Preparation of nanocellulose-based polyaniline composite film and its application in electrochromic device
With the development of nanotechnology, nano biomaterial based on renewable resource is a hot spot of the current research. In this paper, a relatively new concept of using nanocellulose (NC) as matrix materials, the functionality of the composites has been enhanced by using polyaniline (PANI) as a...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2017-07, Vol.28 (14), p.10158-10165 |
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| creator | Zhang, Sihang Fu, Runfang Gu, Yingchun Dong, Liqin Li, Jingjing Chen, Sheng |
| description | With the development of nanotechnology, nano biomaterial based on renewable resource is a hot spot of the current research. In this paper, a relatively new concept of using nanocellulose (NC) as matrix materials, the functionality of the composites has been enhanced by using polyaniline (PANI) as a functional component. Nanocellulose was extracted by swelling cotton pulp with sulphuic acid, following ultrasonic treatment. Composite film of PANI with inclusions 60%NC loadings were prepared using in situ polymerization where aniline-HCl was polymerized with ammonium peroxydisulfate (APS) as oxidant in nanocellulose aqueous suspension. PEDOT:PSS which was a complementary coloring material was used as counter electrode. A viscous polymeric electrolyte (PE) was used in electrochromic device (ECD). The architectural design of device was ITO/NC-PANI/PE/PEDOT:PSS/ITO. The color contrast of the device was achieved as 42.6% at λ
max
of 480 nm. The switching speed of ECD for coloring and bleaching were approximately 1.5 and 1.1 s in a range of −1.0 to +0.8 V. The ECD showed high coloration efficiency of 172 cm
2
/C and remarkable switching stability over 500 cycles. |
| doi_str_mv | 10.1007/s10854-017-6778-9 |
| format | Article |
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max
of 480 nm. The switching speed of ECD for coloring and bleaching were approximately 1.5 and 1.1 s in a range of −1.0 to +0.8 V. The ECD showed high coloration efficiency of 172 cm
2
/C and remarkable switching stability over 500 cycles.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-017-6778-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aniline ; Biomedical materials ; Bleaching ; Cellulose fibers ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Color ; Coloring ; Cotton ; Electrochromic cells ; Electrochromism ; Electrodes ; Electrolytes ; Glass substrates ; Inclusions ; Materials Science ; Matrix materials ; Mechanical properties ; Nanotechnology ; Optical and Electronic Materials ; Polyanilines ; Polymerization ; Polymers ; Renewable resources ; Switching ; Titanium alloys ; Ultrasonic processing</subject><ispartof>Journal of materials science. Materials in electronics, 2017-07, Vol.28 (14), p.10158-10165</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-85e7b79b3c89493d971dce7d59acbfd9aeb397d9784edf22e12502b65ecfa3ae3</citedby><cites>FETCH-LOGICAL-c355t-85e7b79b3c89493d971dce7d59acbfd9aeb397d9784edf22e12502b65ecfa3ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-017-6778-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-017-6778-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zhang, Sihang</creatorcontrib><creatorcontrib>Fu, Runfang</creatorcontrib><creatorcontrib>Gu, Yingchun</creatorcontrib><creatorcontrib>Dong, Liqin</creatorcontrib><creatorcontrib>Li, Jingjing</creatorcontrib><creatorcontrib>Chen, Sheng</creatorcontrib><title>Preparation of nanocellulose-based polyaniline composite film and its application in electrochromic device</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>With the development of nanotechnology, nano biomaterial based on renewable resource is a hot spot of the current research. In this paper, a relatively new concept of using nanocellulose (NC) as matrix materials, the functionality of the composites has been enhanced by using polyaniline (PANI) as a functional component. Nanocellulose was extracted by swelling cotton pulp with sulphuic acid, following ultrasonic treatment. Composite film of PANI with inclusions 60%NC loadings were prepared using in situ polymerization where aniline-HCl was polymerized with ammonium peroxydisulfate (APS) as oxidant in nanocellulose aqueous suspension. PEDOT:PSS which was a complementary coloring material was used as counter electrode. A viscous polymeric electrolyte (PE) was used in electrochromic device (ECD). The architectural design of device was ITO/NC-PANI/PE/PEDOT:PSS/ITO. The color contrast of the device was achieved as 42.6% at λ
max
of 480 nm. The switching speed of ECD for coloring and bleaching were approximately 1.5 and 1.1 s in a range of −1.0 to +0.8 V. The ECD showed high coloration efficiency of 172 cm
2
/C and remarkable switching stability over 500 cycles.</description><subject>Aniline</subject><subject>Biomedical materials</subject><subject>Bleaching</subject><subject>Cellulose fibers</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Color</subject><subject>Coloring</subject><subject>Cotton</subject><subject>Electrochromic cells</subject><subject>Electrochromism</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Glass substrates</subject><subject>Inclusions</subject><subject>Materials Science</subject><subject>Matrix materials</subject><subject>Mechanical properties</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Polyanilines</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Renewable resources</subject><subject>Switching</subject><subject>Titanium alloys</subject><subject>Ultrasonic processing</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtLxDAUhYMoOI7-AHcB19E8mkmzlMEXDOhCwV1I01vNkCY16Qjz7-1QF25cXTic71z4ELpk9JpRqm4Ko7WsCGWKrJSqiT5CCyaVIFXN34_RgmqpSCU5P0VnpWwppatK1Au0fckw2GxHnyJOHY42Jgch7EIqQBpboMVDCnsbffARsEv9kIofAXc-9NjGFvuxYDsMwbt5xUcMAdyYk_vMqfcOt_DtHZyjk86GAhe_d4ne7u9e149k8_zwtL7dECekHEktQTVKN8LVutKi1Yq1DlQrtXVN12oLjdBqiusK2o5zYFxS3qwkuM4KC2KJrubdIaevHZTRbNMux-mlYbrmXAmh6NRic8vlVEqGzgzZ9zbvDaPmoNTMSs2k1ByUGj0xfGbK1I0fkP8s_wv9AG86fJU</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>Zhang, Sihang</creator><creator>Fu, Runfang</creator><creator>Gu, Yingchun</creator><creator>Dong, Liqin</creator><creator>Li, Jingjing</creator><creator>Chen, Sheng</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope></search><sort><creationdate>20170701</creationdate><title>Preparation of nanocellulose-based polyaniline composite film and its application in electrochromic device</title><author>Zhang, Sihang ; Fu, Runfang ; Gu, Yingchun ; Dong, Liqin ; Li, Jingjing ; Chen, Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-85e7b79b3c89493d971dce7d59acbfd9aeb397d9784edf22e12502b65ecfa3ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aniline</topic><topic>Biomedical materials</topic><topic>Bleaching</topic><topic>Cellulose fibers</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Color</topic><topic>Coloring</topic><topic>Cotton</topic><topic>Electrochromic cells</topic><topic>Electrochromism</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Glass substrates</topic><topic>Inclusions</topic><topic>Materials Science</topic><topic>Matrix materials</topic><topic>Mechanical properties</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Polyanilines</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Renewable resources</topic><topic>Switching</topic><topic>Titanium alloys</topic><topic>Ultrasonic processing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Sihang</creatorcontrib><creatorcontrib>Fu, Runfang</creatorcontrib><creatorcontrib>Gu, Yingchun</creatorcontrib><creatorcontrib>Dong, Liqin</creatorcontrib><creatorcontrib>Li, Jingjing</creatorcontrib><creatorcontrib>Chen, Sheng</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Sihang</au><au>Fu, Runfang</au><au>Gu, Yingchun</au><au>Dong, Liqin</au><au>Li, Jingjing</au><au>Chen, Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of nanocellulose-based polyaniline composite film and its application in electrochromic device</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2017-07-01</date><risdate>2017</risdate><volume>28</volume><issue>14</issue><spage>10158</spage><epage>10165</epage><pages>10158-10165</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>With the development of nanotechnology, nano biomaterial based on renewable resource is a hot spot of the current research. In this paper, a relatively new concept of using nanocellulose (NC) as matrix materials, the functionality of the composites has been enhanced by using polyaniline (PANI) as a functional component. Nanocellulose was extracted by swelling cotton pulp with sulphuic acid, following ultrasonic treatment. Composite film of PANI with inclusions 60%NC loadings were prepared using in situ polymerization where aniline-HCl was polymerized with ammonium peroxydisulfate (APS) as oxidant in nanocellulose aqueous suspension. PEDOT:PSS which was a complementary coloring material was used as counter electrode. A viscous polymeric electrolyte (PE) was used in electrochromic device (ECD). The architectural design of device was ITO/NC-PANI/PE/PEDOT:PSS/ITO. The color contrast of the device was achieved as 42.6% at λ
max
of 480 nm. The switching speed of ECD for coloring and bleaching were approximately 1.5 and 1.1 s in a range of −1.0 to +0.8 V. The ECD showed high coloration efficiency of 172 cm
2
/C and remarkable switching stability over 500 cycles.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-017-6778-9</doi><tpages>8</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Aniline Biomedical materials Bleaching Cellulose fibers Characterization and Evaluation of Materials Chemistry and Materials Science Color Coloring Cotton Electrochromic cells Electrochromism Electrodes Electrolytes Glass substrates Inclusions Materials Science Matrix materials Mechanical properties Nanotechnology Optical and Electronic Materials Polyanilines Polymerization Polymers Renewable resources Switching Titanium alloys Ultrasonic processing |
| title | Preparation of nanocellulose-based polyaniline composite film and its application in electrochromic device |
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