au>Gerasimov, E. Yu</au><au>Zadesenets, A. V.</au><au>Maksimovsky, E. A.</au><au>Gromilov, S. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>58</volume><issue>7</issue><spage>1448</spage><epage>1452</epage><pages>1448-1452</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The crystal structure of [NiEn
3
]CrO
4
(En is ethylendiamine), C
6
H
24
CrN
6
NiO
4
is studied:
a
= 9.0408(5) Å,
c
= 9.7466(4) Å,
V
= 689.92(8) Å
3
, space group
P
6
3
/
mmc
,
Z
= 2,
d
x
= 1.704 g/cm
3
, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr
2
O
3
powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn
3
]CrO
4
single crystals.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476617070265</doi><tpages>5</tpages></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Coherent scattering Crystal structure Crystals Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics Thermal decomposition Thermodynamic properties |
| title | [NiEn3]CrO4: Structure, thermal properties, and pseudomorphism |
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